Abstract
Effect of gamma radiation on morphology, mechanical properties and hydrophobicity of hollow fibers made from different polymeric materials, such as poly ether–ether ketone with Card (PEEK-WC), polysulfone, polyacrylonitrile and polyvinyl fluoride was studied by measuring various mechanical properties, such as tensile strength and Young modulus. Mass transport studies of Am(III) with hydrophobic PEEK-WC hollow fibre impregnated with N,N,N′,N′-tetraoctyl diglycolamides (TODGA) gave 30 ± 4 % retention of Am(III) in 30 min. Retention of Am(III) was unaffected after irradiating the fibers to 60 and 120 kGy.
Similar content being viewed by others
References
Choppin GR, Morgenstern A (2000) Radionuclide separations in radioactive waste disposal. J Radioanal Nucl Chem 243:45–51
Holder JV (1978) A review of the solvent extraction process chemistry of fission products. Radiochim Acta 25:171–180
Kastenberg WE, Gratton LJ (1997) Hazardous of managing and disposing of nuclear wastes. Phys Today 50:41–47
Ansari SA, Kandwal P, Mohapatra PK (2015) Liquid membranes for studies involving nuclear waste remediation using hollow-fiber contactors. In: Pabby AK, Rizvi SSH, Sastre AM (eds) Handbook of membrane separations. Chemical, pharmaceutical, food and biotechnological applications, 2nd edn. CRC Press, Boca Raton, p 787
Zakrzewska-Trznadel G (2013) Advances in membrane technologies for the treatment of liquid radioactive waste. Desalination 321:119–130
Pubby AK, Sastre AM (2013) State-of-the-art review on hollow fibre contactor technology and membrane-based extraction processes. J Membr Sci 430:263–303
Ansari SA, Mohapatra PK, Raut DR, Adya VC, Tulsidas SK, Manchanda VK (2008) Separation of Am(III) and trivalent lanthanides from simulated high level waste using hollow fiber supported liquid membrane. Sep Purif Technol 63:239–242
Ansari SA, Mohapatra PK, Raut DR, Kumar M, Rajeswari B, Manchanda VK (2009) Performance of actinide partitioning extractants in hollow fibre supported liquid membrane for the transport of actinides and lanthanides from high level nuclear waste. J Membr Sci 337:304–309
Ansari SA, Mohapatra PK, Manchanda VK (2009) Recovery of actinides and lanthanides from high level waste using hollow fiber supported liquid membrane with TODGA as the carrier. Ind Eng Chem Res 48:8606–8612
Bhattacharyya A, Mohapatra PK, Ansari SA, Raut DR, Manchanda VK (2008) Separation of trivalent actinides from lanthanides using hollow fibre supported liquid membrane containing Cyanex-301 as carrier. J Membr Sci 312:1–5
Ansari SA, Chaudhury S, Mohapatra PK, Aggarwal SK, Manchanda VK (2013) Recovery of plutonium from analytical laboratory waste using hollow fibre supported liquid membrane technique. Sep Sci Technol 48:208–214
Ansari SA, Gujar RB, Mohapatra PK, Kandwal P, Sengupta A, Thulasidas SK, Manchanda VK (2011) A ‘cold’ actinide partitioning run at 20 L scale with hollow fibre supported liquid membrane using diglycolamide extractants. Radiochim Acta 99:815–821
Bhattacharyya A, Ansari SA, Kandwal P, Mohapatra PK, Manchanda VK (2011) Selective recovery of Am(III) over Eu(III) by hollow fibre supported liquid membrane using Cyanex 301 in the presence of synergists as the carrier. Sep Sci Technol 46:205–214
Kandwal P, Ansari SA, Mohapatra PK (2012) A highly efficient supported liquid membrane system for near quantitative recovery of radio-strontium from acidic feeds: part II. Scale up and mass transfer modeling in hollow fiber configuration. J Membr Sci 405–406:85–91
Kandwal P, Ansari SA, Mohapatra PK (2011) Transport of cesium using hollow fiber supported liquid membrane containing calix[4]arene-bis(2,3-naphtho)crown-6 as the carrier extractant: part II. Recovery from simulated high level waste and mass transfer modeling. J Membr Sci 384:37–43
Ansari SA, Bhattacharyya A, Raut DR, Mohapatra PK, Manchanda VK (2009) Separation of actinides using hollow fiber supported liquid membranes. Radiochim Acta 97:149–153
Adya VC, Sengupta A, Ansari SA, Mohapatra PK, Bhide MK, Godbole SV (2013) Application of hollow fiber supported liquid membrane for the separation of americium from the analytical waste. J Radioanal Nucl Chem 295:1023–1028
Figoli A, Simone S, Criscuoli A, Al-Jlil SA, Al Shabouna FS, Al-Romaih HS, Al-Harbi OA, Di Nicolò E, Drioli E (2014) Hollow fibers for seawater desalination from blends of PVDF with different molecular weights: morphology, properties and VMD performance. Polymer 55:1296–1306
Drioli E, Ali A, Simone S, Macedonio F, Al-Jlil SA, Al Shabonah FS, Al-Romaih HS, Al-Harbi O, Figoli A, Criscuoli A (2013) Novel PVDF hollow fiber membranes for vacuum and direct contact membrane distillation applications. Sep Purif Technol 115:27–38
Fakhrali A, Ebadi SV, Gharehaghaji AA (2014) Production of core-sheath nanofiber yarn using two opposite asymmetric nozzles. Fiber Polym 15:2535–2540
Tasselli F, Drioli E (2007) Tuning of hollow fiber membrane properties using different bore fluids. J Membr Sci 301:11–18
Javazmi L, Ravandi SAH, Ghareaghaji AA (2014) Fabrication and characterization of PET nanofiber hollow yarn. Fiber Polym 15:954–960
Mohapatra PK, Raut DR, Ghosh AK, Reddy AVR, Manchanda VK (2013) Radiation stability of several polymeric supports used for radionuclide transport from nuclear wastes using liquid membranes. J Radioanal Nucl Chem 298:807–811
Cassano A, Tasselli F, Conidi C, Drioli E, Timpone R, D’Avella M, Badalamenti F, Corleone V (2013) PAN hollow fibre membranes with triacetyl-β-cyclodextrin for the removal of pesticides from citrus essential oils. Sep Purif Technol 116:124–130
Ansari SA, Pathak PN, Mohapatra PK, Manchanda VK (2012) Chemistry of diglycolamides: promising extractants for actinide partitioning. Chem Rev 112:1751–1772
Chapiro A (1962) General aspects of radiation effects in solid polymers. In: Chapiro A (ed) Radiation chemistry of polymeric systems. Wiley, New York, pp 339–383
Chmielewski AG, Haji-Saeid M, Ahmed S (2005) Progress in radiation processing of polymers. Nucl Instrum Meth B 236:44–54
Acknowledgments
The authors (PKM and SAA) are grateful to Dr. P. K. Pujari, Head, Radiochemistry Division, B.A.R.C. for his constant encouragement and keen interest in this work. PKM thanks Board of Research in Nuclear Sciences for funding through DAE-SRC grant.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Mohapatra, P.K., Ansari, S.A., Raut, D.R. et al. Evaluation of radiation resistance of hollow fibers for possible application in radioactive waste treatment. J Radioanal Nucl Chem 311, 673–679 (2017). https://doi.org/10.1007/s10967-016-5072-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-016-5072-2