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Influence of zeolite carriers on the dyes degradation for framework Fe-doped zeolite catalysts

  • Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)
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Abstract

Fe-doped zeolites with Mobil Five (MFI) structure have been widely used as heterogeneous Fenton catalysts to eliminate dyes from wastewater. However, the influence of carriers on degradation efficiency has not been reported yet. In this work, we have prepared three Fe-doped zeolite catalysts, FeS-1, FeZSM-5, and FeTS-1, with silicalite-1 (S-1), zeolite socony mobil-5 (ZSM-5), and titanium silicalite-1 (TS-1) as carriers, respectively. Characterizations, such as X-ray diffraction (XRD), scanning electron microscopy, energy-disperse X-ray spectroscopy, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflection spectroscopy (UV–Vis DRS), X-ray fluorescence spectrometer, zeta potential, and N2 adsorption/desorption isotherms, were used to investigate the morphologies and physicochemical properties of the synthesized materials. The catalytic performances of all zeolite catalysts were evaluated in the degradation experiments. The results depicted that the degradation efficiency of FeZSM-5 was higher than that of FeS-1 and FeTS-1 owing to its higher hydrophilic property, larger external specific surface area, and more negative zeta potential value. Therefore, the ZSM-5 could be a more suitable solid matrix for heterogeneous Fenton reactions than S-1 and TS-1.

Highlights

  • Three different Fe-doped MFI zeolites have been prepared using hydrothermal synthesis.

  • UV–Vis DRS confirms that Fe has been incorporated into the framework of S-1, TS-1, and ZSM-5.

  • The degradation efficiency of FeZSM-5 is the highest owing to its higher hydrophilic property, larger external specific surface area, and more negative zeta potential value.

  • The ZSM-5 could be a more suitable solid matrix for heterogeneous Fenton reactions than S-1 and TS-1.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (2018YFB0604902), the National Basic Research Program of China (973 Program) (Grant No: 2012CB720302), and the National Key Research and Development Program of China (2016YFF0102503).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300350, China

    Senlin Deng, Xubin Zhang, Guojun Lv, Yi Zhai, Zebin Yang & Fumin Wang

  2. College of Chemistry and Chemical Engineering, Qinghai Nationalities University, Xining, 810007, China

    Yongqiang Zhu & Haichao Li

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  1. Senlin Deng
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  2. Xubin Zhang
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  3. Guojun Lv
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  4. Yi Zhai
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  7. Haichao Li
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Correspondence to Xubin Zhang or Fumin Wang.

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Deng, S., Zhang, X., Lv, G. et al. Influence of zeolite carriers on the dyes degradation for framework Fe-doped zeolite catalysts. J Sol-Gel Sci Technol 91, 54–62 (2019). https://doi.org/10.1007/s10971-019-05030-2

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  • DOI: https://doi.org/10.1007/s10971-019-05030-2

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