Abstract
Pure BiFeO3 and Er-doped BiFeO3 (Bi0.9Er0.1FeO3) thin films were successfully fabricated on cleaned Si (100) substrates by a simple spin-coating processing. X-ray diffraction and Raman spectroscopy indicated the substitutions of Er into the Bi site and a change in crystal structure in Bi0.9Er0.1FeO3 thin film. Scanning electron microscope and transmission electron microscope were used to analyze the morphologies and microstructures of the thin films. X-ray photoemission spectroscopy result indicated that the oxidation state of Fe ion was Fe3+ in the Bi0.9Er0.1FeO3 thin film without detectable Fe2+. In comparison with the BiFeO3 thin film studied here, the Bi0.9Er0.1FeO3 thin film showed the surprising remnant magnetization and saturation magnetization. The remnant magnetization of Bi0.9Er0.1FeO3 thin film was nearly 5 times as large as that of BiFeO3 thin film. Moreover, the possible reasons for the enhancement of magnetization were discussed in detail. These results will have some implications for further research.
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Zhou HF, Hou ZL, Kong LB, Jin HB, Cao MS, Qi X (2013) Phys Status Solidi A 210:809–813
Ramesh R, Spaldin NA (2007) Nature Mater 6:21–29
Wu J, Wang J, Xiao D, Zhu J (2012) ACS Appl Mater Interfaces 4:1182–1185
Agarwal A, Sanghi S, Ashima AN, Monica (2012) J. Appl. Phys 111:113917
Pradhan SK, Roul BK (2012) J Sol-Gel Sci Technol 64:375–380
Cheong S, Mostovoy M (2007) Nature Mater 6:13–20
Wang J, Neaton JB, Zheng H, Nagarajan V, Ogale SB, Liu B, Viehland D, Vaithyanathan V, Schlom DG, Waghmare UV, Spaldin NA, Rabe KM, Wuttig M, Ramesh R (2003) Science 299:1719–1722
Gustau C, James FS (2009) Adv Mater 21:2463–2485
Indrani C, Neeraj P, Amit T, Igor B, Kholkin AL, Venkata SP, Ram SK (2012) Thin Solid Films 520:6493–6498
Chinnambedu MR, Dalhyun D, Jin WK, Kim WJ, Sang SK (2012) J Am Ceram Soc 95:1933–1938
Si HY, Li YTi, Liu H, Che JS, Chow GM (2012) J Sol-Gel Sci Technol 64 64:104–109
Qian FZ, Jiang JS, Jiang DM, Zhang WG, Liu JH (2010) J Phys D Appl Phys 43:025403–025409
Dzyaloshinsky I (1958) J Phys Chem Solids 4:241–255
Moriya T (1960) Phys Rev 120:91–98
Sosnowska I, Peterlin-Neumaier T, Steichele E (1982) J Phys C Solid State Phys 15:4835–4846
Aguiar EC, Ramirez MA, Moura F, Varela JA, Longo E, Simões AZ (2013) Ceram Int 39:13–20
Lee YH, Wu JM, Lai CH (2006) Appl Phys Lett 88:042903
Khomchenko VA, Karpinsky DV, Kholkin AL, Sobolev NA, Kakazei GN, Araujo JP, Troyanchu IO, Costa BFO, Paixao JA (2010) J Appl Phys 108: 074109–074109–5
Guo R, Fang L, Dong W, Zheng F, Shen M (2010) J Phys Chem C 114:21390–21396
Kumar A, Varshney D (2012) Ceram Int 38:3935–3942
Lan C, Jiang Y, Yang J (2011) Mater Sci 46:734–738
Hu Z, Li M, Yu B, Pei L, Liu J, Wang J, Zha X (2009) J Phys D Appl Phys 42:185010
Ostos C, Raymond O, Suarez-Almodovar N, Bueno-Baques D, Mestres L, Siqueiros JM (2011) J Appl Phys 110: 024114–024114–7
Simões AZ, Pianno RF, Aguiar EC, Longo E, Varela JA (2009) J Alloys Compd 479:274–279
Wen Z, You L, Shen X, Li X, Wua D, Wang J, Li A (2011) Mater Sci Eng. B 176:990–995
Yang X, Guo H, Chen K, Zhang W, Lou L, Yin M (2004) J Rare Earth 22:36–39
Radheshyam R, Sunil KM, Singh NK, Seema S, Andrei LK (2011) Curr Appl Phys 11:508–512
Manoj KS, Prellier W, Hyun MJ, Ram SK (2009) Solid State Commun 149:1971–1973
Ashish G, Singh K, Sen K, Kotnala RK, Singh M (2011) Mater Lett 65:591–594
Yuan GL, Or SW, Chan HLW; Liu ZG (2007) J Appl Phys 101: 024106–024106–4
Ternon C, Thery J, Baron T, Ducros C, Sanchette F, Kreisel J (2006) Thin Solid Films 515:481–484
Mishra RK, Pradhan DK, Choudhary RNP, Banerjee A (2008) J Phys Condens Matter 20:045218–045223
Park TJ, Papaefthymiou GC, Viescas AJ, Moodenbaugh AR, Wong SS (2007) Nano Lett 7(3):766–772
Ryu S, Kim J-Y, Shin Y-H, Park B-G, Son JY, Jang HM (2009) Chem Mater 21:5050–5057
Liu J, Fang L, Zheng FG, Ju S, Shen MR (2009) Appl Phys Lett 95:022511
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This work is supported by the National Natural Science Foundation of China (Grant Nos. 61178074), the Program for the development of Science and Technology of Jilin province (Item No. 201215223), the Program for the development of Science and Technology of Jilin province (Item No. 201115218), the Natural Science Foundation of Jiangsu Province of China (BK2010348).
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Liu, Y.Q., Zhang, J., Wu, Y.H. et al. Enhancement of magnetization in Er doped BiFeO3 thin Film. J Sol-Gel Sci Technol 67, 1–7 (2013). https://doi.org/10.1007/s10971-013-3044-3
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DOI: https://doi.org/10.1007/s10971-013-3044-3