Skip to main content
Log in

A Comparison of Crystalline Silicotitanate and Ammonium Molybdophosphate-Polyacrylonitrile Composite Sorbent for the Separation of Cesium from Acidic Waste

  • Published:
Radiochemistry Aims and scope

Abstract

Crystalline silicotitanate manufactured and marketed by UOP as IONSIV IE-911 and an ammonium molybdophosphate-polyacrylonitrile (AMP-PAN) composite sorbent have been evaluated for the removal of cesium from Idaho National Engineering and Environmental Laboratory (INEEL) concentrated acidic tank waste. Equilibrium isotherms were generated with simulated concentrated tank waste solutions and fit to the Langmuir equation. Nonequilibrium sorption was evaluated in column tests employing 1.5 cm3 columns operating at 5, 10 and 20 bed volumes of flow per hour. Results of the equilibrium and nonequilibrium testing for both sorbents are compared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Todd, T.A., Brewer, K.N., Wood, D.J., et al., Sep. Sci. Technol., 2001, vol. 36, nos.5–6, pp. 999–1016.

    Article  Google Scholar 

  2. Mann, N.R. and Todd, T.A., Sep. Sci. Technol., 2004, vol. 39, no.10, pp. 2351–2371.

    Article  Google Scholar 

  3. Tranter, T.J., Tillotson, R.D., and Todd, T.A., Sep. Sci. Technol. (in press).

  4. Todd, T.A., Mann, N.R., Tranter, T.J., et al., J. Radioanal. Nucl. Chem., 2002, vol. 254, no.1, pp. 47–52.

    Article  Google Scholar 

  5. Tranter, T.J., Herbst, R.S., and Todd, T.A., Adsorption, 2002, vol. 8, pp. 291–299.

    Article  Google Scholar 

  6. Tranter, T.J., Herbst, R.S., Todd, T.A., et al., Adv. Environ. Res., 2002, vol. 6, pp. 107–121.

    Article  Google Scholar 

  7. Anthony, R.G., Dosch, R.G., Gu, D., and Philip, C.V., Ind. Eng. Chem. Res., 1994, vol. 33, pp. 2702–2705.

    Article  Google Scholar 

  8. Zheng, Z., Philip, C.V., Anthony, R.G., et al., Ind. Eng. Chem. Res., 1996, vol. 35, pp. 4246–4256.

    Article  Google Scholar 

  9. Smit, J. and Van, R., J. Nature, 1958, p. 1530.

  10. Buchwald, H. and Thistlethwaite, W.P., J. Inorg. Nucl. Chem., 1957, vol. 5, p. 341.

    Article  Google Scholar 

  11. Sebesta, F., J. Radioanal. Nucl. Chem., 1997, vol. 220, no.1, pp. 77–88.

    Article  Google Scholar 

  12. Sebesta, F., John, J., and Motl, A., Waste Treatment and Immobilization Technologies Involving Inorganic Sorbents, IAEA-TECDOC-947, June 1997.

  13. Sebesta, F., John, J., Motl, A., and Stamberg, K., Evaluation of Polyacrylonitrile (PAN) as a Binding Polymer for Absorbers Used to Treat Liquid Radioactive Wastes, SAND95-2729, Albuquerque, New Mexico (the United States): Sandia National Laboratories, 1995.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

From Radiokhimiya, Vol. 47, No. 4, 2005, pp. 364–367.

Original English Text Copyright © 2003 by Todd, Romanovskiy.

This article was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Todd, T.A., Romanovskiy, V.N. A Comparison of Crystalline Silicotitanate and Ammonium Molybdophosphate-Polyacrylonitrile Composite Sorbent for the Separation of Cesium from Acidic Waste. Radiochemistry 47, 398–402 (2005). https://doi.org/10.1007/s11137-005-0109-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11137-005-0109-3

Keywords

Navigation