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Mullite crystallization using fully hydrolyzed silica sol: the gelation temperature influence

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Abstract

Mullite is an aluminosilicate widely used as a structural material for high temperature applications. This paper studies the effect of the gelation temperature on the synthesis of two mullite precursors: polymeric and colloidal silica, using both in fully-hydrolyzed silica sol, derived from sodium silicate. The gels were synthesized using aqueous silicic acid and aluminum nitrate. Ethylene glycol was added into polymeric gels. Two gelation temperatures were used: 80 and 100 °C. In the polymeric precursor, the increasing of the gelation temperature caused an increase in the silica incorporation inside the mullite crystalline lattice at 1,000 °C, and it also generated an increase in the reaction extent at all calcination temperatures. In the colloidal precursors, these effects were more intense than in the polymeric precursors in terms of yield. Colloidal samples calcined at 1,250 °C crystallized cristobalite and alpha alumina in addition to mullite when they were previously gelled at 80 °C. On the other hand, the same sample gelled at 100 °C led to only crystallized mullite. The reaction extent increased by more than 20 % for colloidal samples gelled at 100 °C compared to colloidal samples gelled at 80 °C (calcined at 1,250 °C). This increase was due to the almost total incorporation of alumina and silica in the crystalline lattice of mullite.

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Authors and Affiliations

  1. Divisão de Ciências Fundamentais, Departamento de Física, Instituto Tecnológico de Aeronáutica, Praça Marechal Eduardo Gomes, 50 - Vila das Acácias, São José dos Campos, SP, 12.228-900, Brazil

    Tiago M. B. Campos, Luciana S. Cividanes, Evelyn A. N. Simonetti & Gilmar P. Thim

  2. Instituto Nacional de Pesquisas Espaciais, São José dos Campos, SP, Brazil

    João Paulo B. Machado

  3. Universidade do Vale do Paraíba, São José dos Campos, SP, Brazil

    Liana A. Rodrigues

Authors
  1. Tiago M. B. Campos
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  2. Luciana S. Cividanes
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  3. João Paulo B. Machado
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  4. Evelyn A. N. Simonetti
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  5. Liana A. Rodrigues
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  6. Gilmar P. Thim
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Correspondence to Luciana S. Cividanes.

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Campos, T.M.B., Cividanes, L.S., Machado, J.P.B. et al. Mullite crystallization using fully hydrolyzed silica sol: the gelation temperature influence. J Sol-Gel Sci Technol 72, 219–226 (2014). https://doi.org/10.1007/s10971-014-3285-9

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  • DOI: https://doi.org/10.1007/s10971-014-3285-9

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