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Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate

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Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + NaL+ (nb) ⇔ ML+ (nb) + Na+ (aq) taking place in the two-phase water–nitrobenzene system (M+ = H3O+, \( {\text{NH}}_{4}{}^{+} \), Ag+, Tl+; L = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following order: \( {\text{Ag}}^{ + } \, < \,\hbox{NH}_{4}{}^{ + } \, < \,{\text{H}}_{ 3} {\text{O}}^{ + } \, < \,{\text{Na}}^{ + } \, < \,{\text{Tl}}^{ + }.\)

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Acknowledgments

This work was supported by the Czech Ministry of Education, Youth and Sports, Projects MSM 4977751303 and MSM 6046137307.

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Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Husova 11, 306 14, Pilsen, Czech Republic

    E. Makrlík

  2. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    P. Vaňura

Authors
  1. E. Makrlík
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  2. P. Vaňura
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Correspondence to E. Makrlík.

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Makrlík, E., Vaňura, P. Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate. J Radioanal Nucl Chem 289, 663–666 (2011). https://doi.org/10.1007/s10967-010-0929-2

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  • DOI: https://doi.org/10.1007/s10967-010-0929-2

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