Abstract
Mixed-ligand complexes of the type [M(SB)2acphen], where M = Mn(II), Co(II), Ni(II), Cu(II), and Cd(II), HSB = 3,5-dibromosalicylideneaniline, and acphen = bis(acetophenone)ethylenediamine, have been prepared and characterized on the basis of elemental analyses, magnetic measurements, thermogravimetry, and infrared and electronic absorption spectroscopy. All the mixed-ligand complexes exhibit an octahedral geometry. The mixed-ligand complexes show antimicrobial activities against bacteria, yeast, and fungi.
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References
D. R. Williams, Chem. Rev., 72(3), 203 (1972).
N. K. Singh, N. Singh, A. Sodhi, et al., Trans. Met. Chem., 21, 556 (1996).
D. E. Metzler, E. E. Snell, J. Am. Chem. Soc., 74, 979 (1952).
D. E. Metzler, M. Ikawa, E. E. Snell, J. Am. Chem. Soc., 76, 648 (1954).
N. H. Patel, H. M. Parekh, and M. N. Patel, Trans. Met. Chem., 30, 13 (2005).
H. M. Parekh, P. K. Panchal, and M. N. Patel, Khim.-Farm. Zh., 40(9), 32–35 (2006) [Pharm. Chem. J., 40(9), 494–497 (2006)].
A. I. Vogel, Titrimetric analysis, A Textbook of Quantitative Inorganic Analyses, Longman, Singapore (1989), Ch. 10, p. 257.
F. X. Webster and R. M. Silverstein, Infrared Spectroscopy, in: Spectrophotometric Identification of Organic Compounds, Wiley, New York (1998), Ch. 3, p. 87.
A. Syamal and O. P. Singhal, Synth. React. Inorg. Met.-Org. Chem., 16(6), 857 (1986), Chem. Abstr., 91, 101281b (1986).
V. J. Patel and M. N. Patel, Ind. J. Chem., 28A, 428 (1989); Chem. Abstr., 111, 40044j (1989).
H. H. Freedman, J. Am. Chem. Soc., 83, 2900 (1961); Chem. Abstr., 56, 1064i (1962).
H. L. McMurry and V. Thornton, Anal. Chem., 24, 318 (1951); Chem. Abstr., 45, 1422f (1951).
B. Singh and R. D. Singh, Ind. J. Chem., 21A, 648 (1982); Chem. Abstr., 98, 26790f (1983).
N. Saha and D. Bhattacharya, Ind. J. Chem., 21A, 574 (1982); Chem. Abstr., 98, 26786j (1983).
B. K. Patel and M. M. Patel, Ind. J. Chem., 29(1), 90 (1990); Chem. Abstr., 112, 199274b (1990).
Y. M. Ellis, S. R Vagg, and E. C. Watton, J. Inorg. Nucl. Chem., 36, 1031 (1974).
B. K. Saha and B. K. Mahapatra, J. Ind. Chem. Soc., 56, 825 (1979); Chem. Abstr., 92, 156998g (1980).
R. K. Agarwal, P. Garg, H. Agarwal, and S. Chandra, Synth. React. Inorg. Met.-Org. Chem., 27(2), 251 (1997).
L. Sacconi, M. Ciampolini, and U. Campigli, Inorg. Chem., 4(3), 407 (1965).
N. S. Bhave and R. B. Kharat, J. Ind. Chem. Soc., 58, 1194 (1981); Chem. Abstr., 96, 134838v (1982).
P. S. Patel, R. M. Ray, and M. M. Patel, Ind. J. Chem. Soc., 32, 597 (1993); Chem. Abstr., 119, 240317c (1993).
P. P. Dholakiya and M. N. Patel, Synth. React. Inorg. Met.-Org. Chem., 32(4), 819 (2002).
Y. Anjaneyulu and R. P. Rao, Synth. React. Inorg. Met.-Org. Chem., 16, 257 (1996).
B. G. Tweedy, Phytopathology, 55, 910 (1964).
N. Dharmaraj, P. Viswanathamurthi, and K. Natarajan, Trans. Met. Chem., 26, 105 (2001).
A. D. Damodaran, F. M. Tchaporia, and G. S. Rao, J. Ind. Chem. Soc., 45(8), 690 (1968); Chem. Abstr., 70, 23541m (1969).
N. R. Shah, J. Ind. Chem. Soc., 9, 851 (1981); Chem. Abstr., 96, 96527h (1982).
British Pharmacopoeia, Vol. 2, Her Majesty's Stationary Office London, A 122 (1980); British Pharmacopoeia, Pharmaceutical Press, London (1953), p. 796.
C. J. Alexopoulos and E. S. Beneke, Laboratory Manual for Introductory Mycology, Burgess Publishing Company, Mineapolis, MN (1962), p. 7.
R. Cruickshank, J. P. Dugnid, B. P. Murmium, and R. H. A. Swain, Medical Microbiology, Churchill, Edinburgh (1983), Vol. 2.
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Translated from Khimiko-Farmatsevticheskii Zhurnal, Vol. 41, No. 2, pp. 19–22, February, 2007.
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Patel, N.H., Parekh, H.M. & Patel, M.N. Synthesis, physicochemical characteristics, and biocidal activity of some transition metal mixed-ligand complexes with bidentate (NO and NN) Schiff bases. Pharm Chem J 41, 78–81 (2007). https://doi.org/10.1007/s11094-007-0017-2
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DOI: https://doi.org/10.1007/s11094-007-0017-2