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High-Temperature Corrosion Behavior of T92, TP347HFG and IN625 with Surface Scratching in Carbon Dioxide at 600 °C

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Abstract

The corrosion behavior of T92, TP347HFG and IN625 in high-temperature CO2 at 600 ℃ was investigated. Chromia-forming alloys TP347HFG and IN625 had better corrosion resistance than T92 because of insufficient Cr in T92 for forming Cr-rich oxide scales. More severe internal oxidation of T92 was found underneath the scratch due to the destroy of the Cr-rich oxide layer and the existence of Cr-depletion zone and induced plastic deformation by scratching. With the formation and growth of oxides at the surface of the scratch, the spallation of oxide scales may be caused by the compressive stress causing by scratching. Corrosion thermodynamic calculations were used to reveal the corrosion mechanism of T92, and the Cr–C–O phase diagrams were used to clarify the distribution of carbides.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (51806166) and China Postdoctoral Science Foundation (2020M683474, BX20190269).

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Authors and Affiliations

  1. Key Laboratory of Thermal Fluid Science and Engineering of MOE, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an, 710049, People’s Republic of China

    Tingshan Guo, Mengyao Wang, Zhiyuan Liang, Huaishuang Shao & Qinxin Zhao

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  1. Tingshan Guo
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  2. Mengyao Wang
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  4. Huaishuang Shao
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Correspondence to Zhiyuan Liang.

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Guo, T., Wang, M., Liang, Z. et al. High-Temperature Corrosion Behavior of T92, TP347HFG and IN625 with Surface Scratching in Carbon Dioxide at 600 °C. Oxid Met 97, 97–121 (2022). https://doi.org/10.1007/s11085-021-10078-z

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