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A genuine way to mimic the solar-light conditions in UV driven heterogeneous photocatalytic reactions

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Abstract

Reliable data on heterogeneous photocatalytic processes with colloidal titanium oxide obtained under well defined laboratory conditions and with direct implication to outdoor conditions are rather rare. Here we report a useful guide on how to balance between (and how to correlate) solely exterior experiments and precisely obtained laboratory data. If produced separately, and comparisons attempted, misleading conclusions might be drawn. For the sake of simplicity all tests are carried out with commercial titania catalyst samples, and with Acid Orange 7, as the quite common model reactant in such reactions.

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References

  1. Malato S, Fernandez-Ibanez P, Maldonado MI, Blanco J, Gernjak W (2004) Decontamination and disinfection of water by solar photocatalysis, recent overview and trends. Catal Today 49:1–14

    Google Scholar 

  2. Ikeda S, Sugiyama N, Murakami S, Kominami H, Kera Y, Noguchi H, Uosaki K, Torimoto T, Ohtani B (2003) Quantitative analysis of defective sites in titanium(IV) oxide photocatalyst powders. Phys Chem Chem Phys 5:778–783

    Article  CAS  Google Scholar 

  3. Wei X, Xie T, Xu D, Zhao Q, Pang S, Wang D (2008) A study of the dynamic properties of photo-induced charge carriers at nanoporous TiO2/conductive substrate interfaces by the transient photovoltage technique. Nanotechnol 19:1–6

    Google Scholar 

  4. Katoh R, Furube A, Yamanaka K, Morikawa T (2010) Charge separation and trapping in N-doped TiO2 photocatalysts, a time-resolved microwave conductivity study. J Phys Chem Lett 1:3261–3265

    Article  CAS  Google Scholar 

  5. Duncan WR, Prezhdo OV (2007) Theoretical studies of photoinduced electron transfer in dye-sensitized TiO2. Annu Rev Phys Chem 58:143–184

    Article  CAS  Google Scholar 

  6. Kment S, Kmentova H, Kluson P, Krysa J, Hubicka Z, Cirkva V, Gregora I (2010) Notes on the photo-induced characteristics of transition metal-doped and undoped titanium dioxide thin films. J Colloid Interface Sci 348:198–205

    Article  CAS  Google Scholar 

  7. Bosc F, Ayral A, Keller N, Keller V (2008) Mesostructured anatase TiO2 for visible light and UV photocatalysis with confinement effect and semiconductor coupling. J Solar Energy Eng 130:1–5

    Article  Google Scholar 

  8. Kavan L, Gratzel M, Gilbert SE, Klemenz C, Scheel HJ (1996) Electrochemical and photoelectrochemical investigation of single-crystal anatase. J Am Chem Soc 118:6716–6723

    Article  CAS  Google Scholar 

  9. Soutsas K, Karayannis V, Poulios I, Riga A, Ntampegliotis K, Spiliotis X, Papapolymerou G (2010) Decolorization and degradation of reactive azo dyes via heterogeneous photocatalytic processes. Desalination 250:345–350

    Article  CAS  Google Scholar 

  10. Zlamal M, Krysa J, Jirkovsky J (2009) Photocatalytic degradation of Acid Orange 7 on TiO2 films prepared from various powder catalyst. Catal Lett 133:160–166

    Article  CAS  Google Scholar 

  11. Mozia S, Morawski AW, Toyoda M, Inagaki M (2009) Application of anatase-phase TiO2 for decomposition of azo dyes in a photocatalytic membrane reactor. Desalination 241:97–105

    Article  CAS  Google Scholar 

  12. Konstantinou IK, Albanis TA (2004) TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution, kinetic and mechanistic investigations. Appl Catal B 49:1–14

    Article  CAS  Google Scholar 

  13. Zita J, Krysa J, Mills A (2009) Correlation of oxidative and reductive dye bleaching on TiO2 photocatalyst films. J Photochem Photobiol A 203:119–124

    Article  CAS  Google Scholar 

  14. Chen F, Xie Y, Zhao J, Lu G (2001) Photocatalytic degradation of dyes on a magnetically separated photocatalyst under visible and UV irradiation. Chemosphere 44:1159–1168

    Article  CAS  Google Scholar 

  15. Goncalves MST, Oliveira-Campos AMF, Pinto EMMS, Plasencia PMS, Queiroz MJRP (1999) Photochemical treatment of solutions of azo dyes containing TiO2. Chemosphere 39:781–786

    Article  CAS  Google Scholar 

  16. Tanaka K, Padermpole K, Hisanaga T (1999) Photocatalytic degradation of commercial azo dyes. Water Res 34:327–333

    Article  Google Scholar 

  17. Xiang Q, Yu J, Wong PK (2011) Quantitative characterization of hydroxyl radicals produced by various photocatalysts. J Colloid Interface Sci 357:163–167

    Article  CAS  Google Scholar 

  18. Ohtani B (2008) Preparing articles on photocatalysis–beyond the illusions, misconceptions, and speculation. Chem Lett 37:216–229

    Article  Google Scholar 

  19. Ohtani B, Mahaney OOP, Amano F, Murakami N, Abe R (2010) What are titania photocatalysts?–an exploratory correlation of photocatalytic activity with structural and physical properties. J Adv Oxid Technol 13:247–261

    CAS  Google Scholar 

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Acknowledgments

The authors wish to acknowledge the project Recheba FR-TI1/065 funded by Ministry of Industry and Trade of the Czech Republic. SH specifically thanks the Internal Grant Project of UJEP supporting the development of the Photochemical Research Centre.

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Correspondence to Peter Kluson.

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Kluson, P., Hejda, S., Hejdova, M. et al. A genuine way to mimic the solar-light conditions in UV driven heterogeneous photocatalytic reactions. Reac Kinet Mech Cat 104, 273–280 (2011). https://doi.org/10.1007/s11144-011-0358-4

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  • DOI: https://doi.org/10.1007/s11144-011-0358-4

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