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Synthesis and structure of AMP/oxide support

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Abstract

Compositions based on oxides and containing 5–20% w/w of ammonium molybdophosphate have been synthesized by means of different routes. Prepared samples have been studied using nitrogen adsorption–desorption, XRD, DTA–TG, and FTIR spectroscopy. Keggin structure is retained at incorporation of ammonium molybdophosphate into siliceous framework or its deposition on oxide surface and duration following calcinations up to 500 °C. Compositions possess porous structure from micromesoporous to mesomacroporous depending on the preparation method.

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Acknowledgements

This study was supported by International Visegrad Fund (Contract No. 50910373).

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology, NAS of Ukraine, Kyiv, Ukraine

    V. Sydorchuk & S. Khalameida

  2. O. O. Chuiko Institute of Surface Chemistry, NAS of Ukraine, Kyiv, Ukraine

    V. Sydorchuk

  3. Faculty of Chemistry, Maria Curie-Skłodowska University, Poland, Lublin

    J. Skubiszewska-Zięba & R. Leboda

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  1. V. Sydorchuk
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  2. S. Khalameida
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  4. R. Leboda
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Correspondence to V. Sydorchuk.

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Sydorchuk, V., Khalameida, S., Skubiszewska-Zięba, J. et al. Synthesis and structure of AMP/oxide support. J Therm Anal Calorim 103, 257–265 (2011). https://doi.org/10.1007/s10973-010-0967-6

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  • DOI: https://doi.org/10.1007/s10973-010-0967-6

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