Skip to main content
Log in

Electrical conductivity studies on some dibenzoylmethane arylhydrazones (DBMAH)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Electrical conductivity of some dibenzoylmethane arylhydrazones (DBMAH) were measured during heating and reheating runs. The observed variation of the conductance of the polycrystalline sample during thermal agitation was found to depend on the ordering and disordering of molecules which in turn cause the lattice dipole to distort. A semiconducting behavior was detected for these systems as it was deduced from their conductance values (1.7 × 10−6 − 8.25 × 10−7 ohm−1 cm−1). The presence of substituents affects markedly the measured electrical conductivity and calculated activation energy values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Pati S, editor. The chemistry of the hydrazo, azo and azoxy groups. London: Wiley; 1975.

    Google Scholar 

  2. Druckrey H, Preussman R, Matzkies F, Matzkies F, Ivankovic S. Carcinogene wirkung von 1,2-diathylhydrazin an ratten. Naturwissen Schaften. 1966;53:557.

    Article  CAS  Google Scholar 

  3. Toth B. Tumorigenesis studies with 1, 2-dimethylhydrazine dihydrochloride, hydrazine sulfate, and isonicotinic acid in golden Hamster. Cancer Res. 1972;32:804–7.

    CAS  Google Scholar 

  4. Luckens RJ. Chemistry of antifungal action. Berlin: Springer Verlag; 1972.

    Google Scholar 

  5. El-Nagdi MH, Kassab NAL, Sobhy MEE, Hamza MR, Wahby MV. Reaction of arylhydrazones with Grignard reagents. J Prakt Chem. 1972;314:815–21.

    Article  CAS  Google Scholar 

  6. El-Nagdi MH, Abdallah SO. Reacions with the arylhtdrazones of some α-cyanoketones. J Prakt Chem. 1973;315:1009–16.

    Article  CAS  Google Scholar 

  7. Emsly J. The composition, structure and hydrogen bonding of the β-diketones. Struct Bonding. 1984;57:147–91.

    Article  Google Scholar 

  8. Vojta GM, Etterant MC. The use of solid-state NMR and X-ray crystallography as complementary tools for studying molecular recognition. J Mol Graphics. 1989;7:3–11.

    Article  Google Scholar 

  9. Kopleva TS, Shigoin DN. Theoretical study of proton encircling modes in proton sponges with tetraamido/diamido qudermized macrocycles: thr role of π-conjugation and aliphatic bridges. Russ J Phys Chem. 1974;48:312.

    Google Scholar 

  10. Frisch MJ, Schneiner AC, Shaeffer III HF, Binkley JS. The malonaldehyde equilibrium geometry: a major structural shift due to the effects of electron correlation. J Chem Phys. 1985;82:4194.

    Article  CAS  Google Scholar 

  11. Bertolassi V, Ferreti V, Gilli P, Issa YM, Sherif OE. Intramolecular N-H.….O Hydrogen bonding assisted by resonance, Part 2-Intercorrelation between structural and spectroscopic parameters for five 1, 3-diketone arylhydrazones derived from dibenzoylmethane. J Chem Soc Perkin Trans. 1993;2:2223–8.

    Google Scholar 

  12. Bertolassi V, Nanni L, Gilli P, Ferreti V, Gilli G, Issa YM. Sherif OE Intramolecular N-HOC hydrogen bonding assisted by resonance inter-correlation between structural and spectroscopic data for six β-biketo-arylhydrazones derived from bonzoylacetone or acetylacetone. New J Chem. 1994;18:251–61.

    Google Scholar 

  13. Salem AA, Issa YM, Ayad MI, El Kholy M. Electrical, spectral and thermochromic properties of some hydrazone derivatives. J Mat Sci Mat Electron. 1994;5:199–202.

    CAS  Google Scholar 

  14. Hassib HB, Issa YM, Mohamed WS. Electrical and thermal studies on some acetylacetone- and benzoylacetone-arylhydrazones. J Therm Anal Calorim. 2008;92:775–82.

    Article  CAS  Google Scholar 

  15. Phillips NE, Fisher RA. Superconducting-state energy gap parameters from specific heat measurements MgB2 and Na0.3CoO2·1.3H2O. J Therm Anal Calorim. 2005;81:631–5.

    Article  CAS  Google Scholar 

  16. Natividad E, Castro M, Burriel R, Angurel LA. Thermal conductance measurements of superconducting bi-2212 rods and a bi-2212-based current leadmodule. J Therm Anal Calorim. 2006;84:307–16.

    Article  CAS  Google Scholar 

  17. Shamsipur M, Taskhourian J, Sharghi H (2005) Development of a PVC-membrane ion-selective bulk optode, for UO2 2+ ion, based on tri-n-octylphosphine oxide and dibenzoylmethane. Anal Biomed Anal. doi: 10.1007/s00216-005-3225-1.

  18. Stanimirov SS, Petkov IK (2008) Novel pH responsive luminescent poly(oxyethylene phosphate) tris (β-diketonate) europium (III) complexes. Cent Eur J Chem. doi: 10.2478/s11532-008-0035-2.

  19. Gnanasoundary VG, Natarajan KK. Synthesis, characterization and catalytic studies of iron(III), cobalt(II), nickel(II) and copper(II) complexes containing triphenylphosphine and β-diketones. Transit Met Chem. 2005;30:433–8.

    Article  Google Scholar 

  20. Xu J, Xiong Q, Chen B, Wang L, Liu L, Xu W. Modeling the relative intensity ratio of Eu(III) complex in different solvents based on QSPR method. J Fluoresc. 2009;19:203–9.

    Article  CAS  Google Scholar 

  21. Sallam SA. Binuclear copper(II), nickel(II), and cobalt(II) complexes with N2O2 chromophores of glycylglycine Schiff-bases of acetylacetone, benzoylacetone and thenoyltrifluoroacetone. Transit Met Chem. 2006;31:46–55.

    Article  CAS  Google Scholar 

  22. Yao HC, Resnic P. J Am Chem Soc. 1962;84:3514.

    Article  Google Scholar 

  23. Abou Sekkina M, Issa YM. Further studies on semiconductivity in correlation with the optical properties of some related solid charge transfer complexes for their possible application in solar cells. Thermochim Acta. 1985;83:321–30.

    Article  CAS  Google Scholar 

  24. El-Ansary AL, Issa YM, Mohamed HA. Spectrophotometric studies on some β-diketo-arylhydrazones. Kolriszt Erte 1987;141–52.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y. M. Issa.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Issa, Y.M., Hassib, H. & Mohamed, W.S. Electrical conductivity studies on some dibenzoylmethane arylhydrazones (DBMAH). J Therm Anal Calorim 100, 219–223 (2010). https://doi.org/10.1007/s10973-009-0224-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-009-0224-z

Keywords

Navigation