Skip to main content

Advertisement

SpringerLink
Log in

Synthesis of HAP coating on galvanostatically treated stainless steel substrates by sol–gel method

  • Original Paper
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

Producing bioactive hydroxyapatite coatings on metallic implant materials combines the mechanical advantages of implant materials and biological affinity of the hydroxyapatite surface to the natural tissue. In this work, hydroxyapatite was synthesized on 316L stainless steel substrates via sol–gel method by using Ca(NO3)2·4H2O and C6H15O3P. In order to improve adherence of the coatings produced, the surface of the substrate was initially modified by electrodepositing nucleus of calcium phosphate compounds. Effect of aging time for preparation of the sol solution and coating characteristics were investigated. The phase compositions and structures of the coatings were characterized by X-ray diffractometry, and scanning electron microscopy was used to determine morphological characteristics of the coatings. Adhesion between the hydroxyapatite coating and the substrate was investigated by using scanning scratch tester. The coating produced on the modified surface by the sol solution aged for 24 h was found to prove better morphological and adhesion properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Wen CE, Xu W, Hu WY et al (2007) Acta Biomater 3:403. doi:10.1016/j.actbio.2006.10.004

    Article  PubMed  CAS  Google Scholar 

  2. Bogdanoviciene I, Beganskiene A, Tonsuaadu K et al (2006) Mater Res Bull 41:1754. doi:10.1016/j.materresbull.2006.02.016

    Article  CAS  Google Scholar 

  3. Tkalcec E, Sauer M, Nonninger R et al (2001) J Mater Sci 36:5253. doi:10.1023/A:1012462332440

    Article  CAS  Google Scholar 

  4. Byung-Hoon K, Jeong J, Jeon Y et al (2007) Ceram Int 33:119. doi:10.1016/j.ceramint.2005.08.002

    Article  Google Scholar 

  5. Cheng K, Zhang S, Weng W et al (2006) Thin Solid Films 515:135. doi:10.1016/j.tsf.2005.12.051

    Article  ADS  CAS  Google Scholar 

  6. Huang L, Xu K (2000) J Mater Sci Mater Med 11:667. doi:10.1023/A:1008934522363

    Article  PubMed  CAS  Google Scholar 

  7. Liu DM, Chou HM, Wu JD (1994) J Mater Sci Mater Med 5:147. doi:10.1007/BF00053335

    Article  Google Scholar 

  8. Berndt C, Haddad G, Farmer A et al (1990) Mater Forum 14:161

    CAS  Google Scholar 

  9. Ducheyne P, Cuckler JM (1992) Clin Orthop Relat Res 276:102

    PubMed  Google Scholar 

  10. Ducheyne P, Van Raemdonck W, Heughebaert JC et al (1990) Biomaterials 11:244. doi:10.1016/0142-9612(90)90005-B

    Article  PubMed  CAS  Google Scholar 

  11. Monma H (1993) J Ceram Soc Jpn Int Edn 101:718

    Google Scholar 

  12. Manso M, Jimenez C, Morant C et al (2000) Biomaterials 21:1755. doi:10.1016/S0142-9612(00)00061-2

    Article  PubMed  CAS  Google Scholar 

  13. Torrisi L, Foti G, Ke V (1993) Appl Phys Lett 62:237. doi:10.1063/1.108976

    Article  ADS  CAS  Google Scholar 

  14. Cotell CM (1993) Appl Surf Sci 69:140. doi:10.1016/0169-4332(93)90495-W

    Article  ADS  CAS  Google Scholar 

  15. Brinker CJ, Scherrer GW (1992) Sol–gel science: the physics and chemistry of sol–gel processing. Academic Press, New York

    Google Scholar 

  16. Liu D, Troczynskia T, Tseng WJ (2002) Biomaterials 23:1227. doi:10.1016/S0142-9612(01)00242-3

    Article  PubMed  CAS  Google Scholar 

  17. Liu D, Yang Q, Troczynski T (2002) Biomaterials 23:691. doi:10.1016/S0142-9612(01)00157-0

    Article  PubMed  CAS  Google Scholar 

  18. Garcia C, Cere S, Duran A (2004) J Non Cryst Solids 348:218. doi:10.1016/j.jnoncrysol.2004.08.172

    Article  ADS  CAS  Google Scholar 

  19. Balamurugan A, Kannan S, Rajeswari S (2004) Can Metall Q 43:293

    CAS  Google Scholar 

  20. Balamurugan A, Balossier G, Kannan S et al (2006) Mater Lett 60:2288. doi:10.1016/j.matlet.2005.12.126

    Article  CAS  Google Scholar 

  21. Misra RDK, Mali SA, Nayak SS et al (2008) Scr Mater 59:834. doi:10.1016/j.scriptamat.2008.06.017

    Article  CAS  Google Scholar 

  22. Hshieh MF, Pwerng LH, Chin TS (2002) Mater Chem Phys 74:245. doi:10.1016/S0254-0584(01)00474-6

    Article  Google Scholar 

  23. Fernandez-Pradas JM, Garcia-Cuenca MV, Cleries L et al (2002) Appl Surf Sci 195:31. doi:10.1016/S0169-4332(02)00002-8

    Article  ADS  CAS  Google Scholar 

  24. Wang J, Layrolle P, Stigter M et al (2004) Biomaterials 25:583. doi:10.1016/S0142-9612(03)00559-3

    Article  PubMed  CAS  Google Scholar 

  25. Schaffer UE, Kleer G (2000) Surf Coat Tech 133:215. doi:10.1016/S0257-8972(00)00939-7

    Article  Google Scholar 

  26. Han Y, Fu T, Lu J et al (2001) J Biomed Mater Res 54:96. doi:10.1002/1097-4636(200101)54:1<96::AID-JBM11>3.0.CO;2-U

    Article  PubMed  CAS  Google Scholar 

  27. Monma H (1993) J Ceram Soc Jpn 101:737

    CAS  Google Scholar 

  28. Shih W, Chen Y, Wang S et al (2005) J Cryst Growth 285:633. doi:10.1016/j.jcrysgro.2005.08.042

    Article  ADS  CAS  Google Scholar 

  29. Shirkhanzadeh M (1993) J Mater Sci Lett 12:16

    CAS  Google Scholar 

  30. Liu D, Troczynski T, Hakimi DJ (2002) J Mater Sci Mater Med 13:657. doi:10.1023/A:1015733624638

    Article  PubMed  CAS  Google Scholar 

  31. Ben-Nissan B, Green D, Kannangara G et al (2001) J Sol Gel Sci Technol 21:27. doi:10.1023/A:1011281826850

    Article  CAS  Google Scholar 

  32. Gross K, Chai C, Kannagara G et al (1998) J Mater Sci Mater Med 9:839. doi:10.1023/A:1008948228880

    Article  PubMed  CAS  Google Scholar 

  33. Gee A, Deitz VR (1955) J Am Ceram Soc 77:2961

    CAS  Google Scholar 

  34. Daculsi G (1998) Biomaterials 19:1473. doi:10.1016/S0142-9612(98)00061-1

    Article  PubMed  CAS  Google Scholar 

  35. Instruction Manual (2002) Schimadzu scanning scratch tester SSt-W101, Schimadzu Corporation: 4

Download references

Acknowledgments

The authors would like to acknowledge the support provided by The Scientific & Technical Research Council of Turkey, under project number MISAG-259 and T.R. Prime Ministry State Planning Organization for providing the infrastructure of our laboratories.

Author information

Authors and Affiliations

  1. Department of Metallurgical and Materials Engineering, Faculty of Engineering, Dokuz Eylul University, 35160, Buca, Izmir, Turkey

    F. Ak Azem & A. Cakir

Authors
  1. F. Ak Azem
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Cakir
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Ak Azem.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ak Azem, F., Cakir, A. Synthesis of HAP coating on galvanostatically treated stainless steel substrates by sol–gel method. J Sol-Gel Sci Technol 51, 190–197 (2009). https://doi.org/10.1007/s10971-009-1964-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-009-1964-8

Keywords

Search

Navigation