Skip to main content
Log in

A facile TiO2/PVDF composite membrane synthesis and their application in water purification

  • Research Paper
  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

In this work, we have demonstrated a facile wet chemical method to synthesise TiO2/PVDF composite membranes as alternative water purification method to traditional polymer-based membrane. For the first time, hydrothermally grown TiO2 nanofibers under alkali conditions were successfully inserted into PVDF membranes matrix. The structure, permeability and anti-fouling performance of as-prepared PVDF/TiO2 composite membranes were studied systematically. The TiO2/PVDF composite membranes prepared in this work promise great potential uses in water purification applications as microfiltration membranes due to its excellent physical/chemical resistance, anti-fouling and mechanical properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Berney M, Vital M, Hülshoff I, Weilenmann HU, Egli T, Hammes F (2008) Rapid, cultivation-independent assessment of microbial viability in drinking water. Water Res 42:4010–4018

    Article  Google Scholar 

  • Buonomenna MG, Lopez LC, Favia P, Agostino R, Gordano A, Drioli E (2007) New PVDF membranes: the effect of plasma surface modification on retention in nanofiltration of aqueous solution containing organic compounds. Water Res 41:4309–4316

    Article  Google Scholar 

  • Calvo JI, Hernández A, Prádanos P, Martınez L, Bowen WR (1995) Pore size distributions in microporous membranes ii. Bulk characterization of track-etched filters by air porometry and mercury porosimetry. J Colloid Interface Sci 176:467–478

    Article  Google Scholar 

  • Campinas M, Rosa MJ (2010) Evaluation of cyanobacterial cells removal and lysis by ultrafiltration. Sep Purif Technol 70:345–353

    Article  Google Scholar 

  • Cao XC, Ma J, Shi XH, Ren ZJ (2006) Effect of TiO2 nanoparticle size on the performance of PVDF membrane. Appl Surf Sci 253:2003–2010

    Article  Google Scholar 

  • Chang Y, Ko CY, Shih YJ, Quémener D, Deratani A, Wei TC, Wang DM, Lai JY (2009) Surface grafting control of PEGylated poly(vinylidene fluoride) antifouling membrane via surface-initiated radical graft copolymerization. J Membr Sci 345:160–169

    Article  Google Scholar 

  • Chen X, Mao SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107:2891–2959

    Article  Google Scholar 

  • Chen W, Westerhoff P, Leenheer JA, Booksh K (2003) Fluorescence excitation–emission matrix regional integration to quantify spectra for dissolved organic matter. Environ Sci Technol 37:5701–5710

    Article  Google Scholar 

  • Chen WJ, Su YL, Peng JM, Zhao XT, Jiang ZY, Dong YN, Zhang Y, Liang YG, Liu JZ (2011) Efficient wastewater treatment by membranes through constructing tunable antifouling membrane surfaces. Environ Sci Technol 45:6545–6552

    Article  Google Scholar 

  • Damodar RA, You SJ, Chou HH (2009) Study the self cleaning, antibacterial and photocatalytic properties of TiO2 entrapped PVDF membranes. J Hazard Mater 172:1321–1328

    Article  Google Scholar 

  • Ebert K, Fritsch D, Koll J, Tjahjawiguna C (2004) Influence of inorganic fillers on the compaction behaviour of porous polymer based membranes. J Membr Sci 233:71–78

    Article  Google Scholar 

  • Hammes F, Goldschmidt F, Vital M, Wang Y, Egli T (2010) Measurement and interpretation of microbial adenosine tri-phosphate (ATP) in aquatic environments. Water Res 44:3915–3923

    Article  Google Scholar 

  • Henderson RK, Baker A, Murphy KR, Hambly A, Stuetz RM, Khan SJ (2009) Fluorescence as a potential monitoring tool for recycled water systems: a review. Water Res 43:863–881

    Article  Google Scholar 

  • Khulbe KC, Feng CY, Matsuura T (2010) Membrane characterization. Membrane processes. United Nations Educational, Scientific and Cultural Organization, pp 131–172

    Google Scholar 

  • Kim J, Bruggen BV (2010) The use of nanoparticles in polymeric and ceramic membrane structures: review of manufacturing procedures and performance improvement for water treatment. Environ Pollut 158:2335–2349

    Article  Google Scholar 

  • Li H, Xu YY, Zhu LP, Wang JH, Du CH (2009) Fabrication and characterization of a novel TiO2 nanoparticle self-assembly membrane with improved fouling resistance. J Membr Sci 326:659–666

    Article  Google Scholar 

  • Liu F, Hashim NA, Liu YT, Abed MRM, Li K (2011) Progress in the production and modification of PVDF membranes. J Membr Sci 375:1–27

    Article  Google Scholar 

  • Meng JQ, Chen CL, Huang LP, Du QY, Zhang YF (2011) Surface modification of PVDF membrane via AGET ATRP directly from the membrane surface. Appl Surf Sci 257:6282–6290

    Article  Google Scholar 

  • Mi B, Elimelech M (2008) Chemical and physical aspects of organic fouling of forward osmosis membranes. J Membr Sci 320:292–302

    Article  Google Scholar 

  • Peller JR, Whitman RL, Griffith S, Harris P, Peller C, Scalzitti J (2007) TiO2 as a photocatalyst for control of the aquatic invasive alga, Cladophora, under natural and artificial light. J Photochem Photobiol A 186:212–217

    Article  Google Scholar 

  • Rahimpour A, Madaeni SS, Zereshki S, Mansourpanah Y (2009) Preparation and characterization of modified nano porous PVDF membrane with high antifouling property using UV photo-grafting. Appl Surf Sci 255:7455–7461

    Article  Google Scholar 

  • Rahimpour A, Jahanshahi M, Rajaeian B, Rahimnejad M (2011) TiO2 entrapped nanocomposite PVDF/SPES membranes: preparation, characterization, antifouling and antibacterial properties. Desalination 278:343–353

    Article  Google Scholar 

  • Rana D, Matsuura T (2010) Surface modifications for antifouling membranes. Chem Rev 110:2448–2471

    Article  Google Scholar 

  • Reid K, Dixon M, Pelekani C, Jarvis K, Willis M, Yu Y (2014) Biofouling control by hydrophilic surface modification of polypropylene feed spacers by plasma polymerisation. Desalination 335:108–118

    Article  Google Scholar 

  • Rickman M, Pellegrino J, Davis R (2012) Fouling phenomena during membrane filtration of algae. J Membr Sci 423–424:33–42

    Article  Google Scholar 

  • Saadi I, Borisover M, Armon R, Laor Y (2006) Monitoring of effluent DOM biodegradation using fluorescence, UV and DOC measurements. Chemosphere 63:530–539

    Article  Google Scholar 

  • Van der Wielen PM, Van der Kooij D (2010) Effect of water composition, distance and season on the adenosine triphosphate concentration in unchlorinated drinking water in The Netherlands. Water Res 44:4860–4867

    Article  Google Scholar 

  • Wang Y, Foo SW, Chung TS (2009) Mixed matrix PVDF hollow fibre membranes with nanoscale pores for desalination through direct contact membrane distillation. Ind Eng Chem Res 48:4474–4483

    Article  Google Scholar 

  • Ye Q, Yang CJ, Tian LH, Zan L, Peng TY (2011) Tunable photocatalytic selectivity of fluoropolymer PVDF modified TiO2. Appl Surf Sci 257:8072–8077

    Article  Google Scholar 

  • Yi S, Yu SL, Shi WX, Sun N, Jin LM, Wang S, Zhang B, Ma C, Sun LP (2011) The influence of important factors on ultrafiltration of oil/water emulsion using PVDF membrane modified by nano-sized TiO2/Al2O3. Desalination 281:179–184

    Article  Google Scholar 

  • Yoshida R, Suzuki Y, Yoshikawa S (2005) Syntheses of TiO2 (B) nanowires and TiO2 anatase nanowires by hydrothermal and post heat treatments. J Solid State Chem 178:2179–2185

    Article  Google Scholar 

  • Yuliwati E, Ismail AF (2011) Effect of additives concentration on the surface proper-ties and performance of PVDF ultrafiltration membranes for refinery produced wastewater treatment. Desalination 273:226–234

    Article  Google Scholar 

  • Zhang YX, Li GH, Jin YX, Zhang Y, Zhang J, Zhang LD (2002) Hydrothermal synthesis and photoluminescence of TiO2 nanowires. Chem Phys Lett 365:300–304

    Article  Google Scholar 

  • Zhang W, Zou L, Wang L (2009) Photocatalytic TiO2/adsorbent nanocomposites prepared via wet chemical impregnation for wastewater treatment: a review. Appl Catal A 371:1–9

    Article  Google Scholar 

  • Zhang W, Zou L, Wang L (2010) Visible-light assisted methylene blue (MB) removal by novel TiO2/adsorbent nanocomposites. Water Sci Technol 61:2863–2871

    Article  Google Scholar 

  • Zhang W, Zou L, Wang L (2011) A novel charge-driven self-assembly method to prepare visible-light sensitive TiO2/activated carbon nanocomposites for dissolved organic compound removal. Chem Eng J 168:485–492

    Article  Google Scholar 

  • Zhong JQ, Ryu B, Kim MM, Kim SK (2008) Free radical and reactive oxygen species scavenging activities of the extracts from seahorse, Hippocampus kuda bleeler. Biotechnol Bioprocess Eng 6:705–715

    Google Scholar 

  • Zhu P, Yu JZ, Xu YY, Xi ZY, Zhu BK (2009) Surface modification of PVDF porous membranes via poly(DOPA) coating and heparin immobilization. Colloid Surf B 69:152–155

    Article  Google Scholar 

  • Zou L, Zhang W (2013) Key contaminants for water purification in view of remediation by nanomaterials. In: Van der Bruggen B (ed) Applications of nanomaterials for water quality. Future Science Limited, London, pp 30–50

    Google Scholar 

Download references

Acknowledgments

Assistance by Dr. Changseok Han (University of Cincinnati) in SEM analysis was greatly appreciated. Advice from Mr. Steve Amos (University of Adelaide) during the preparation of algae water solution was also gratefully acknowledged. Dr. Wei Zhang would also like to thank Australian Endeavour Fellowship Program and University of South Australia Early Career Researcher Travel Grant Scheme for their financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Wei Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, W., Zhang, Y., Fan, R. et al. A facile TiO2/PVDF composite membrane synthesis and their application in water purification. J Nanopart Res 18, 31 (2016). https://doi.org/10.1007/s11051-015-3281-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11051-015-3281-1

Keywords

Navigation