Skip to main content
SpringerLink
Log in

Thermodynamics and phase equilibrium studies of silver halide-cobalt(II) halide systems

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Phase diagrams for the systems AgCl-CoCl2 and AgBr-CoBr2 were determined by differential scanning calorimetry. The systems are of the eutectic type. Eutectic points are at 271±2 K, 19.5 mol% CoCl2 and 653±2 K, 17.0 mol% CoBr2, respectively. The solid solubility does not exceed 2 and 4 mol% in the systems AgCl-CoCl2 and AgBr-CoBr2, respectively. Thermodynamic activities of components in molten mixtures and molar free enthalpies of mixing were determined for both systems on the basis of liquidus curves. Deviations from ideality were not found to be considerable.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. Vassilev, L. Aljihmani and V. Parvanova, J. Therm. Anal. Cal., 75 (2004) 63.

    Article  CAS  Google Scholar 

  2. V. Vassilev, V. Parvanova and V. Vatchkov, J. Therm. Anal. Cal., 83 (2006) 467.

    Article  CAS  Google Scholar 

  3. H. J. Seifert, J. Therm. Anal. Cal., 83 (2006) 479.

    Article  CAS  Google Scholar 

  4. A. Wojakowska and E. Krzyżak, J. Therm. Anal. Cal., 83 (2006) 597.

    Article  CAS  Google Scholar 

  5. A. Wojakowska, E. Krzyżak, A. Wojakowski and M. Wołcyrz, Z. Naturforsch., 62a (2007) 507.

    Google Scholar 

  6. F. J. Martinez Casado, M. Ramos Riesco and J. A. R. Cheda, J. Therm Anal. Cal., 87 (2007) 73.

    Article  CAS  Google Scholar 

  7. J.-Y. Tilquin, J. Fournier, D. Guay, J. P. Dodelet and G. Dénes, Carbon, 35 (1997) 299.

    Article  CAS  Google Scholar 

  8. N. Ouahdi, S. Guillemet, J. J. Demai, B. Durand, L. Er Rakho, R. Moussa and A. Samdi, Mater. Lett., 59 (2005) 334.

    Article  CAS  Google Scholar 

  9. H. J. Seifert and L. Stäudel, Z. Anorg. Allg. Chem., 429 (1977) 105.

    Article  CAS  Google Scholar 

  10. A. Wojakowska, A. Górniak, A. Wojakowski and S. Plińska, J. Therm. Anal. Cal., 77 (2004) 41.

    Article  CAS  Google Scholar 

  11. A. Wojakowska, E. Krzyżak and S. Plińska, J. Therm. Anal. Cal., 88 (2007) 525.

    Article  CAS  Google Scholar 

  12. J. Wydeven and N. W. Gregory, J. Phys. Chem., 68 (1964) 3249.

    Article  CAS  Google Scholar 

  13. A. Wojakowska, S. Plińska and E. Krzyżak, J. Therm. Anal. Cal., 90 (2007) 355.

    Article  CAS  Google Scholar 

  14. V. Vassilev, K. Tomova and V. Parvanova, J. Therm. Anal. Cal., 86 (2006) 199.

    Article  CAS  Google Scholar 

  15. G. Tamman, Z. Anorg. Chem., 47 (1905) 289.

    Article  Google Scholar 

  16. E. Ingier-Stocka, S. Gadzuric, L. Rycerz, M. Cieślak-Golonka and M. Gaune-Escard, J. Nucl. Mater., 344 (2005) 120.

    Article  CAS  Google Scholar 

  17. A. Wojakowska, J. Chim. Phys. Physicochim. Biol., 90 (1993) 561.

    CAS  Google Scholar 

  18. A. Wojakowska and E. Krzyżak, J. Phys. IV, 122 (2004) 203.

    Article  CAS  Google Scholar 

  19. A. Wojakowska, A. Górniak and A. Wojakowski, J. Chem. Eng. Data, 49 (2004) 1231.

    Article  CAS  Google Scholar 

  20. W. T. Thompson and S. N. Flengas, Can. J. Chem., 49 (1971) 1553.

    Article  Google Scholar 

  21. A. Winzer, Krist. Techn., 14 (1979) 51.

    Article  CAS  Google Scholar 

  22. I. Bibas and J. Leonardi, Compt. Rend. Acad. Sci., Ser. C, 268 (1969) 87.

    Google Scholar 

  23. O. Kubaschewski, C. B. Alcock and P. J. Spencer, Materials Thermochemistry, Pergamon Press, Oxford 1993, Chapter 5, Table I, p. 271.

    Google Scholar 

  24. Y. Dutt and T. Ostvold, Acta Chem. Scand., 26 (1972) 2743.

    Article  CAS  Google Scholar 

  25. C. Robelin, P. Chartrand and A. D. Pelton, J. Chem. Thermodyn., 36 (2004) 809.

    Article  CAS  Google Scholar 

  26. J. Lumsden, Thermodynamics of Molten Salt Mixtures, Academic Press, London 1966.

    Google Scholar 

  27. C. Robelin, P. Chartrand and A. D. Pelton, J. Chem. Thermodyn., 36 (2004) 793.

    Article  CAS  Google Scholar 

  28. G. N. Papatheodorou and O. J. Kleppa, J. Chem. Thermodyn., 12 (1980) 807.

    Article  CAS  Google Scholar 

  29. G. N. Papatheodorou and O. J. Kleppa, J. Inorg. Nucl. Chem., 33 (1971) 1249.

    Article  CAS  Google Scholar 

  30. Y. Takagi and T. Nakamura, Philos. Mag. B, 51 (1985) L43

    Article  CAS  Google Scholar 

  31. G. N. Papatheodorou and O. J. Kleppa, Z. Anorg. Allg. Chem., 401 (1973) 132.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska, 38 50 139, Wrocław, Poland

    E. Krzyżak & Alina Wojakowska

Authors
  1. E. Krzyżak
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Alina Wojakowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Krzyżak.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krzyżak, E., Wojakowska, A. Thermodynamics and phase equilibrium studies of silver halide-cobalt(II) halide systems. J Therm Anal Calorim 93, 721–726 (2008). https://doi.org/10.1007/s10973-008-9135-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-008-9135-7

Keywords

Search

Navigation