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Excess molar enthalpies of binary mixtures for (tributyl phosphate+methanol/ethanol) at 298.15 K

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Abstract

Excess molar enthalpies of binary mixtures for tributyl phosphate (TBP)+methanol/ethanol were measured with a TAM air Isothermal calorimeter at 298.15 K and ambient. The results for xTBP+(1–x)CH3OH are negative in the whole range of composition, while the values for xTBP+(1–x)C2H5OH change from positive values at low x to small negative values at high x. The experimental results have been correlated with the Redlich–Kister polynomial. IR spectra of the mixtures were measured to investigate the effect of hydrogen bonding in the mixture.

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References

  1. AJ Britz FLD Cloete (1990) Hydrometallurgy 25 213 Occurrence Handle1:CAS:528:DyaK3cXlvFGiur0%3D Occurrence Handle10.1016/0304-386X(90)90040-9

    Article  CAS  Google Scholar 

  2. JN Mathur MS Mruali PR Natarajan (1993) Waste Manag. 13 317 Occurrence Handle1:CAS:528:DyaK2cXhslKjtrs%3D Occurrence Handle10.1016/0956-053X(93)90060-A

    Article  CAS  Google Scholar 

  3. KG Furton L Chen R Jaffe (1995) Anal. Chim. Acta 304 203 Occurrence Handle1:CAS:528:DyaK2MXkvVaisL4%3D Occurrence Handle10.1016/0003-2670(94)00524-P

    Article  CAS  Google Scholar 

  4. M Rajan VM Shinde (1996) J. Radioanal. Nucl. Chem. 203 169 Occurrence Handle1:CAS:528:DyaK28Xhs1GntrY%3D Occurrence Handle10.1007/BF02060392

    Article  CAS  Google Scholar 

  5. WA Abbasi M Streat (1998) Solvent Extr. Ion Exch. 16 1303 Occurrence Handle1:CAS:528:DyaK1cXls1Sjur4%3D

    CAS  Google Scholar 

  6. A Dodi G Verda (2001) J. Chromatogr. A 920 275 Occurrence Handle1:CAS:528:DC%2BD3MXktlWhtbY%3D Occurrence Handle10.1016/S0021-9673(01)00834-2

    Article  CAS  Google Scholar 

  7. WW Schulz LL Burger JD Nabratil et al. (1990) Science and Technology of Tributylphosphate, Application of Tributylphosphate in Nuclear Fuel Processing, Vol. 3 CRC Press Florida

    Google Scholar 

  8. C Erkey (2000) J. Supercrit. Fluids 17 259 Occurrence Handle1:CAS:528:DC%2BD3cXjtFSqtbw%3D Occurrence Handle10.1016/S0896-8446(99)00047-9

    Article  CAS  Google Scholar 

  9. CM Wai SF Wang (2000) J. Biochem. Biophys. Methods 43 273 Occurrence Handle1:CAS:528:DC%2BD3cXktlKkuro%3D Occurrence Handle10.1016/S0165-022X(00)00061-0

    Article  CAS  Google Scholar 

  10. KE Laintz E Tachikawa (1994) Anal. Chem. 66 2190 Occurrence Handle1:CAS:528:DyaK2cXkt1Snu7s%3D Occurrence Handle10.1021/ac00085a040

    Article  CAS  Google Scholar 

  11. O Tomioka Y Enokida I Yamamoto T Takahashi (2000) Prog. Nucl. Energy 37 417 Occurrence Handle1:CAS:528:DC%2BD3cXovF2ksr8%3D Occurrence Handle10.1016/S0149-1970(00)00081-0

    Article  CAS  Google Scholar 

  12. R Shimizu K Sawada Y Enokida I Yamamoto (2005) J. Supercrit. Fluids 33 235 Occurrence Handle1:CAS:528:DC%2BD2cXhtFams7%2FI Occurrence Handle10.1016/j.supflu.2004.08.004

    Article  CAS  Google Scholar 

  13. AK Dillow KP Hafner SLJ Yun F Deng SG Kazarian CL Liotta CA Eckert (1997) AIChE J. 43 515 Occurrence Handle1:CAS:528:DyaK2sXhtFalsrs%3D Occurrence Handle10.1002/aic.690430224

    Article  CAS  Google Scholar 

  14. K Mishima K Matsuyama M Nagatani (1999) Fluid Phase Equilib. 161 315 Occurrence Handle1:CAS:528:DyaK1MXksV2rs70%3D Occurrence Handle10.1016/S0378-3812(99)00211-3

    Article  CAS  Google Scholar 

  15. S-J Liu Y Inada S Funahashi (2004) J. Supercrit. Fluids 30 237 Occurrence Handle10.1016/j.supflu.2003.08.002

    Article  Google Scholar 

  16. Y Inada T Horita Y Yokooka S Funahashi (2004) J. Supercrit. Fluids 31 175 Occurrence Handle1:CAS:528:DC%2BD2cXnvVOgu7o%3D Occurrence Handle10.1016/j.supflu.2003.10.002

    Article  CAS  Google Scholar 

  17. N Asprion H Hasse G Maurer (2003) Fluid Phase Equilib. 205 195 Occurrence Handle1:CAS:528:DC%2BD3sXjtl2qtrs%3D Occurrence Handle10.1016/S0378-3812(02)00181-4

    Article  CAS  Google Scholar 

  18. N Asprion H Hasse G Maurer (2003) Fluid Phase Equilib. 208 23 Occurrence Handle1:CAS:528:DC%2BD3sXktF2ktro%3D Occurrence Handle10.1016/S0378-3812(02)00317-5

    Article  CAS  Google Scholar 

  19. JM Simonson RE Mesmer PSZ Rogers (1989) J. Chem. Thermodyn. 21 561 Occurrence Handle1:CAS:528:DyaL1MXlt1ajsbw%3D Occurrence Handle10.1016/0021-9614(89)90172-9

    Article  CAS  Google Scholar 

  20. HF Holmes RH Buscy JM Simonson RE Mesmer (1987) J. Chem. Thermodyn. 19 863 Occurrence Handle1:CAS:528:DyaL2sXlsVantrg%3D Occurrence Handle10.1016/0021-9614(87)90033-4

    Article  CAS  Google Scholar 

  21. N Hubert R Solimando A Pere L Schuffenecker (1997) Thermochim. Acta 294 157 Occurrence Handle1:CAS:528:DyaK2sXks1aksbw%3D Occurrence Handle10.1016/S0040-6031(97)00058-0

    Article  CAS  Google Scholar 

  22. G Olofsson LG Hepler (1975) J. Solution Chem. 4 127 Occurrence Handle1:CAS:528:DyaE2MXksV2hsrw%3D Occurrence Handle10.1007/BF00649154

    Article  CAS  Google Scholar 

  23. M Landgren D McEachern Q Olofsson S Randzio S Sunner (1978) J. Chem. Thermodyn. 10 847 Occurrence Handle1:CAS:528:DyaE1cXlvVKrurk%3D Occurrence Handle10.1016/0021-9614(78)90158-1

    Article  CAS  Google Scholar 

  24. I Nagata K Tamura (1999) J. Chem. Thermodyn. 31 491 Occurrence Handle1:CAS:528:DyaK1MXitV2gtLw%3D Occurrence Handle10.1006/jcht.1998.0482

    Article  CAS  Google Scholar 

  25. JB Ott JT Sipowska (1996) J. Chem. Eng. Data 41 987 Occurrence Handle1:CAS:528:DyaK28XltV2hu70%3D Occurrence Handle10.1021/je960105a

    Article  CAS  Google Scholar 

  26. JR Battler RL Rowley (1985) J. Chem. Thermodyn. 17 719 Occurrence Handle1:CAS:528:DyaL2MXltFSqsL0%3D Occurrence Handle10.1016/0021-9614(85)90101-6

    Article  CAS  Google Scholar 

  27. L Pikkarainen (1986) J. Solution Chem. 15 473 Occurrence Handle1:CAS:528:DyaL28XksFSjtL0%3D Occurrence Handle10.1007/BF00644890

    Article  CAS  Google Scholar 

  28. I Nagata K Tamura (1986) J. Chem. Thermodyn. 18 39 Occurrence Handle1:CAS:528:DyaL28Xps1yhsA%3D%3D Occurrence Handle10.1016/0021-9614(86)90041-8

    Article  CAS  Google Scholar 

  29. JY Coxam SE Gillespie JL Oscarson RM Izatt (1995) J. Chem. Thermodyn. 27 1133 Occurrence Handle1:CAS:528:DyaK2MXos1yktLY%3D Occurrence Handle10.1006/jcht.1995.0117

    Article  CAS  Google Scholar 

  30. MJ Pederson WB Kay HC Hershey (1975) J. Chem. Thermodyn. 7 1107

    Google Scholar 

  31. I Nagata Y Ogasawara (1982) Thermochim. Acta 52 155 Occurrence Handle1:CAS:528:DyaL38Xpt1OksA%3D%3D Occurrence Handle10.1016/0040-6031(82)85193-9

    Article  CAS  Google Scholar 

  32. I Nagata K Tamura (1983) Fluid Phase Equilibria 15 67 Occurrence Handle1:CAS:528:DyaL3sXmtF2rsLY%3D Occurrence Handle10.1016/0378-3812(83)80022-3

    Article  CAS  Google Scholar 

  33. I Nagata K Tamura (1984) J. Chem. Thermodyn. 16 975 Occurrence Handle1:CAS:528:DyaL2cXmtlKns7w%3D Occurrence Handle10.1016/0021-9614(84)90167-8

    Article  CAS  Google Scholar 

  34. K Kurihara T Iguchi T Banaka K Ochi K Kojima (2001) Fluid Phase Equilib. 180 59 Occurrence Handle1:CAS:528:DC%2BD3MXjt12msrw%3D Occurrence Handle10.1016/S0378-3812(00)00510-0

    Article  CAS  Google Scholar 

  35. SJ O’Shea RH Stokes (1986) J. Chem. Thermodyn. 18 691 Occurrence Handle1:CAS:528:DyaL28Xks1OntL8%3D Occurrence Handle10.1016/0021-9614(86)90072-8

    Article  CAS  Google Scholar 

  36. S-B Park J-S Kim H Lee (1999) J. Chem. Thermodyn. 31 1265 Occurrence Handle1:CAS:528:DyaK1MXlvVWrur0%3D Occurrence Handle10.1006/jcht.1999.0534

    Article  CAS  Google Scholar 

  37. T Kimura T Matsushita M Momoki H Mizuno N Kanbayashi T Kamiyama M Fujisawa S Takagi Y Toshiyasu (2004) Thermochim. Acta 424 83 Occurrence Handle1:CAS:528:DC%2BD2cXovVCktrg%3D Occurrence Handle10.1016/j.tca.2004.05.009

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, China, 410083

    Liu H.-L., Liu S.-J., Xiao Z.-L. & Chen Q.-Y.

  2. Department of Chemistry and Environmental Engineering, Changsha University of Science and Technology, Changsha, Hunan, China, 410076

    Yang D.-W.

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  1. Liu H.-L.
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  2. Liu S.-J.
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  3. Xiao Z.-L.
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  4. Chen Q.-Y.
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Correspondence to Liu S.-J..

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Liu, HL., Liu, SJ., Xiao, ZL. et al. Excess molar enthalpies of binary mixtures for (tributyl phosphate+methanol/ethanol) at 298.15 K. J Therm Anal Calorim 85, 541–544 (2006). https://doi.org/10.1007/s10973-006-7635-x

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  • DOI: https://doi.org/10.1007/s10973-006-7635-x

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