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Elastic and Sorption Characteristics of an Epoxy Binder in a Composite During Its Moistening

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Abstract

Results of an experimental investigation into the elastic and sorption characteristics of a model composite material (CM) — epoxy resin filled with LiF crystals — during its moistening are presented. Properties of the binder in the CM with different filler contents (v f = 0, 0.05, 0.11, 0.23, 0.28, 0.33, 0.38, and 0.46) were evaluated indirectly by using known micromechanical models of CMs. It was revealed that, for the CM in a conditionally initial state, the elastic modulus of the binder in it and the filler microstrain (change in the interplanar distance in the crystals, measured by the X-ray method) as functions of filler content had the same character. The elastic modulus of the binder in the CM with a low filler content was equal to that for the binder in a block; the elastic modulus of the binder in the CM decreased with increasing filler content. The maximum (corresponding to water saturation of the CM) stresses in the binder and the filler microstresses as functions of filler content were of the same character. Moreover, the absolute values of maximum stresses in the binder and of filler microstresses coincided for high and low contents of the filler. At v f = 0.2–0. 3, the filler microstrains exceeded the stresses in the binder. The effect of moisture on the epoxy binder in the CM with a high filler content was not entirely reversible: the elastic characteristics of the binder increased, the diffusivity decreased, and the ultimate water content increased after a moistening-drying cycle.

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REFERENCES

  1. Yu. S. Lipatov, F. G. Fabulyak, and N. G. Popova, “Investigation of molecular mobility in epoxy polymers at various stages of curing in the bulk and at the interface,” Vysokomol. Soed., A13, No.11, 2601–2606 (1971).

    Google Scholar 

  2. V. P. Korkhov, M. G. Kamenskii, and E. A. Faitel’son, “Effect of the adhesion interaction and the degree of filling on the internal stresses in finely divided crystalline fillers of epoxy composites,” Mech. Compos. Mater., 35, No.6, 527–534 (1999).

    Google Scholar 

  3. V. P. Korkhov, E. A. Faitel’son, T. I. Glaskova, and Yu. O. Janson, “Influence of moisture on the structure and properties of the interphase layer of a composite based on an epoxy binder with a disperse filler,” Mech. Compos. Mater. (2005) (in press).

  4. V. A. Latyshenko, Diagnostics of the Rigidity and Strength of Materials [in Russian], Zinatne, Riga (1968).

    Google Scholar 

  5. E. H. Kerner, “The elastic and thermoelastic properties of composite media,” Proc. Phys. Soc., 29, No.440B, 808–813 (1956).

    Google Scholar 

  6. G. Z. Xiao and M. E. R. Shanahan, “Swelling of DGEBA/DDA epoxy resin during hygrothermal ageing,” Polymer, 39, No.14, 3253–3260 (1998).

    Article  Google Scholar 

  7. J. Crank, The Mathematics of Diffusion, Oxford (1956).

  8. R. D. Stepanov and O. F. Shlenskii, Strength Calculations for Plastic Structures Operating in Liquid Media [in Russian], Moscow (1981).

  9. M. E. R. Shanahan and Y. Auriac, “Water absorption and leaching effects in cellulose diacetate,” Polymer, 39, No.5, 1155–1164 (1998).

    Article  Google Scholar 

  10. J. A. Manson and L. H. Spearling, Polymer Blends and Composites, Premium Press, New York (1981).

    Google Scholar 

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Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 4, pp. 499–511, July–August, 2005.

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Aniskevich, K., Glaskova, T. & Jansons, J. Elastic and Sorption Characteristics of an Epoxy Binder in a Composite During Its Moistening. Mech Compos Mater 41, 341–350 (2005). https://doi.org/10.1007/s11029-005-0059-z

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