Skip to main content
SpringerLink
Log in

Synergistic effect of AM-4VP-9 copolymer and iodide ion on corrosion inhibition of mild steel in 1 M H2SO4

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The effect of iodide ions on the corrosion inhibition of mild steel in 1 M sulfuric acid in the presence of poly(acrylamide-co-4-vinylpyridine) copolymer abbreviated by (AM-4VP-9) was studied by weight loss measurements and electrochemical techniques (impedance spectroscopy and polarisation curves) at 18 °C. The results obtained showed that the inhibition efficiency increased with increasing copolymer concentration. It was also found that the inhibition efficiency increased with the addition of potassium iodide (KI) to the copolymer. A synergistic effect was observed between the AM-4VP-9 copolymer and KI. On the other hand, it was found that the inhibiting effect of the system (AM-4VP-9 + KI) increased with increasing immersion time. Polarisation curves indicate that (AM-4VP-9) copolymer act as mixed inhibitors. EIS measurements show an increase of the transfer resistance with the inhibitor concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. A. El Sayed, J. Appl. Electrochem. 27, 193 (1997)

    Article  Google Scholar 

  2. M. Ajmal, A.S. Mideen, M.A. Quraishi, Corros. Sci. 36, 79 (1994)

    Article  CAS  Google Scholar 

  3. F. Bentiss, M. Traisnel, M. Lagrenee, Corros. Sci. 42, 127 (2000)

    Article  CAS  Google Scholar 

  4. X.L. Cheng, H.Y. Ma, S.H. Chen, R. Yu, X. Chen, Z.M. Yao, Corros. Sci. 41, 321 (1999)

    Article  CAS  Google Scholar 

  5. M. Ajmal, J. Rawat, M.A. Quraishi, Br. Corros. J. 34, 220 (1999)

    Article  CAS  Google Scholar 

  6. S. Kertit, B. Hammouti, Appl. Surf. Sci. 93, 59 (1996)

    Article  CAS  Google Scholar 

  7. S.A. Abd El-Maksound, Int. J. Electrochem. Sci. 3, 528 (2008)

    Google Scholar 

  8. A. Chetouani, B. Hammouti, A.T. Benhadda, M. Daoudi, Appl. Surf. Sci. 249, 375 (2005)

    Article  CAS  Google Scholar 

  9. K.F. Khaled, Electrochim. Acta 48, 2493 (2003)

    Article  CAS  Google Scholar 

  10. M. Lebrini, M. Lagrenée, M. Vezin, L. Gengembre, F. Bentiss, Corros. Sci. 47, 485 (2005)

    Article  CAS  Google Scholar 

  11. F. Bentiss, M. Lagrenée, M. Traisnel, J.C. Hornez, Corros. Sci. 41, 789 (1999)

    Article  CAS  Google Scholar 

  12. C. Jeyaprabha, S. Sathiyanarayanan, G. Venkatachari, Appl. Surf. Sci. 253, 432 (2007)

    Article  Google Scholar 

  13. S.A. Umoren, E.E. Ebenso, Mater. Chem. Phys. 106, 387 (2007)

    Article  CAS  Google Scholar 

  14. S.A. Umoren, Y. Lia, F.H. Wang, Corros. Sci. 52, 1777 (2010)

    Article  CAS  Google Scholar 

  15. S.A. Umoren, Y. Lia, F.H. Wang, Corros. Sci. 52, 2422 (2010)

    Article  CAS  Google Scholar 

  16. Y. Abed, B. Hammouti, F. Touhami, A. Aouniti, S. Kertit, A. Mansri, K. Elkacemi, Bull. Electrochem. 17, 105 (2001)

    CAS  Google Scholar 

  17. A. Chetouani, K. Medjahed, K.E. Benabadji, B. Hammouti, S. Kertit, A. Mansri, Prog. Org. Coat. 46, 312 (2003)

    Article  CAS  Google Scholar 

  18. Y. Abed, Z. Arrar, B. Hammouti, F. Touhami, M. Taleb, S. Kertit, A. Mansri, Anticorros. Methods Mater. 48, 304 (2001)

    Article  CAS  Google Scholar 

  19. L. Larabi, Y. Harek, M. Traisnel, A. Mansri, J. Appl. Electrochem. 34, 833 (2004)

    Article  CAS  Google Scholar 

  20. L. Larabi, Y. Harek, Portgu. Electrochim. Acta. 22, 227 (2004)

    Article  CAS  Google Scholar 

  21. S.A. Umoren, O. Ogbobe, E.E. Ebenso, U.J. Ekpe, Pigment Resin Technol. 35, 284 (2006)

    Article  CAS  Google Scholar 

  22. S.A. Umoren, U.M. Eduok, E.E. Oguzie, Portgu. Electrochim. Acta 26, 533 (2008)

    Article  CAS  Google Scholar 

  23. S.A. Umoren, O. Ogbobe, E.E. Ebenso, Bull. Electrochem. 22, 155 (2006)

    CAS  Google Scholar 

  24. G. Baojiao, L. Yuexian, J. Hongfang, J. Polym. Int. 52, 1468 (2003)

    Article  Google Scholar 

  25. B. Grassl, G. Clisson, A. Khoukh, L. Billon, Eur. Polym. J. 44, 50 (2008)

    Article  CAS  Google Scholar 

  26. Z. Gui, J. Qian, Q. An, H. Xu, Q. Zhao, Eur Polym. J. 45, 1403 (2009)

    Article  CAS  Google Scholar 

  27. K. Benmansour, K. Medjahed, L. Tennouga, A. Mansri, Eur. Polym. J. 39, 1443 (2003)

    Article  CAS  Google Scholar 

  28. Y. Bernard, D. Coleman, R.M. Fuoss, J. Am. Chem. Soc. 77, 5472 (1955)

    Article  Google Scholar 

  29. G. Mu, X. Li, Q. Qu, J. Zhou, Corros. Sci. 48, 445 (2006)

    Article  CAS  Google Scholar 

  30. C. Jeyaprabha, S. Sathiyanarayanan, S. Muralidharan, G. Venkatachari, J. Braz. Chem. Soc. 17, 61 (2006)

    Article  CAS  Google Scholar 

  31. S.R. Lodha, Pharm. Rev. 6, 1 (2008)

    Google Scholar 

  32. A. Zarrouk, B. Hammouti, H. Zarrok, I. Warad, M. Bouachrine, Der Pharma Chem. 2, 263 (2011)

    Google Scholar 

  33. F.S. de Souza, A. Spinelli, Corros. Sci. 51, 642 (2009)

    Article  Google Scholar 

  34. C. Selles, O. Benali, B. Tabti, L. Larabi, Y. Harek, J. Mater. Environ. Sci. 3, 2028 (2012)

    Google Scholar 

  35. T. Szauer, A. Brandt, Electrochim. Acta 26, 1209 (1981)

    Article  CAS  Google Scholar 

  36. Z. A. Foroulis, in Proceedings of the 6th European Symposium on Corrosion Inhibitors, Ferrara, 1985, p. 48

Download references

Author information

Authors and Affiliations

  1. Laboratoire d’Application des Electrolytes et des Polyélectrolytes Organiques (LAEPO), Département de Chimie, Université de Tlemcen, B.P. 119, 13000, Tlemcen, Algeria

    A. Mansri & B. Bouras

  2. LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, Oujda, Morocco

    B. Hammouti & A. Chetouani

  3. Department of Chemistry, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia

    I. Warad

  4. Laboratoire de chimie physique, Centre Pédagogique Régional des Professions de l’Education et de Formation “CRPEF”, Académie Régionale de l’Orientale, Oujda, Morocco

    A. Chetouani

Authors
  1. A. Mansri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Bouras
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Hammouti
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. Warad
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Chetouani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Chetouani.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mansri, A., Bouras, B., Hammouti, B. et al. Synergistic effect of AM-4VP-9 copolymer and iodide ion on corrosion inhibition of mild steel in 1 M H2SO4 . Res Chem Intermed 39, 1753–1770 (2013). https://doi.org/10.1007/s11164-012-0710-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-012-0710-y

Keywords

Search

Navigation