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Physical–chemical analysis and kinetics of the magnetic biocatalyst for 2,3,6,-trimethylphenol oxidation

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Abstract

In the paper, the synthesis of the magnetic biocatalyst based on immobilized peroxidase is described. This catalyst was tested in the reaction of 2,3,6,-trimethylphenol oxidation with the help of hydrogen peroxide to 2,3,5-trimethylhydrochinone (vitamin E intermediate). In the work, the method for magnetic nanoparticle synthesis was chosen. To characterize the synthesized biocatalyst physical–chemical analysis was carried out: transmission electron microscopy, FTIR spectroscopy, the study of magnetic characteristics with vibration magnetometer, X-ray photoelectron spectroscopy, low-temperature nitrogen adsorption. The optimum conditions for the process of 2,3,6,-trimethylphenol oxidation in the presence of magnetic biocatalyst (the substrate initial concentration, temperature, pH).

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Acknowledgements

The financial support was provided by the Russian Science Foundation (Grant No. 19-79-00134).

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Authors and Affiliations

  1. Department of Biotechnology and Chemistry, Tver State Technical University, 22 A. Nikitina St, Tver, Russia, 170026

    Olga Grebennikova, Aleksandrina Sulman, Valentina Matveeva & Ester Sulman

Authors
  1. Olga Grebennikova
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  2. Aleksandrina Sulman
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  3. Valentina Matveeva
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  4. Ester Sulman
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Correspondence to Olga Grebennikova.

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Grebennikova, O., Sulman, A., Matveeva, V. et al. Physical–chemical analysis and kinetics of the magnetic biocatalyst for 2,3,6,-trimethylphenol oxidation. Reac Kinet Mech Cat 130, 317–329 (2020). https://doi.org/10.1007/s11144-020-01762-3

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  • DOI: https://doi.org/10.1007/s11144-020-01762-3

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