Abstract
Single electron in spherical shell in infinite potential barrier is investigated. Schrödinger equation in effective mass approximation for this spherical heterosystem is solved to get eigenenergies and corresponding wave functions. In case of infinite potential barrier the ground state energy depends only on the shell width. Self-polarization potential is obtained by solving Poisson equation in three concentric spherical regions: core, shell and surrounding medium. Shell self-polarization energy depends on geometry (core and shell radius) and the dielectric mismatch at the quantum dot boundaries. Self-polarization energy is used as perturbation. One electron ground state energy results are presented in this paper. CdSe is placed in the shell. Surrounding medium is dielectric of smaller permittivity (vacuum or water), that is the most realistic case. The core dielectric permittivity influence on ground state energy is analysed. The self-polarization corrections to the ground state energy for different compositions, i.e. core and shell radius, are presented. For smaller core radius and the same shell thickness (which imply the same unperturbed ground state energy) bigger is the energy correction, i.e. perturbed energy state, for fixed value of the core dielectric permittivity. Increase of core dielectric permittivity produces decrease of energy correction.
Similar content being viewed by others
References
Boichuk, V.I., Bilynskyi, I.V., Leshko, R.Y.: Ground and excited states of D0 and D− donors in a spherical quantum dots. Ukr. J. Phys. 53, 991–996 (2008)
Chafai, A., Dujardin, F., Essaoudi, I., Ainane, A.: Energy spectrum of an exciton in a CdSe/ZnTe type-II core/shell spherical quantum dot. Superlattices Microstruct. 101, 40–48 (2017)
Cristea, M., Radu, A., Niculescu, E.C.: Electric field effect on the third-order nonlinear optical susceptibility in inverted core–shell nanodots with dielectric confinement. J. Lumin. 143, 592–599 (2013)
Fonoberov, V.A., Pokatilov, E.P., Balandin, A.A.: Exciton states and optical transitions in colloidal CdS quantum dots: Shape and dielectric mismatch effects. Phys. Rev. B 66, 085310 (2002)
Gheshaghi, N., Pisheh, H.S., Karim, M.R., Unlu, H.: Interface strain effects on ZnSe/(CdSe) based Type I and ZnSe/CdS Type II core/shell quantum dots. Energy Procedia 102, 152–163 (2016)
Ibral, A., Zouitine, A., Assaid, E.M., El Achouby, H., Feddi, E.M., Dujardin, F.: Polarization effects on spectra of spherical core/shell nanostructures: perturbation theory against finite difference approach. Physica B 458, 73–84 (2015)
Kostić, R., Stojanović, D.: Nonlinear absorption spectra for intersubband transition of CdSe/ZnS spherical quantum dots. J. Nanophotonic 5, 051810 (2011)
Niculescu, E.C.: Interlevel transition in core-shell nanodots with dielectric environment. Superlattices Microstruct. 51, 814–824 (2012)
Pu, C., Peng, X.: To battle surface traps on CdSe/CdS core/shell nanocrystals: shell isolation versus surface treatment. J. Am. Chem. Soc. 138, 8134–8142 (2016)
Sahin, M., Nizamoglu, S., Kavruk, A.E., Demir, H.V.: Self-consistent computation of electronic and optical properties of a single exciton in a spherical quantum dot via matrix diagonalization method. J. Appl. Phys. 106, 043704 (2009)
Schoss, D., Mews, A., Eychmuller, A., Weller, H.: Quantum-dot quantum well CdS/HgS/CdS: theory and experiment. Phys. Rev. B 49, 17072–17078 (1994)
Stojanović, D., Kostić, R.: Binding energy of D0 and D− impurity centers in CdTe/ZnTe spherical quantum dot. J. Nanosci. Nanotechnol. 12, 8715–8720 (2012)
Sukkabot, W.: Atomistic tight-binding computations of exitonic fine structure splitting in CdSe/ZnSe type-I and ZnSe/CdSe invert type-I core/shell nanocrystals. Mater. Sci. Semicond. Process. 47, 57–61 (2016)
Tyrrell, E.J., Tomić, S.: Effect of correlation and dielectric confinement on 1S (e)1/2 n 1S (h)3/2 excitons in CdTe/CdSe and CdSe/CdTe Type-II quantum dots. J. Phys. Chem. C 119, 12720–12730 (2015)
Acknowledgements
This work is supported by Serbian Ministry of Education and Science, under Projects No. III45003.
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is part of the Topical Collection on Focus on Optics and Bio-photonics, Photonica 2017.
Guest Edited by Jelena Radovanovic, Aleksandar Krmpot, Marina Lekic, Trevor Benson, Mauro Pereira, Marian Marciniak.
Rights and permissions
About this article
Cite this article
Stojanović, D., Kostić, R. Self-polarization effects in spherical inverted core–shell quantum dot. Opt Quant Electron 50, 174 (2018). https://doi.org/10.1007/s11082-018-1438-8
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11082-018-1438-8