Skip to main content
Log in

Effect of chemical additives on the stability and performance of suspended-emulsion fracturing fluid formed by associative thickener

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Using suspended-emulsion is one of the important methods to achieve the online-mixing of fracturing fluid. In order to solve the practical problems that the conventional suspended-emulsion fracturing fluid is limited to online mixing and needs additional additives to endow it other function during construction, in this paper, the effect of different chemical additives on the suspended stability, bulk viscosity and other performances of suspended-emulsion fracturing fluid were investigated by different measurements, and the long-term suspension-stability mechanism was revealed by optical microscope analysis. The results show that both the stability and the bulk viscosity of the suspened-emulsion gradually increase with the addition of emulsifier, suspension stabilizer and dispersion stabilizer, whereas the addition of emulsifier APEO can cause the decrease of the viscosity releasing rate. Adding 6.0wt% mixture of OBS with APEO (3:1 mass ratio), 3.0% YJT-180 and 2.4% PAE-2, a suspended-emulsion system with no significant stratification after 90 days, moderate bulk viscosity (321 mPa·s) and high viscosity releasing rate can be formed, in which the fine-dense microscopic morphology with uniform distribution can be vividly seen. Moreover, the addition of APEO and OBS not only can greatly promote the suspension stability, but also can obviously improve the thickening property and temperature-shear resistance of the fracturing fluid through the synergistic interaction, and can positively change the surface tension and contact angle of the gel-breaking liquid because of the high surface activity. It can be concluded that the addition of APEO and OBS to the suspended-emulsion can directly give it the functions of increasing viscosity and assisting discharge, which can provide important guidance for the design of multi-functional and online-mixing fracturing fluids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. Zou G, Pan B, Zhu W et al (2023) Investigation of fracturing fluid flowback in hydraulically fractured formations based on microscopic visualization experiments. Polymers 15:1560

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. Zhou CY, Lei MY, Zhou M et al (2022) Preparation and properties of bifunctional associative polymer with twin tail and long chain structure for shale gas fracturing. Polym Adv Technol 33:1069–1078

    Article  CAS  Google Scholar 

  3. He L, Wang SB, Guo JC et al (2015) Research progress of high salinity water-based fracturing fluid technology. Oilfield Chem 32:621–627

    CAS  Google Scholar 

  4. Lei Q, Guan B, Cai B et al (2019) Technological progress and prospects of reservoir stimulation. Pet Explor Dev 46:605–613

    Article  Google Scholar 

  5. Lei Q, Weng D, Xiong S et al (2021) Progress and development directions of shale oil reservoir stimulation technology of China National Petroleum Corporation. Pet Explor Dev 48:1198–1207

    Article  Google Scholar 

  6. Wu Z, Cui C, Jia P et al (2022) Advances and challenges in hydraulic fracturing of tight reservoirs: a critical review. Energy Geosci 3:427–435

    Article  Google Scholar 

  7. Yang B, Zhao J, Mao J et al (2019) Review of friction reducers used in slickwater fracturing fluids for shale gas reservoirs. J Nat Gas Sci Eng 62:302–313

    Article  Google Scholar 

  8. Zhang Y, Mao J, Zhao J et al (2018) Preparation of a novel ultra-high temperature low-damage fracturing fluid system using dynamic crosslinking strategy. Chem Eng J 354:913–921

    Article  CAS  Google Scholar 

  9. Luo L, Wang Y, Qu G et al (2022) Development and application of integrated multi-function anti-salt thickener. Drill Fluid Complet Fluid 39:383–389

    CAS  Google Scholar 

  10. Al-Hajri S, Negash BM, Rahman MM et al (2022) Perspective review of polymers as additives in water-based fracturing fluids. ACS Omega 7:7431–7443

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  11. Liu K, Luo PY, Ding XH et al (2017) Research and application of fast soluble low damage hydrophobic association polymer fracturing fluid. Oilfield Chem 34:433–437

    Google Scholar 

  12. Liu K, Luo PY, Ding XH et al (2017) Performance evaluation of salt-resistant slick-water drag reducer. Oilfield Chem 34:444–448

    CAS  Google Scholar 

  13. Wang L, Wang D, Shen Y et al (2016) Study on properties of hydrophobic associating polymer as drag reduction agent for fracturing fluid. J Polym Res 23:235

    Article  Google Scholar 

  14. Mao J, Xue J, Zhang H et al (2022) Investigation of a hydrophobically associating polymer’s temperature and salt resistance for fracturing fluid thickener. Colloid Polym Sci 300:569–582

    Article  CAS  Google Scholar 

  15. Chi XM (2013) Continuous-mixing fracturing fluid and liquid dispensing device. Oil Forum 32:57–59; 72–73

    Google Scholar 

  16. Jiang LL (2002) Research on development and application of oil-alcohol concentrated fracturing fluid. Harbin Engineering University, Harbin, China

    Google Scholar 

  17. Li KZ (2023) Performance evaluation and application of a multi-functional mixed fracturing fluid. Petrochem Appl 42:53–56

    Google Scholar 

  18. Ye DS, Wang SB, Cai YH et al (2013) Continuous-mixing fracturing fluid and continuous mixing process application practice. Nat Gas Ind 33:47–51

    CAS  Google Scholar 

  19. Zhang QS (2015) Field test study of industrial fracturing technology. Northeast Petroleum University, Daqing, China

    Google Scholar 

  20. Li CH, Qiao MZ, Chen D et al (2023) Performance evaluation of continuously mixed salt-resistant fracturing fluids. Spec Petrochem 40:18–22

    CAS  Google Scholar 

  21. Maieryemuguli A, Pu D, Zhai HJ et al (2022) Development and application of high efficiency drag reducing sand carrying fracturing fluid based on suspension. Oilfield Chem 39:387–392

    Google Scholar 

  22. Zhang PY, He JB, Zhang S et al (2020) Synthesis and performance evaluation of seawater based continuously mixed clean fracturing fluid. Pet Eng Constr 46:242–245

    Google Scholar 

  23. Wei J, Liu TY, Dai XL et al (2020) Preparation and properties of concentration thickener for supramolecular polymer cleaning fracturing fluid. Fine Chem 37:385–390

    Google Scholar 

  24. Zhang YY (2019) Study on synthesis of thickener for emulsion fracturing. Chem Eng Equip 2019:28–31

    Google Scholar 

  25. Wang ZL, Shi SB, Liu XM et al (2022) Synthesis of a mobility regulating agent and research of its adaptability in Gudong reservoir. Chem Eng Oil Gas 51:82–90

    CAS  Google Scholar 

  26. Liu S, Zhao M, Wu Y et al (2022) Development and performance evaluation of a novel silica nanoparticle-reinforced CO2-sensitive fracturing fluid with high temperature and shear resistance ability. Energ Fuel 36:7177–7185

    Article  CAS  Google Scholar 

  27. Zhu BY, Zhang ZQ, Li G et al (2009) Organic modified bentonite and its effect on the physical stability of nicosulfuron oil suspension system. Appl Chem 26:881–884

    CAS  Google Scholar 

  28. Wu J, Luo JS, Wang CJ et al (2023) Experimental study on stability of white oil emulsion and mechanism analysis. Chem Res Application 35:525–531

    Google Scholar 

  29. Liang Y, Guo Y, Yang X et al (2019) Insights on the Interaction between sodium dodecyl sulfate and partially hydrolyzed microblock hydrophobically associating polyacrylamides in different polymer concentration regimes. Colloids Surf A Physicochem Eng Asp 572:152–166

    Article  CAS  Google Scholar 

  30. Calvo F, Gómez JM, Alvarez O et al (2022) Effect of emulsification parameters on the rheology, texture, and physical stability of cosmetic emulsions: a multiscale approach. Chem Eng Res Des 186:407–415

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported financially by the Science and Technology Project of CNPC Western Drilling Engineering Co., LTD (Grant No. 2023XZ201). The authors are grateful for the financial support.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yan Liang, Sukai Wang or Guiyi Zhang.

Ethics declarations

Competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liang, Y., Song, Z., Pu, S. et al. Effect of chemical additives on the stability and performance of suspended-emulsion fracturing fluid formed by associative thickener. J Polym Res 31, 115 (2024). https://doi.org/10.1007/s10965-024-03957-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-024-03957-x

Keywords

Navigation