Abstract
Nanocellulose producing from wood pulp and its derivatives is a well-known and characterized industrial process. However, agro-industrial residues can also be used for this process as they have a high content of lignocellulosic portions, particularly cellulose. Usually discarded or used as animal feed their composition pose a great potential for the generation of value added products. As an alternative to wood pulp, cellulose from residues represent a great source for obtaining nanocellulose due to its wide availability and low cost. Given that many other studies have focused on generating nanocellulose out of wood pulp due to its intrinsic characteristics, such as high aspect ratio, biodegradability, and good overall mechanical properties, it was decided to characterize the processing of agro-industrial residues on last decade in this review as their composition greatly varies among plant sources, presenting influence on produced nanocrystals quality. The intrinsic properties of nanocellulose justify its utilization in many applications, including use in food, cosmetic, and material industry. This review attempts to follow through the state-of-art for crystalline nanocellulose preparation, presenting its current concerns in process and commercial viability, and finally, indicating some future perspectives on using agro-industrial residues as an environmentally-friendly alternative to wood sources.
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Abraham E, Deepa B, Pothan LA, Jacob M, Thomas S, Cvelbar U, Anandjiwala R (2011) Extraction of nanocellulose fibrils from lignocellulosic fibres: a novel approach. Carbohydr Polym 86:1468–1475. doi:10.1016/j.carbpol.2011.06.034
Acharya SK, Mishra P, Mehar SK (2011) Effect of surface treatment on the mechanical on the mechanical properties of bagasse fiber reinforced polymer composite. Bioresource 6:3155–3165. doi:10.1177/0021998302036008180
Alemdar A, Sain M (2008) Isolation and characterization of nanofibers from agricultural residues: wheat straw and soy hulls. Bioresour Technol 99:1664–1671. doi:10.1016/j.biortech.2007.04.029
Azelee WNI, Jahim JM, Rabu A, Murad AMA, Bakar FDA, Illias RM (2014) Efficient removal of lignin with the maintenance of hemicellulose from kenaf by two-stage pretreatment process. Carbohydr Polym 99:447–453. doi:10.1016/j.carbpol.2013.08.043
Beck S, Bouchard J, Berry R (2010) Controlling the reflection wavelength of iridescent solid films of nanocrystalline cellulose. Biomacromolecules 12:167–172. doi:10.1021/bm1010905
Belbekhouche S, Bras J, Siqueira G, Chappey C, Lebrun L, Khelifi B, Marais S, Dufresne A (2011) Water sorption behavior and gas barrier properties of cellulose whiskers and microfibrils films. Carbohydr Polym 83:1740–1748. doi:10.1016/j.carbpol.2010.10.036
Berthet MA, Angellier-Coussy H, Machado D, Hilliou L, Staebler A, Vicente A, Gontard N (2015) Exploring the potentialities of using lignocellulosic fibres derived from three food by-products as constituents of biocomposites for food packaging. Ind Crop Prod 69:110–122. doi:10.1016/j.indcrop.2015.01.028
Besbes I, Vilar MR, Boufi S (2011) Nanofibrillated cellulose from Alfa, Eucalyptus and Pine fibres: preparation, characteristics and reinforcing potential. Carbohydr Polym 86:1198–1206. doi:10.1016/j.carbpol.2011.06.015
Brito BS, Pereira FV, Putaux JL, Jean B (2012) Preparation, morphology and structure of cellulose nanocrystals from bamboo fibers. Cellulose 19:1527–1536. doi:10.1007/s10570-012-9738-9
Cao Y, Zhang R, Cheng T, Guo J, Xian M, Liu H (2017) Imidazolium-based ionic liquids for cellulose pretreatment: recent progresses and future perspectives. Appl Microbiol Biotechnol 101:521–532. doi:10.1007/s00253-016-8057-8
Casas-Orozco D, Villa AL, Bustamante F, González L (2015) Process development and simulation of pectin extraction from orange peels. Food Bioprod Process 96:86–98. doi:10.1016/j.fbp.2015.06.006
Cengiz M, Dinctur OD, Sahin HT (2010) Fractional extraction and structural characterization of opium poppy and cotton stalks hemicelluloses. Pharmacogn Mag 6:315. doi:10.4103/0973-1296.71798
Chen W, Yu H, Liu Y, Chen P, Zhang M, Hai Y (2011a) Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments. Carbohydr Polym 83:1804–1811. doi:10.1016/j.carbpol.2010.10.040
Chen W, Yu H, Liu Y, Hai Y, Zhang M, Chen P (2011b) Isolation and characterization of cellulose nanofibers from four plant cellulose fibers using a chemical-ultrasonic process. Cellulose 18:433–442. doi:10.1007/s10570-011-9497-z
Chen D, Lawton D, Thompson MR, Liu Q (2012) Biocomposites reinforced with cellulose nanocrystals derived from potato peel waste. Carbohydr Polym 90:709–716. doi:10.1016/j.carbpol.2012.06.002
Chen L, Wang Q, Hirth K, Baez C, Agarwal UP, Zhu JY (2015) Tailoring the yield and characteristics of wood cellulose nanocrystals (CNC) using concentrated acid hydrolysis. Cellulose 22:1753–1762. doi:10.1007/s10570-015-0615-1
Chen L, Zhu JY, Baez C, Kitin P, Elder T (2016) Highly thermal-stable and functional cellulose nanocrystals and nanofibrils produced using fully recyclable organic acids. Green Chem 18:3835–3843. doi:10.1039/C6GC00687F
Cherian BM, Leão AL, Souza SF, Thomas S, Pothan LA, Kottaisamy M (2010) Isolation of nanocellulose from pineapple leaf fibres by steam explosion. Carbohydr Polym 81:720–725. doi:10.1016/j.carbpol.2010.03.046
Chirayil CJ, Mathew L, Thomas S (2014) Review of recent research in nano cellulose preparation from different lignocellulosic fibers. Rev Adv Mat Sci 37:20–28
Cudjoe E, Hunsen M, Xue Z, Way AE, Barrios E, Olson RA, Hore MJA, Rowan SJ (2017) Miscanthus Giganteus: a commercially viable sustainable source of cellulose nanocrystals. Carbohydr Polym 155:230–241. doi:10.1016/j.carbpol.2016.08.049
Cui S, Zhang S, Ge S, Xiong L, Sun Q (2016) Green preparation and characterization of size-controlled nanocrystalline cellulose via ultrasonic-assisted enzymatic hydrolysis. Ind Crop Prod 83:346–352. doi:10.1016/j.indcrop.2016.01.019
Dai D, Fan M, Collins P (2013) Fabrication of nanocelluloses from hemp fibers and their application for the reinforcement of hemp fibers. Ind Crops Prod 44:192–199. doi:10.1016/j.indcrop.2012.11.010
Deepa B, Abraham E, Cherian BM, Bismarck A, Blacker JJ, Pothan LA, Leao AL, Souza SF, Kottaisamy M (2011) Structure, morphology and thermal characteristics of banana nano fibers obtained by steam explosion. Bioresour Technol 102:1988–1997. doi:10.1016/j.biortech.2010.09.030
Dufresne A (2010) Processing of Polymer nanocomposites reinforced with polysaccharide nanocrystals. Molecules 15:4111–4128. doi:10.3390/molecules15064111
Elanthikkal S, Gopalakrishnapanicker U, Varghese S, Guthrie JT (2009) Cellulose microfibres produced from banana plant wastes: isolation and characterization. Carbohydr Polym 80:852–859. doi:10.1016/j.carbpol.2009.12.043
Espino-Pérez E, Bras J, Ducruet V, Guinault A, Dufresne A, Domenek S (2013) Influence of chemical surface modification of cellulose nanowhiskers on thermal, mechanical, and barrier properties of poly(lactide) based bionanocomposites. Euro Pol J 49:3144–3154. doi:10.1016/j.eurPolymj.2013.07.017
Floros M, Hojabri L, Abraham E, Jose J, Thomas S, Pothan L, Leao AL, Narime S (2012) Enhancement of thermal stability, strength and extensibility of lipid-based polyurethanes with cellulose-based nanofibers. Polym Degrad Stab 97:1970–1978. doi:10.1016/j.Polymdegradstab.2012.02.016
Gao X, Shi Z, Liu C, Yang G, Sevostianov I, Silberschmidt VV (2015) Inelastic behaviour of bacterial cellulose hydrogel: in aqua cyclic tests. Polym Test 44:82–92. doi:10.1016/j.Polymertesting.2015.03.021
García A, Gandini A, Labidi J, Belgacem N, Bras J (2016) Industrial and crop wastes: a new source for nanocellulose biorefinery. Ind Crop Prod 93:26–38. doi:10.1016/j.indcrop.2016.06.004
Haafiz MKM, Hassan A, Zakaria Z (2014) Inuwa IM (2014) Isolation and characterization of cellulose nanowhiskers from oil palm biomass microcrystalline cellulose. Carbohydr Polym 103:119–125. doi:10.1016/j.carbpol.2013.11.055
Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500. doi:10.1021/cr900339w
Hamid SBA, Zain SK, Das R, Centi G (2016) Synergic effect of tungstophosphoric acid and sonication for rapid synthesis of crystalline nanocellulose. Carbohydr Polym 138:349–355. doi:10.1016/j.carbpol.2015.10.023
Henrique MA, Silvério HA, Neto WPF, Pasquini D (2013) Valorization of an agro-industrial waste, mango seed, by the extraction and characterization of its cellulose nanocrystals. J Environ Manag 121:202–209. doi:10.1016/j.jenvman.2013.02.054
Hodzic A, Shanks R (2014) Natural fibre composites: materials, processes and properties. Woodhead Publishing, Philadelphia
Jabbar A, Militký J, Wiener J, Kale BM, Ali U, Rwawiire S (2017) Nanocellulose coated woven jute/green epoxy composites: characterization of mechanical and dynamic mechanical behavior. Compos Struct 161:340–349. doi:10.1016/j.compstruct.2016.11.062
Jiang F, Hsieh YL (2015) Cellulose nanocrystal isolation from tomato peels and assembled nanofibers. Carbohydr Polym 122:60–68. doi:10.1016/j.carbpol.2014.12.064
Johar N, Ahmad I, Dufresne A (2012) Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Ind Crops Prod 37:93–99. doi:10.1016/j.indcrop.2011.12.016
Jonoobi M, Harun J, Shakeri A, Misra M, Oksman K (2009) Chemical composition, crystallinity, and thermal degradation of bleached and unbleached kenaf bast (Hibiscus cannabinus) pulp and nanofibers. Bioresources 4:626–639
Kallel F, Bettaieb F, Khiari R, García A, Bras J, Chaabouni SE (2016) Isolation and structural characterization of cellulose nanocrystals extracted from garlic straw residues. Ind Crop Prod 87:287–296. doi:10.1016/j.indcrop.2016.04.060
Karimi S, Tahir PM, Karimi A, Dufresne A, Abdulkhani A (2014) Kenaf bast cellulosic fibers hierarchy: a comprehensive approach from micro to nano. Carbohydr Polym 101:878–885. doi:10.1016/j.carbpol.2013.09.106
Khajavi R, Esfahani EJ, Sattari M (2011) Crystalline structure of microbial cellulose compared with native and regenerated cellulose. Int J Polym Mater 60:1178–1192. doi:10.1080/00914037.2010.551372
Kiziltas EE, Kiziltas A, Gardner DJ (2015) Synthesis of bacterial cellulose using hot water extracted wood sugars. Carbohydr Polym 124:131–138. doi:10.1016/j.carbpol.2015.01.036
Lamaming J, Hashim R, Sulaiman O, Leh CP, Sugimoto T, Nordin NA (2015) Cellulose nanocrystals isolated from oil palm trunk. Carbohydr Polym 127:202–208. doi:10.1016/j.carbpol.2015.03.043
Lamaming J, Hashim R, Leh CP, Sulaiman O (2017) Properties of cellulose nanocrystals from oil palm trunk isolated by total chlorine free method. Carbohydr Polym 156:409–416. doi:10.1016/j.carbpol.2016.09.053
Li J, Wei X, Wang Q, Chen J, Chang G, Kong L, Su J, Liu Y (2012) Homogeneous isolation of nanocellulose from sugarcane bagasse by high pressure homogenization. Carbohydr Polym 90:1609–1613. doi:10.1016/j.carbpol.2012.07.038
Liang T, Wang L (2015) An environmentally safe and nondestructive process for bleaching birch veneer with peracetic acid. J Clean Prod 92:37–43. doi:10.1016/j.jclepro.2014.12.087
Lu P, Hsieh YL (2010) Preparation and properties of cellulose nanocrystals: rods, spheres, and network. Carbohydr Polym 82:329–336. doi:10.1016/j.carbpol.2010.04.073
Lu P, Hsieh YL (2012) Cellulose isolation and core–shell nanostructures of cellulose nanocrystals from chardonnay grape skins. Carbohydr Polym 87:2546–2553. doi:10.1016/j.carbpol.2011.11.023
Lu H, Gui Y, Zheng L, Liu X (2013) Morphological, crystalline, thermal and physicochemical properties of cellulose nanocrystals obtained from sweet potato residue. Food Res Int 50:121–128. doi:10.1016/j.foodres.2012.10.013
Lu Q, Tan L, Lin F, Wang S, Chen Y, Chen X, Huang B (2014) Preparation and characterization of cellulose nanocrystals via ultrasonication-assisted FeCl3-catalyzed hydrolysis. Cellulose 21:3497–3506. doi:10.1007/s10570-014-0376-2
Ludueña L, Fasce D, Alvarez VA, Stefani PM (2011) Nanocellulose from rice husk following alkaline treatment to remove silica. Bioresource 6:1440–1453
Mandal A, Chakrabarty D (2011) Isolation of nanocellulose from waste sugarcane bagasse (SCB) and its characterization. Carbohydr Polym 86:1291–1299. doi:10.1016/j.carbpol.2011.06.030
Mesquita JP, Donnici CL, Teixeira IF, Pereira FV (2012) Bio-based nanocomposites obtained through covalent linkage between chitosan and cellulose nanocrystals. Carbohydr Polym 90:210–217. doi:10.1016/j.carbpol.2012.05.025
Minelli M, Baschetti MG, Doghieri F, Ankerfors M, Lindström T, Siró I, Plackett D (2010) Investigation of mass transport properties of microfibrillated cellulose (MFC) films. J Membr Sci 358:67–75. doi:10.1016/j.memsci.2010.04.030
Mohammadkazemi F, Azin M, Ashori A (2014) Production of bacterial cellulose using different carbon sources and culture media. Carbohydr Polym 205:518–523. doi:10.1016/j.carbpol.2014.10.008
Morais JPS, Rosa MDF, De Souza Filho MDSM, Nascimento LD, Nascimento DM, Cassales AR (2013) Extraction and characterization of nanocellulose structures from raw cotton linter. Carbohydr Polym 91:229–235. doi:10.1016/j.carbpol.2012.08.010
Moriana R, Vilaplana F, Ek M (2016) Cellulose nanocrystals from forest residues as reinforcing agents for composites: a study from macro-to nano-dimensions. Carbohydr Polym 139:139–149. doi:10.1016/j.carbpol.2015.12.020
Nascimento DM, Almeida JS, Vale MDS, Leitão RC, Muniz CR, de Figueirêdo MCB, Morais JPS, Rosa MDF (2016) A comprehensive approach for obtaining cellulose nanocrystal from coconut fiber. Part I: proposition of technological pathways. Ind Crop Prod 93:66–75. doi:10.1016/j.indcrop.2015.12.078
Neto WPF, Silvério HA, Dantas NO, Pasquini D (2013) Extraction and characterization of cellulose nanocrystals from agro-industrial residue: Soy hulls. Ind Crops Prod 42:480–488. doi:10.1016/j.indcrop.2012.06.041
Oliveira FB, Bras J, Pimenta MTB, da Silva Curvelo AA, Belgacem MN (2016) Production of cellulose nanocrystals from sugarcane bagasse fibers and pith. Ind Crop Prod 93:48–57. doi:10.1016/j.indcrop.2016.04.064
Pal N, Dubey P, Gopinath P, Pal K (2017) Combined effect of cellulose nanocrystal and reduced graphene oxide into poly-lactic acid matrix nanocomposite as a scaffold and its anti-bacterial activity. Int J Biol Macromol 95:94–105. doi:10.1016/j.ijbiomac.2016.11.041
Pasquini D, Teixeira EDM, Curvelo AADS, Belgacem MN, Dufresne A (2010) Extraction of cellulose whiskers from cassava bagasse and their applications as reinforcing agent in natural rubber. Ind Crops Prod 32:486–490. doi:10.1016/j.indcrop.2010.06.022
Peng Y, Gardner DJ, Han Y (2012) Drying cellulose nanofibrils: in search of a suitable method. Cellulose 19:91–102. doi:10.1007/s10570-011-9630-z
Peng Y, Gardner DJ, Han Y, Kiziltas A, Cai Z, Tshabalala MA (2013) Influence of drying method on the material properties of nanocellulose I: thermostability and crystallinity. Cellulose 20:2379–2392. doi:10.1007/s10570-013-0019-z
Rambabu N, Panthapulakkal S, Sain M, Dalai AK (2016) Production of nanocellulose fibers from pinecone biomass: evaluation and optimization of chemical and mechanical treatment conditions on mechanical properties of nanocellulose films. Ind Crop Prod 83:746–754. doi:10.1016/j.indcrop.2015.11.083
Rånby BG, Ribi ED (1950) Uber den Feinbau Zellulose. Experientia 1:12–14
Razera IAT, Frollini E (2004) Composites based on jute fibers and phenolic matrices: properties of fibers and composites. J Appl Polym Sci 91:1077–1085. doi:10.1002/app.13224
Rebouillat S, Pla F (2013) State of the art manufacturing and engineering of nanocellulose: a review of available data and industrial applications. J Biomater Nanobiotechnol 04:165–188. doi:10.4236/jbnb.2013.42022
Rehman N, Miranda MIG, Rosa SM, Pimentel DM, Nachtigall SM, Bica CI (2014) Cellulose and nanocellulose from maize straw: an insight on the crystal properties. J Polym Environ 22:252–259. doi:10.1007/s10924-013-0624-9
Roman M, Winter WT (2004) Effect of sulfate groups from sulfuric acid hydrolysis on the thermal degradation behavior of bacterial cellulose. Biomacromolecules 5:1671–1677. doi:10.1021/bm034519
Rosa MF, Medeiros ES, Malmonge JA, Gregorski KS, Wood DF, Mattoso LHC, Glenn G, Orts WJ, Iman SH (2010) Cellulose nanowhiskers from coconut husk fibers: effect of preparation conditions on their thermal and morphological behavior. Carbohydr Polym 81:83–92. doi:10.1016/j.carbpol.2010.01.059
Rosli NA, Ahmad I, Abdullah I (2013) Isolation and characterization of cellulose nanocrystals from Agave angustifolia fibre. Bioresource 8:1893–1908
Santos RM, Neto WPF, Silvério HA, Martins DF, Dantas NO, Pasquini D (2013) Cellulose nanocrystals from pineapple leaf, a new approach for the reuse of this agro-waste. Ind Crop Prod 50:707–714. doi:10.1016/j.indcrop.2013.08.049
Savadekar NR, Mhaske ST (2012) Synthesis of nano cellulose fibers and effect on thermoplastics starch based films. Carbohydr Polym 89:146–151. doi:10.1016/j.carbpol.2012.02.063
Sehaqui H, Allais M, Zhou Q, Berglund LA (2011) Wood cellulose biocomposites with fibrous structures at micro- and nanoscale. Compos Sci Technol 71:382–387. doi:10.1016/j.compscitech.2010.12.007
Shen D, Zhang L, Xue J, Guan S, Liu Q, Xiao R (2015) Thermal degradation of xylan-based hemicellulose under oxidative atmosphere. Carbohydr Polym 127:363–371. doi:10.1016/j.carbpol.2015.03.067
Sheykhnazari S, Tabarsa T, Ashori A, Shakeri A, Golalipour M (2011) Bacterial synthesized cellulose nanofibers; Effects of growth times and culture mediums on the structural characteristics. Carbohydr Polym 86:1187–1191. doi:10.1016/j.carbpol.2011.06.011
Silvério HA, Flauzino Neto WP, Dantas NO, Pasquini D (2013) Extraction and characterization of cellulose nanocrystals from corncob for application as reinforcing agent in nanocomposites. Ind Crops Prod 44:427–436. doi:10.1016/j.indcrop.2012.10.014
Siqueira G, Abdillahi H, Bras J, Dufresne A (2010a) High reinforcing capability cellulose nanocrystals extracted from Syngonanthus nitens (Capim Dourado). Cellulose 17:289–298. doi:10.1007/s10570-009-9384-z
Siqueira G, Bras J, Dufresne A (2010b) Cellulosic bionanocomposites: a review of preparation, properties and applications. Polymers 2:728–765. doi:10.3390/polym2040728
Siqueira G, Bras J, Dufresne A (2010c) Luffa cylindrica as a lignocellulosic source of fiber, microfibrillated cellulose and cellulose nanocrystals. Bioresource 5:727–740
Siqueira G, Tapin-Lingua S, Bras J, Perez DS, Dufresne A (2010d) Morphological investigation of nanoparticles obtained from combined mechanical shearing, and enzymatic and acid hydrolysis of sisal fibers. Cellulose 17:1147–1158. doi:10.1007/s10570-010-9449-z
Sonia A, Dasan KP (2013) Chemical, morphology and thermal evaluation of cellulose microfibers obtained from Hibiscus sabdariffa. Carbohydr Polym 92:668–674. doi:10.1016/j.carbpol.2012.09.015
Sun RC (2010) Cereal straw and a resource for sustainable biomaterials and biofuels: chemistry, extractives, lignins, hemicelluloses and cellulose. Elsevier BV, Amsterdam
Sun JX, Sun XF, Zhao H, Sun RC (2004) Isolation and characterization of cellulose from sugarcane bagasse. Polym Degrad Stab 84:331–339. doi:10.1016/j.Polymdegradstab.2004.02.008
Sundari MT, Ramesh A (2012) Isolation and characterization of cellulose nanofibers from the aquatic weed water hyacinth—Eichhornia crassipes. Carbohydr Polym 87:1701–1705. doi:10.1016/j.carbpol.2011.09.076
Swain SK, Dash S, Behera C, Kisku SK, Behera L (2013) Cellulose nanobiocomposites with reinforcement of boron nitride: study of thermal, oxygen barrier and chemical resistant properties. Carbohydr Polym 95:728–732. doi:10.1016/j.carbpol.2013.02.080
Tang Y, Shen X, Zhang J, Guo D, Kong F, Zhang N (2015) Extraction of cellulose nano-crystals from old corrugated container fiber using phosphoric acid and enzymatic hydrolysis followed by sonication. Carbohydr Polym 125:360–366. doi:10.1016/j.carbpol.2015.02.063
USDOE—US Department of Energy, Office of Science (2016) Genomics: GTL roadmap. http://genomicsgtl.energy.gov.sci-hub.cc/roadmap/. Accessed 1 Feb 2016
Wang Q, Zhao X, Zhu JY (2014a) Kinetics of strong acid hydrolysis of a bleached kraft pulp for producing cellulose nanocrystals (CNCs). Ind Eng Chem Res 53:11007–11014. doi:10.1021/ie501672m
Wang X, Chen Q, Lü X (2014b) Pectin extracted from apple pomace and citrus peel by subcritical water. Food Hydrocol 38:129–137. doi:10.1016/j.foodhyd.2013.12.003
Wang S, Ru B, Dai G, Sun W, Qiu K, Zhou J (2015a) Pyrolysis mechanism study of minimally damaged hemicellulose polymers isolated from agricultural waste straw samples. Bioresour Technol 190:211–218. doi:10.1016/j.biortech.2015.04.098
Wang S, Ru B, Lin H, Sun W, Luo Z (2015b) Pyrolysis behaviors of four lignin polymers isolated from the same pine wood. Bioresour Technol 182:120–127. doi:10.1016/j.biortech.2015.01.127
Wang Z, Yao Z, Zhou J, Zhang Y (2016) Reuse of waste cotton cloth for the extraction of cellulose nanocrystals. Carbohydr Polym 157:945–952. doi:10.1016/j.carbpol.2016.10.044
Wong A, Zhang H, Kuma A (2016) Life cycle water footprint of hydrogenation-derived renewable diesel production from lignocellulosic biomass. Water Res 102:330–345. doi:10.1016/j.watres.2016.06.045
Wüstenberg T (2015) Cellulose and cellulose derivatives in the food industry. Wiley VCH, Weinheim
Yadav MP, Hicks KB (2015) Isolation of barley hulls and straw constituents and study of emulsifying properties of their arabinoxylans. Carbohydr Polym 132:529–536. doi:10.1016/j.carbpol.2015.06.049
Yin Y, Tian X, Jiang X, Wang H, Gao W (2016) Modification of cellulose nanocrystal via SI-ATRP of styrene and the mechanism of its reinforcement of polymethylmethacrylate. Carbohydr Polym 142:206–212. doi:10.1016/j.carbpol.2016.01.014
Zain NFM, Yusop SM, Ahmad I (2013) Cellulose nanocrystal from pomelo (C. grandis Osbeck) albedo: chemical, morphology and crystallinity evaluation. In: Abdul Murad AMH et al (ed) AIP conference proceedings—AIP, pp 674–679
Zainuddin N, Ahmad I, Kargarzadeh H, Ramli S (2017) Hydrophobic kenaf nanocrystalline cellulose for the binding of curcumin. Carbohydr Polym 163:261–269. doi:10.1016/j.carbpol.2017.01.036
Zimmermann T, Bordeanu N, Strub E (2010) Properties of nanofibrillated cellulose from different raw materials and its reinforcement potential. Carbohydr Polym 79:1086–1093. doi:10.1016/j.carbpol.2009.10.045
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Malucelli, L.C., Lacerda, L.G., Dziedzic, M. et al. Preparation, properties and future perspectives of nanocrystals from agro-industrial residues: a review of recent research. Rev Environ Sci Biotechnol 16, 131–145 (2017). https://doi.org/10.1007/s11157-017-9423-4
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DOI: https://doi.org/10.1007/s11157-017-9423-4