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Impinging streams application in mass production of rare earth ions doped upconversion luminescence microparticles

  • Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)
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Abstract

Known as one efficient upconversion luminescent material, Rare-earth ions doped natrium yttrium fluoride NaYF4:Yb/Re has broad application prospects. However, due to the limitation of the existing preparation methods, it is difficult to realize industrial production. In this paper, the upconversion luminescence microparticles, rare earth ions doped Natrium Yttrium Fluoride NaYF4:Yb/Er, were synthesized productively by impinging stream method. Synthesis conditions were optimized as EDTA: Ln to 0.5 and NaF: Ln to 6 (Ln represents the sum of moles of Y, Yb, and Er), reacting temperature and time to 50 °C and 3 h to obtain a high yield of 99.92% and particle with good monodispersity. To get strong upconversion luminescence, the effect of the calcination temperature and the amount of EDTA were investigated. The bright upconversion emissions by excited with laser radiation at 975 nm were found at 510–690 nm. The higher the calcination temperature, the stronger the luminescence and the strongest luminescence occurs when calcined at 600 °C. And the adding of EDTA will decrease the luminescence intensity. However, the sintering of particles at high temperatures and aggregation of particles without EDTA are unfavorable for the application of the products. Based on the above considerations, the optimal calcination temperature was determined at 450 °C, and the ratio of EDTA: Ln is preferred at 0.5. The impinging stream method to prepare upconversion material has the advantages of being simple in the process and equipment, high in output, low in investment, and convenient to be applied and popularized.

Highlights

  • Mass Production of up-conversion luminescence materials is illustrated.

  • NaYF4:Yb/Er microparticles were synthesized by the novel impinging stream method.

  • Products with high yield of 99.92% and good mono-dispersity could be obtained at optimal condition.

  • The hexagonal crystals were obtained by calcinations at 450 °C, and it can emit bright up-conversion emissions of at 510–690 nm.

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Funding

This research work was supported by the National Natural Science Foundation of China (51502210), the fund of Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science (CHCL21002), the Innovation Project of Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education (LCX2021001), the 15th and 16th President’s Foundation of Wuhan Institute of Technology (XZJJ2020002, XZJJ2021091), the 2020 National College Students Innovation and Entrepreneurship Training Program (202010490002).

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Engineering process of Ministry of Education, Engineering Research Center of Phosphorus Resource Development and Utilization of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan, Hubei, 430205, China

    Ping Li, Liuyong Zhao, Xiaohui Zhang, Huaiyuan Jiang, Ruizhen Liu, Nengchuang Zhao, Jian Cheng & Renliang Lyu

  2. Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang, Hubei, 441053, China

    Song Wang

  3. Department of Chemical Engineering and Materials Engineering, The College of Post and Telecommunication of WIT, Wuhan, 430074, China

    Caili Xu

  4. Key Laboratory of Novel Reactor and Green Chemical Technology of Hubei Province, School of Foreign Languages of Wuhan Institute of Technology, 206 Guanggu Yi Road, East Lake High-tech Development Zone, Hubei Province, Wuhan, China

    He Zhao

Authors
  1. Ping Li
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  2. Liuyong Zhao
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  3. Song Wang
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  4. Xiaohui Zhang
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  5. Huaiyuan Jiang
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  6. Ruizhen Liu
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  7. Nengchuang Zhao
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  8. Jian Cheng
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  9. Caili Xu
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  10. He Zhao
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  11. Renliang Lyu
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Contributions

LZ prepared a new batch of samples and characterized the samples by EDS and XRD. SW recorded the PL spectra of the new samples prepared by LZ and put forward many advices on the discussion of PL spectra.

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Correspondence to Caili Xu or Renliang Lyu.

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Li, P., Zhao, L., Wang, S. et al. Impinging streams application in mass production of rare earth ions doped upconversion luminescence microparticles. J Sol-Gel Sci Technol 101, 215–226 (2022). https://doi.org/10.1007/s10971-021-05675-y

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