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Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water

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Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1·Cs+(nb) ⇔1·C+ (nb) + Cs+(aq) taking place in the two–phase water–nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, protonated tyramine, protonated dopamine, protonated DL–noradrenaline; 1 = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1·C+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: protonated tyramine < protonated dopamine < triethanolammonium < diethanolammonium < protonated DL-noradrenaline < propylammonium < ethanolammonium < ethylammonium < methylammonium.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society,” and by the Czech Ministry of Education, Youth, and Sports, Project MSM 6046137307.

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic

    E. Makrlík

  2. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    P. Vaňura

  3. Nuclear Research Institute, 250 68, Řež, Czech Republic

    P. Selucký

Authors
  1. E. Makrlík
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  2. P. Vaňura
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  3. P. Selucký
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Correspondence to E. Makrlík.

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Makrlík, E., Vaňura, P. & Selucký, P. Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water. J Radioanal Nucl Chem 295, 2077–2081 (2013). https://doi.org/10.1007/s10967-012-2216-x

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  • DOI: https://doi.org/10.1007/s10967-012-2216-x

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