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Liquid phase hydrogenation of naphthalene in the presence of CO over supported Ni catalyst

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Abstract

The liquid phase hydrogenation of naphthalene was performed in the presence of CO over a commercial Ni/SiO2-Al2O3 catalyst. Naphthalene was hydrogenated even in the presence of CO at elevated temperatures, accompanying the hydrogenation of CO. Two activation energy values were obtained for the naphthalene hydrogenation depending on the reaction temperature. FT-IR measurement of the adsorbed CO was also carried out. Hydrogenation of the adsorbed CO created sites active for naphthalene hydrogenation.

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Authors and Affiliations

  1. Graduate School of Science and Engineering, Saitama University, Shimo-okubo 255, Sakura-ku, Saitama City, 338-8570, Japan

    Hiroshi Sekine, Masaaki Ohshima, Hideki Kurokawa & Hiroshi Miura

Authors
  1. Hiroshi Sekine
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  2. Masaaki Ohshima
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  3. Hideki Kurokawa
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  4. Hiroshi Miura
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Correspondence to Hiroshi Miura.

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Sekine, H., Ohshima, M., Kurokawa, H. et al. Liquid phase hydrogenation of naphthalene in the presence of CO over supported Ni catalyst. React Kinet Catal Lett 95, 99–105 (2008). https://doi.org/10.1007/s11144-008-5295-5

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  • DOI: https://doi.org/10.1007/s11144-008-5295-5

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