Abstract
A chelating fiber (CF), containing amine and hydroxyl groups, has been characterized and used as an adsorbent for the removal of U(VI) from aqueous solutions. The effects of pH value, contact time, adsorbent dosage, initial U(VI) concentration, temperature, and stripping agents on the adsorption behavior of U(VI) are studied. The results demonstrated that the maximum adsorption capacity is achieved at pH 3.0 and contact time 20 min. The adsorption behavior can be well described by the pseudo-second order kinetic and the Langmuir isotherm model equations. Additionally, it was found that the adsorbent can be reused for five repeating cycles.
Similar content being viewed by others
References
Singhal RK, Basu H, Pimple MV, Manisha V, Basan MKT, Reddy AVR (2013) Spectroscopic determination of U(VI) species sorbed by the Chlorella (Chlorella pyrenoidosa) fresh water algae. J Radioanal Nucl Chem 298(1):587–592
Singhal RK, Joshi VM, Preetha J, Karpe R, Kumar A, Hegde AG (2007) Determination of ultra trace level of uranium in ground water of different geo-chemical environment by adsorptive stripping voltammetry. Water Air Soil Pollut 184(1–4):17–27
Calì E, Qi J, Preedy O, Chen S, Boldrin D, Branford WR, Vandeperrea L, Ryanab MP (2018) Functionalised magnetic nanoparticles for uranium adsorption with ultra-high capacity and selectivity. J Mater Chem A 6:3063–3073
Feng ML, Sarma D, Qi XH, Du KZ, Huang XY, Kanatzidis MG (2016) Efficient removal and recovery of uranium by a layered organic–inorganic hybrid thiostannate. J Am Chem Soc 138(38):12578–12585
Mondal S, Kumar V, Singh DK, Sharma JN, Sreenivas T, Kain V (2017) Process for recovery of uranium from low grade SDU of phosphoric acid/D2EHPA-TBP plant origin using DHOA/n-dodecane solvent. Sep Purif Technol 189:341–346
Nazal MK, Albayyari MA, Khalili FI, Asoudani E (2017) Synergistic effect of tri-n-butyl phosphate (TBP) or tri-n-octyl phosphine oxide (TOPO) with didodecylphosphoric acid (HDDPA) on extraction of uranium(VI) and thorium(IV) ions. J Radioanal Nucl Chem 312(1):133–139
Singh DK, Hareendran KN, Sreenivas T, Kain V, Dey GK (2017) Development of a phosphate precipitation method for the recovery of uranium from lean tenor alkaline leach liquor. Hydrometallurgy 171:228–235
Pang L, Zhang L, Hu J, Liang Y, Zhang M, Wu G (2017) High-performance functionalized polyethylene fiber for the capture of trace uranium in water. J Radioanal Nucl Chem 314(3):2393–2403
Yang S, Qian J, Kuang L, Hua D (2017) Ion-imprinted mesoporous silica for selective removal of uranium from highly acidic and radioactive effluent. ACS Appl Mater Interfaces 9(34):29337–29344
Tan L, Zhang X, Liu Q, Wang J, Sun Y, Jing X, Liu J, Song D, Liu L (2015) Preparation of magnetic core–shell iron oxide@silica@nickel-ethylene glycol microspheres for highly efficient sorption of uranium(VI). Dalton Trans 44:6909–6917
Guo X, Feng Y, Ma L, Yu J, Jing J, Gao D, Khan AS, Gong H, Zhang Y (2018) Uranyl ion adsorption studies on synthesized phosphoryl functionalised MWCNTs: a mechanistic approach. J Radioanal Nucl Chem 316(1):397–409
Yang C, Niu D, Zhong Y, Li L, Lv H, Liu Y (2018) Adsorption of uranium by hydrous manganese dioxide from aqueous solution. J Radioanal Nucl Chem 315(3):533–542
Xu G, Wang L, Xie Y, Tao M, Zhang W (2018) Highly selective and efficient adsorption of Hg2+ by a recyclable aminophosphonic acid functionalized polyacrylonitrile fiber. J Hazard Mater 344:679–688
Zhang L, Zhang X, Li P, Zhang W (2009) Effective Cd2+ chelating fiber based on polyacrylonitrile. React Funct Polym 69(1):48–54
Recepoğlu YK, Kabay N, Ipek IY, Arda M, Yüksel M, Yoshizuka K, Nishihama S (2018) Packed bed column dynamic study for boron removal from geothermal brine by a chelating fiber and breakthrough curve analysis by using mathematical models. Desalination 437:1–6
Wang G, Liu J, Wang X, Xie Z, Deng N (2009) Adsorption of uranium (VI) from aqueous solution onto cross-linked chitosan. J Hazard Mater 168(2–3):1053–1058
Singhal RK, Basu H, Bassan MKT, Pimple MV, Manisha V, Avhad DK, Sharma PK, Reddy AVR (2012) Rapid and interference free determination of ultra trace level of uranium in potable water originating from different geochemical environments by ICP-OES. J Radioanal Nucl Chem 292(2):675–681
Thomsen V, Schatzlein D, Mercuro D (2003) Limits of detection in spectroscopy. Spectroscopy 18(12):112–114
Hu H, Zhang X, Wang T, Sun L, Wu H, Chen X (2018) Bamboo (Acidosasa longiligula) shoot shell biochar: its potential application to isolation of uranium(VI) from aqueous solution. J Radioanal Nucl Chem 316(1):349–362
Neghlani PK, Rafizadeh M, Taromi FA (2011) Preparation of aminated-polyacrylonitrile nanofiber membranes for the adsorption of metal ions: comparison with microfibers. J Hazard Mater 186(1):182–189
Gupta A (2017) Preparation of ethyleneamine functionalized crosslinked poly(acrylonitrile-ethylene glycol-dimethacrylate) chelating resins for adsorption of lead ions. Sep Sci Technol 52(3):447–455
Deng S, Bai R (2004) Removal of trivalent and hexavalent chromium with aminated polyacrylonitrile fibers: performance and mechanisms. Water Res 38(9):2424–2432
Li F, Li D, Li X, Liao J, Li S, Yang J, Yang Y, Tang J, Liu N (2016) Microorganism-derived carbon microspheres for uranium removal from aqueous solution. Chem Eng J 284:630–639
Basu H, Singhal RK, Saha S, Pimple MV (2017) Chitosan impregnated Ca-alginate: a new hybrid material for removal of uranium from potable water. J Radioanal Nucl Chem 314(3):1905–1914
Zhang S, Zeng M, Li J, Li J, Xu J, Wang X (2014) Porous magnetic carbon sheets from biomass as an adsorbent for the fast removal of organic pollutants from aqueous solution. J Mater Chem A 2:4391–4397
Sadeghi S, Azhdari H, Arabi H, Moghaddam AZ (2012) Surface modified magnetic Fe3O4 nanoparticles as a selective sorbent for solid phase extraction of uranyl ions from water samples. J Hazard Mater 215–216:208–216
Khawassek YM, Masoud AM, Taha MH, Hussein AEM (2018) Kinetics and thermodynamics of uranium ion adsorption from waste solution using Amberjet 1200 H as cation exchanger. J Radioanal Nucl Chem 315(3):493–502
Nguyen-Trung C, Begun GM, Palmer DA (1992) Aqueous uranium complexes. 2. Raman spectroscopic study of the complex formation of the dioxouranium(VI) ion with a variety of inorganic and organic ligands. Inorg Chem 31(25):5280–5287
Acknowledgements
This work was financially supported by the Doctor Research Foundation of Southwest University of Science and Technology (Grant 16zx7156) and the Longshan academic talent research supporting program of Southwest University of Science and Technology (17LZX531, 18LZXT03). Funding from the Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory (Grant No. 16kfhk01), the China National Natural Science Foundation (Grant No. 41502316) and the Post-Doctor Foundation of China (Grant No. 2017M612991) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
He, Y., Wang, X., Nie, X. et al. Uranium(VI) removal from aqueous solutions by a chelating fiber. J Radioanal Nucl Chem 317, 1005–1012 (2018). https://doi.org/10.1007/s10967-018-5956-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-018-5956-4