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Relationship between properties of fluorinated graphite intercalates and matrix composition Part III. Intercalates with 1,2-dichloroethane

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Abstract

Inclusion compounds (intercalates) of fluorinated graphite matrix with 1,2-dichloroethane (C2FxBrz·yC2H4Cl2, x=0.49, 0.69, 0.87, 0.92, z≈0.01) were synthesized by guest substitution from acetonitrile to dichloroethane. The kinetics of the thermal decomposition (the 1st stage of filling→the 2nd stage of filling) was studied under isothermal conditions at 289–313 K. The relationship between the structure of host matrices with thermal properties and kinetic parameters of inclusion compounds is discussed.

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References

  1. D. V. Pinakov and V. A. Logvinenko, J. Therm. Anal. Cal., 86 (2006) 173.

    Article  CAS  Google Scholar 

  2. D. V. Pinakov, V. A. Logvinenko, Yu. V. Shubin and G. N. Chekhova, J. Therm. Anal. Cal., 90 (2007) 399.

    Article  CAS  Google Scholar 

  3. O. A. Osipov, V. I. Minkin and Yu. B. Kletenik, Dipole Moments Reference Book., Rostov 1961, p. 242 (in Russian).

  4. N. F. Yudanov and I. I. Yakovlev, Izv. Sib. Branch of USSR Acad. of Sciences, Ser. Chem. Sci., 21 (1988) 66.

    Google Scholar 

  5. G. N. Chekhova, E. A. Ukraintseva, I. M. Ivanov, N. F. Yudanov, Yu. V. Shubin, V. A. Logvinenko, D. V. Pinakov, V. P. Fadeeva and N. I. Alferova, J. Inorg. Chem., 50 (2005) 1143 (in Russian).

    CAS  Google Scholar 

  6. Yu. V. Shubin, D. V. Pinakov, G. N. Chekhova, N. I. Alferova and V. A. Logvinenko, J. Struct. Chem., 47 (2006) 1150.

    Google Scholar 

  7. D. V. Pinakov, Different Fluorination Degree Fluorinated Graphite Matrices Intercalates Synthesis and Thermal Stability. Ph.D. Thesis, Novosibirsk 2007, p. 163.

  8. A. J. Gordon and R. A. Ford, The Chemist’s Companion, New York-London-Sydney-Tokyo 1972.

  9. Chemical Reference Book, Vol. 1. Moscow-Leningrad 1962, V. 1, p. 694.

    Google Scholar 

  10. B. V. Erofeev, Generalized Equation of Chemical Kinetics and Its Application to Solid Phase Reactions, Rep. USSR Acad. Sci., 52 (1946) 515.

    Google Scholar 

  11. G. V. Sakovich, Tomsk State University Scientific Notes, 26 (1955) 103.

    Google Scholar 

  12. K. I. Patrilyak, Inclusion compounds and certain problems of heterogeneous equilibria, Kiev, Naukova Dumka 1987 (in Russian).

    Google Scholar 

  13. L. T. Vlaev, G. G. Gospodinov and S. D. Genieva, J. Phys. Chem., 76 (2002) 1437.

    Google Scholar 

  14. V. A. Logvinenko, Thermal Analysis of Coordination Compounds and Clathrates, Novosibirsk, Nauka, Siberian Department, 1982 (in Russian).

    Google Scholar 

  15. D. Stull, E. Westram and G. Sinke, Chemical Thermodynamics of Organic Compounds, Wiley, N. Y., Washington 1969.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, Novosibirsk-90, 630090, Russia

    D. V. Pinakov, V. A. Logvinenko, Yu. V. Shubin & G. N. Chekhova

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  1. D. V. Pinakov
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  2. V. A. Logvinenko
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  3. Yu. V. Shubin
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  4. G. N. Chekhova
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Correspondence to D. V. Pinakov.

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Pinakov, D.V., Logvinenko, V.A., Shubin, Y.V. et al. Relationship between properties of fluorinated graphite intercalates and matrix composition Part III. Intercalates with 1,2-dichloroethane. J Therm Anal Calorim 96, 501–505 (2009). https://doi.org/10.1007/s10973-008-9534-9

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  • DOI: https://doi.org/10.1007/s10973-008-9534-9

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