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New photo-Fenton type catalyst of soda-lime aluminosilicate glass prepared by recycling waste slag–a review

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Abstract

In this review, the structure of iron-containing soda-lime aluminosilicate glass–ceramics prepared by domestic waste slag from waste combustion plants in Japan and its simulated composite was investigated by 57Fe-Mössbauer spectroscopy. The photo-Fenton catalytic ability of the samples was evaluated by a degradation test using an aqueous methylene blue (MB) solution. The photo-Fenton catalytic efficacy of the specimens was assessed through a degradation examination employing an aqueous methylene blue (MB) solution. The MB degradation test recorded a k value of 2.25–2.65 × 10–3 min−1 using the composite of (silicate + iron oxide nanoparticles) prepared from domestic waste slag. The 57Fe-Mössbauer spectra were mainly composed of three sextets due to nanoparticles of Fe3O4 and α-Fe2O3. After exploring the chemical composition of soda lime iron aluminosilicates as domestic waste-modeled slag, we revealed that heat-treated simulated slag samples of 5Na2O-41.4CaO-20Al2O3-27.6SiO2-6Fe2O3 glass showed the largest k value of 115 × 10–3 min−1 under photo-Fenton reaction which highly covalent distorted FeIIIO4 caused. It is concluded that municipal waste slag can be a starting material for the Photo-Fenton catalyst with high activity, which contributes purification of wastewater.

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Acknowledgements

One of the authors (A.I.) expresses his gratitude for the financial support by Grant-in-Aid for Scientific Research Hoga (KAKENHI, No. 26630321) and Tokyo Metropolitan Government Advanced Research Grant No. H29-1.

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Authors and Affiliations

  1. Department of Chemistry, Tokyo Metropolitan University, Tokyo, 192-0397, Japan

    A. Ibrahim & S. Kubuki

  2. Department of Physics, Faculty of Science, Al-Azhar University, Assiut, 71542, Egypt

    A. S. Ali

  3. Centre for Energy Research, Surface Chemistry and Catalysis Department, Konkoly-Thege Út 29-33, Budapest, 1121, Hungary

    I. Khan

  4. Xuefu Road 301, Jingkou District, Zhenjiang City, Jiangsu Province, China

    B. Zhang

  5. Institute of Chemistry, Eötvös Loránd University, Pázmány P. S. 1/A, Budapest, 1117, Hungary

    K. Sinkό, Z. Homonnay & E. Kuzmann

  6. Division of Materials Chemistry, Ruđer Bošković Institute, Bijenička 54, Zagreb, Croatia

    S. Krehula, M. Ristić, S. Musić, L. Pavić & A. Santić

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  1. A. Ibrahim
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  2. A. S. Ali
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Correspondence to A. Ibrahim.

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Ibrahim, A., Ali, A.S., Khan, I. et al. New photo-Fenton type catalyst of soda-lime aluminosilicate glass prepared by recycling waste slag–a review. J Radioanal Nucl Chem 332, 3859–3878 (2023). https://doi.org/10.1007/s10967-023-09127-5

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