Abstract
The authors present a novel method of fabricating crystalline gold nanoparticles used in plasmonic application. The preparation and characterization of monocrystalline Au nanoparticles with diameters between 10 and 100 nm embedded in an YBa2Cu3O7−δ matrix is presented as well as a future vision of structured particle arrangements by photolithographic procedures. To use these particles for biological applications, the matrix may has to be dissolved to obtain extracted nanoparticles on a dielectric substrate. Whether the nanoparticles change their position during the extraction process is investigated and the realized dissolving procedure by citric acid solution is shown. The dissolution of the matrix thereby is investigated by X-ray diffraction experiments and energy-dispersive X-ray spectroscopy. Furthermore, the spectral characterization by particle selection is illustrated based on microspectroscopy.
Similar content being viewed by others
References
Agostinelli JA, Chen S, Braunstein G (1991) Cubic phase in the Y-Ba-Cu-O system. Phys Rev B 43:11396–11399
Berg KJ, Berger A, Hofmeister H (1991) Small silver particles in glass surface layers produced by sodium–silver ion exchange—their concentration and size depth profile. Z Phys D 20:309–311
Céspedes E, Babonneau D, de Sousa Meneses D, Prieto C, Fonda E, Lyon O, Briand E, Traverse A (2011) Effects of Au layer thickness and number of bilayers on the properties of Au/ZnO multilayers. J Appl Phys 109:094308
Cho S, Lee S, Lee TS, Cheong BK, Kim WM, Lee KS (2007) Microstructural effect on optical properties of Au:SiO2 nanocomposite waveguide films. J Appl Phys 102:123501
Christke S, Katzer C, Grosse V, Schmidl F, Schmidl G, Fritzsche W, Petschulat J, Pertsch T, Rettenmayr M (2011) Optical resonances of self-organized monocrystalline Au nanoparticles embedded in SrTiO3 matrix. Opt Mater Express 1:890–897
Csaki A, Schneider T, Wirth J, Jahr N, Steinbrück A, Stranik O, Garwe F, Müller R, Fritzsche W (2011) Molecular plasmonics: light meets molecules at the nanoscale. Philos Trans A 369:3483
Fritzsche W, Porwol H, Wiegand A, Bornmann S, Köhler JM (1998) In situ formation of Ag-containing nanoparticles in thin polymer films. Nanostruct Mater 10:89
Grosse V, Engmann S, Schmidl F, Undisz A, Rettenmayr M, Seidel P (2010) Formation of gold nano particles during pulsed laser deposition of YBa2Cu3O7−δ thin films. Phys Status Solidi RRL 4:97
Kaempfe M, Rainer T, Berg KJ, Seifert G, Graener H (1999) Ultrashort laser pulse induced deformation of silver nanoparticles in glass. Appl Phys Lett 74:1200
Katzer C et al (2011) Increased flux pinning in YBa2Cu3O7−δ thin-film devices through embedding of Au nano crystals. Europhys Lett 95:68005
Konstantinovic Z, del Muro MG, Varela M, Batlle X, Labarta A (2006) Particle growth mechanisms in Ag–ZrO2 and Au–ZrO2 granular films obtained by pulsed laser deposition. Nanotechnology 17:4106–4111
Liedberg B, Nylander C, Lundström I (1983) Surface plasmon resonance for gas detection and biosensing. Sens Actuator 4:299
Low IM, Low SS, Klauber C (1993) Chemical reactivity of YBaCuO and Bi(Pb)SrCaCuO superconductors in water. J Mater Sci Lett 12:1574
Maier SA (2007) Plasmonics—fundamentals and applications. Springer Science Business Media LLC, London
Mappes T, Jahr N, Csaki A, Vogler N, Popp J, Fritzsche W (2012) 100 years of immersion ultramicroscopy. Angew Chem Int Ed (submitted)
Schmidl F, Linzen S, Wunderlich S, Seidel P (1998) High-Tc direct current SQUIDs on silicon bicrystal substrates operating at 77 K. Appl Phys Lett 72:602–604
Seidel P, Schmidl F, Steigmeier C, Linzen S, Peiselt K, Mans M, Jacob H, Schmidt F, Scherbel J (2002) Thin YBCO films on different substrates and their use in Josephson junctions and SQUIDs. Supercond Sci Technol 15:462–467
Sharma S, Kamins TI, Stanley Williams R (2005) Synthesis of thin silicon nanowires using gold-catalyzed chemical vapor deposition. Appl Phys A 80:1225–1229
Siedentopf H, Zsigmondy R (1902) Über Sichtbarmachung und Größenbestimmung ultramikroskopischer Teilchen, mit besonderer Anwendung auf Goldrubingläser. Ann Phys 315:1–39
Stuart HR, Hall DG (1996) Absorption enhancement in silicon-on-insulator waveguides using metal island films. Appl Phys Lett 69:2327
Tiberto P, Gupta S, Bianco S, Celegato F, Martino P, Chiolerio A, Tagliaferro A, Allia P (2011) Morphology and magnetic properties of island-like Co and Ni films obtained by de-wetting. J Nanopart Res 13:245–255
Torrell M, Kabir R, Cunha L, Vasilevskiy MI, Vaz F, Cavaleiro A, Alves E, Barradas NP (2011) Tuning of the surface plasmon resonance in TiO2/Au thin films grown by magnetron sputtering: the effect of thermal annealing. J Appl Phys 109:074310
Worsch C, Kracker M, Wisniewski W, Rüssel C (2012) Optical properties of self assembled oriented island evolution of ultra-thin gold layers. Thin Solid Films 520:4941–4946
Wunderlich S, Schmidl F, Dörrer L, Schneidewind H, Seidel P (1999) Improvement of sensor performance of high-TC thin film planar SQUID gradiometers by ion beam etching. IEEE Trans Appl Supercond 9:71–76
Yan MF, Barns RL, O’Brayan HM (1987) Water interaction with the superconducting YBa2Cu3O7 phase. Appl Phys Lett 51:532
Acknowledgments
One of us (C. Katzer) would like to thank the Landesgraduiertenförderung Thüringen for financial support.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Katzer, C., Grosse, V., Schmidl, F. et al. YBa2Cu3O7−δ matrix-induced in situ growth of plasmonic Au nanoparticles for biological sensor devices. J Nanopart Res 14, 1285 (2012). https://doi.org/10.1007/s11051-012-1285-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-012-1285-7