Abstract
The oxygen-doped porous carbon nitride (O-PCN) was prepared via calcinating oxalic acid and urea to activate peroxydisulfate (PS) for abatement of 17α-ethinylestradiol (EE2) under visible light. The results indicated that O-PCN possessed relatively higher specific area (50.48 m2 g−1), larger pore volume (0.168 cm3 g−1), larger average size (14.33 nm) and thinner layer compared to g-C3N4. This structure feather can utilize light more efficiently because more light can penetrate the pore of O-PCN reflect in the pores and reflect. Most importantly, O-PCN has quasi-full-visible-light response (790 nm) compared to pure g-C3N4 (480 nm), which can broaden utilization efficiency of visible light range. In PS/O-PCN/Vis system, 6 mg/L EE2 can be completely removed only within 20 min, and degradation rate constant of EE2 is 6.81 and 2.00 times than those in PS/g-C3N4/Vis and O-PCN/Vis systems. The h+ and ∙O2− are main contributors for EE2 abatement in the PS/O-PCN/Vis system. The effect of anion (Cl−, HCO3−, NO3− and SO42−) and typical natural organic matters (HA and FA) present in water matrixes on EE2 abatement in this system is explored, and the estrogenic activities of treated process is also evaluated by MCF-7 cell viability.
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Plahuta M, Tišler T, Toman MJ, Pintar A (2017) Chemosphere 174:342–353
Manickum T, John W (2014) Sci Total Environ 468:584–597
Guo W, Li J, Luo M, Mao Y, Yu X, Elskens M, Baeyens W, Gao Y (2022) Water Res 214:118189–118200
Chen G, Yu Y, Liang L, Duan X, Li R, Lu X, Yan B, Li N, Wang S (2021) J Hazard Mater 408:124461–124476
Hasija V, Nguyen VH, Kumar A, Raizada P, Krishnan V, Khan AAP, Singh P, Lichtfouse E, Wang C, Thi Huong P (2021) J Hazard Mater 413:125324–125336
Liu B, Qiao M, Wang Y, Wang L, Gong Y, Guo T, Zhao X (2017) Chemosphere 189:115–122
Patnaik S, Sahoo DP, Parida K (2021) Carbon 172:682–711
Sun H, Guo F, Pan J, Huang W, Wang K, Shi W (2021) Chem Eng J 406:12684–12695
Sher M, Javed M, Shahid S, Hakami O, Qamar MA, Iqbal S (2021) Al-Anazy MM Baghdadi HB. J Photochem Photobiol A 418:113393–113405
Chang C, Fu Y, Hu M, Wang C, Shan G, Zhu L (2013) Appl Catal B 142–143:553–560
Sethuraman S, Marimuthu A, Kattamuthu R, Karuppasamy G (2021) Appl Surf Sci 561:150077–150093
Wang L, Guo X, Chen Y, Ai S, Ding H (2019) Appl Surf Sci 467–468:954–962
Wang Y, Zhao X, Cao D, Wang Y, Zhu Y (2017) Appl Catal B 211:79–88
Meng Y, Li Z, Tan J, Li J, Wu J, Zhang T, Wang X (2021) Chem Eng J 429:130860–130874
Lin KYA, Zhang ZY (2017) Chem Eng J 313:1320–1327
She S, Wang Y, Chen R, Yi F, Sun C, Hu J, Li Z, Lu G, Zhu M (2021) Chemosphere 266:128929–128939
Cui M, Cui K, Liu X, Chen X, Guo Z, Chen Y, Li CX (2021) J Hazard Mater 418:126338–126345
Tang Q, An X, Zhou J, Lan H, Liu H, Qu J (2020) J Colloid Interface Sci 579:455–462
Qiu P, Xu C, Chen H, Jiang F, Wang X, Lu R, Zhang X (2017) Appl Catal B 206:319–327
Yang Y, Luo L, Xiao M, Li H, Pan X, Jiang F (2015) Mater Sci Semicond Process 40:183–193
Luo L, Meng D, He L, Wang X, Xia L, Pan X, Jiang F, Wang H, Dai J (2022) Chem Eng J 446:137325–137342
Dong F, Zhao Z, Xiong T, Ni Z, Zhang W, Sun Y, Ho WK (2013) ACS Appl Mater Interfaces 5:11392–11401
Zhang S, Liu Y, Gu P, Ma R, Wen T, Zhao G, Li L, Ai Y, Hu C, Wang X (2019) Appl Catal B 248:1–10
Lente G (2018) Curr Opin Cheml Eng 21:76–83
Deng Y, Zhou Z, Zeng H, Tang R, Li L, Wang J, Feng C, Gong D, Tang L, Huang Y (2023) Appl Catal B 320:121942–121957
Khataee A, Arefi-Oskoui S, Fathinia M, Esmaeili A, Hanifehpour Y, Joo SW, Hamnabard N (2015) J Mol Catal A 398:255–267
Negishi N, Miyazaki Y, Kato S, Yang Y (2019) Appl Catal B 242:449–459
Gao B, Yap PS, Lim TM, Lim TT (2011) Chem Eng J 171:1098–1107
Rebert AB, John CC, David WH (1999) J Environ Eng 1:77–86
Shi W, Hao C, Fu Y, Guo F, Tang Y, Yan X (2022) Chem Eng J 433:133741–133753
Wang KH, Hsieh YH, Wu CH, Chang CY (2000) Chemosphere 40:389–394
Liu X, Wang J, Wu D, Wang Z, Li Y, Fan X, Zhang F, Zhang G, Peng W (2022) Appl Catal B 310:121304–121312
Oh WD, Dong Z, Lim TT (2016) Appl Catal B 194:169–201
Tang Q, An X, Lan H, Liu H, Qu J (2019) Appl Catal B 268:118394–118402
Song Y, Huang L, Zhang X, Zhang H, Wang L, Zhang H, Liu Y (2020) J Hazard Mater 393:122379–122386
Dai H, He H, Lai C, Xu Z, Zheng X, Yu G, Huang B, Pan X, Dionysiou DD (2021) Water Res 190:116740–116750
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This work was supported by the National Natural Science Foundation of China (No. 22266036, 21767030 and 22065036) and the Yunnan Provincial Department of Science and Technology (No. 202105AC160055 and 202201BF079001-013).
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Zuo, Yd., Xia, Lh., Luo, Lj. et al. 17α-Ethinylestradiol abatement by O-doped porous carbon nitride in the presence of peroxydisulfate. Reac Kinet Mech Cat 136, 1423–1435 (2023). https://doi.org/10.1007/s11144-023-02421-z
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DOI: https://doi.org/10.1007/s11144-023-02421-z