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Structure and spectral property of 8-(2-(5-(4-methylphenyl)-2-thienyl)vinyl)-10,10-dimethyl-10H-pyrido[1,2-a]indolium perchlorate

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Abstract

The title compound 8-(2-(5-(4-methylphenyl)-2-thienyl)vinyl)l-10,10-dimethyl-10H-pyrido[1,2-a]indolium perchlorate (3) has been synthesized by cycloaddition and condensation reactions, and characterized by elemental analysis, IR, 1H NMR, and single-crystal X-ray diffraction. The crystal structure analysis exhibits that the molecule of 3 possesses good coplanarity, and the three rings (10H-pyrido[1,2-a]indolium, thienyl and phenyl) and vinyl moiety can make up a large conjugated system. Its UV-Vis and fluorescence spectra were measured, and found that it displays larger maximum absorptions and emission wavelengths in comparison with 8-(4-methylphenyl)vinyl analogue.

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Authors and Affiliations

  1. College of Chemistry and Material Science, Shandong Agricultural University, Tai’an, 271018, China

    Lin Jiang, Peng Cao, Yulei Zhang & Xiezhong Xie

  2. College of Water Conservancy and Civil Engineering, Shandong Agricultural University, Tai’an, China

    Yulei Zhang & Xiezhong Xie

Authors
  1. Lin Jiang
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  2. Peng Cao
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  3. Yulei Zhang
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  4. Xiezhong Xie
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Correspondence to Lin Jiang.

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Jiang, L., Cao, P., Zhang, Y. et al. Structure and spectral property of 8-(2-(5-(4-methylphenyl)-2-thienyl)vinyl)-10,10-dimethyl-10H-pyrido[1,2-a]indolium perchlorate. Res Chem Intermed 38, 2229–2235 (2012). https://doi.org/10.1007/s11164-012-0539-4

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  • DOI: https://doi.org/10.1007/s11164-012-0539-4

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