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Synthesis of polyacrolein organic gel and its adsorption properties on acid fuchsin

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Abstract

In this paper, the organic gel polyacrolein (PAOG) was prepared by NaOH-induced ionic polymerization with acrolein as raw material, which presented good adsorption performance on acid fuchsin (AF). It has been characterized using BET, FT-IR, zeta potential measurements, and XPS to determine the structural and physicochemical properties of PAOG. The adsorption performance was examined in relation to contact time, temperature, and pH value. According to the results, polyacrolein gel adsorbent had a fast adsorption rate, and the adsorption process basically reached equilibrium in the first thirty minutes, which agreed with the pseudo-second-order kinetics. It was determined that the adsorption isotherm conformed to the Langmuir model, which was the endothermic spontaneous reaction (ΔH > 0, ΔG < 0). The five executed adsorption–desorption cycles of AF suggested a good reusability of PAOG. These results can help us better understand the adsorption mechanism of PAOG on AF and provide useful treatment method for removing AF.

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References

  1. Zeng H, Gao M, Shen T et al (2018) Modification of silica nanosheets by gemini surfactants with different spacers and its superb adsorption for rhodamine B. Colloids Surf A Physicochem Eng Aspects 555:746–753

    Article  CAS  Google Scholar 

  2. Visa M, Bogatu C, Duta A (2010) Simultaneous adsorption of dyes and heavy metals from multicomponent solutions using fly ash. Appl Surf Sci 256(17):5486–5491

    Article  CAS  Google Scholar 

  3. Lin S, Chen M (1997) Combined ozonation and ion exchange treatments of textile wastewater effluents. Environ Sci Health Part A 32(7):1999–2010

    Google Scholar 

  4. Wu J, Eiteman MA, Law SE (1998) Evaluation of membrane filtration and ozonation processes for treatment of reactive-dye wastewater. Environ Eng 124(3):272–277

    Article  Google Scholar 

  5. Ovejero G, Sotelo JL, Rodríguez A et al (2011) Wet air oxidation and catalytic wet air oxidation for dyes degradation. Environ Sci Pollut Res 18(9):1518–1526

    Article  CAS  Google Scholar 

  6. Mondal PK, Chauhan B (2012) Microbial degradation of dye-containing wastewater. Microbial Degradation of Xenobiotics. Springer 317–338

  7. Pang YL, Lim S, Ong HC et al (2016) Research progress on iron oxide-based magnetic materials: synthesis techniques and photocatalytic applications. Ceram Int 42(1):9–34

    Article  CAS  Google Scholar 

  8. Kloster GA, Mosiewicki MA, Marcovich NE (2019) Chitosan/iron oxide nanocomposite films: Effect of the composition and preparation methods on the adsorption of congo red. Carbohyd Polym 221:186–194

    Article  CAS  Google Scholar 

  9. Wang J, Yao J, Wang L et al (2020) Multivariate optimization of the pulse electrochemical oxidation for treating recalcitrant dye wastewater. Sep Purif Technol 230:115851

    Article  CAS  Google Scholar 

  10. Dash S, Chaudhuri H, Udayabhanu G et al (2016) Fabrication of inexpensive polyethylenimine-functionalized fly ash for highly enhanced adsorption of both cationic and anionic toxic dyes from water. Energy Fuels 30(8):6646–6653

    Article  Google Scholar 

  11. Haque E, Jun JW, Jhung SH (2011) Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235). Hazard Mater 185(1):507–511

    Article  CAS  Google Scholar 

  12. Zhao S, Chen D, Wei F et al (2017) Removal of Congo red dye from aqueous solution with nickel-based metal-organic framework/graphene oxide composites prepared by ultrasonic wave-assisted ball milling. Ultrason Sonochem 39:845–852

    Article  CAS  PubMed  Google Scholar 

  13. Sonai GG, de Souza SMGU, de Oliveira D et al (2016) The application of textile sludge adsorbents for the removal of Reactive Red 2 dye. Environ Manag 168:149–156

    CAS  Google Scholar 

  14. Chen H, Wageh S, Al-Ghamdi AA et al (2019) Hierarchical C/NiO-ZnO nanocomposite fibers with enhanced adsorption capacity for Congo red. Colloid Interface Sci 537:736–745

    Article  CAS  Google Scholar 

  15. Shah KH, Ghafoor A, Fahad M et al (2019) Natural ferruginous manganese ore as a potential low-cost adsorbent for Congo red dye removal from aqueous solution. Mater Res Express 6(12):125515

    Article  CAS  Google Scholar 

  16. Chaudhuri H, Dash S, Sarkar A (2016) Adsorption of different dyes from aqueous solution using Si-MCM-41 having very high surface area. Porous Mater 23(5):1227–1237

    Article  CAS  Google Scholar 

  17. Lei C, Pi M, Kuang P et al (2017) Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: Isotherm, kinetic and mechanism studies. Colloid Interface Sci 496:158–166

    Article  CAS  Google Scholar 

  18. Favier A, Charreyre MT (2006) Experimental requirements for an efficient control of free-radical polymerizations via the reversible addition-fragmentation chain transfer (RAFT) process. Macromol Rapid Commun 27(9):653–692

    Article  CAS  Google Scholar 

  19. Liu H, Ning S, Li Z et al (2022) Preparation of a novel silica-based N-donor ligand functional adsorbent for efficient separation of palladium from high level liquid waste. Sep Purif Technol 296:121373

    Article  CAS  Google Scholar 

  20. Tang J, Zhang Y-F, Liu Y et al (2020) Efficient ion-enhanced adsorption of congo red on polyacrolein from aqueous solution: Experiments, characterization and mechanism studies. Sep Purif Technol 252:117445

    Article  CAS  Google Scholar 

  21. Tekin N, Şafaklı A, Bingöl D (2015) Process modeling and thermodynamics and kinetics evaluation of Basic Yellow 28 adsorption onto sepiolite. Desalin Water Treat 54(7):2023–2035

    Article  CAS  Google Scholar 

  22. Xu X, Ouyang X-K, Yang L-Y (2021) Adsorption of Pb (II) from aqueous solutions using crosslinked carboxylated chitosan/carboxylated nanocellulose hydrogel beads. Mol Liquids 322:114523

    Article  CAS  Google Scholar 

  23. Fan S, Wang Y, Wang Z et al (2017) Removal of methylene blue from aqueous solution by sewage sludge-derived biochar: Adsorption kinetics, equilibrium, thermodynamics and mechanism. Environ Chem Eng 5(1):601–611

    Article  CAS  Google Scholar 

  24. Li M-F, Liu Y-G, Liu S-B et al (2017) Cu (II)-influenced adsorption of ciprofloxacin from aqueous solutions by magnetic graphene oxide/nitrilotriacetic acid nanocomposite: competition and enhancement mechanisms. Chem Eng 319:219–28

    Article  CAS  Google Scholar 

  25. Yang S, Wu Y, Wu Y et al (2015) Optimizing decolorization of Acid Fuchsin and Acid Orange II solution by MnO2 loaded MCM-41. Taiwan Inst Chem Eng 50:205–214

    Article  Google Scholar 

  26. Mukurala N, Mokurala K, Suman S et al (2021) Synthesis of porous Cu2FeSnS4 particles via solvothermal process for removal of organic acid fuchsin dye pollutant from wastewater. Nano-Struct Nano-Objects 26:100697

    Article  CAS  Google Scholar 

  27. Feng M, Huang Y, Cheng Y et al (2018) Rational design of sulfonated poly (ether ether ketone) grafted graphene oxide-based composites for proton exchange membranes with enhanced performance. Polymer 144:7–17

    Article  CAS  Google Scholar 

  28. Zhang B, Liu L, Wang L et al (2018) Covalent modification of graphene oxide with poly (N-vinylcarbazole) containing pendant azobenzene chromophores for nonvolatile ternary memories. Carbon 134:500–506

    Article  CAS  Google Scholar 

  29. Renita AA, Kumar PS, Jabasingh SA (2019) Redemption of acid fuchsin dye from wastewater using de-oiled biomass: Kinetics and isotherm analysis. Bioresour Technol Rep 7:100300

    Article  Google Scholar 

  30. Mukurala N, Mokurala K, Suman S et al (2021) Synthesis of porous Cu2FeSnS4 particles via solvothermal process for removal of organic acid fuchsin dye pollutant from wastewater. Nano-Struct Nano-Objects 26:100697

    Article  CAS  Google Scholar 

  31. Kalkan E, Nadaroglu H, Celebi N et al (2015) Experimental study to remediate acid fuchsin dye using laccase-modified zeolite from aqueous Solutions. Environ Stud 24(1)

    CAS  Google Scholar 

  32. Li J, Gao Q, Ua Zhang H et al (2012) Effect of MWCNTs doping on the morphology, structure and properties of chitosan beads. Macromol Sci 49(8):674–9

    Article  CAS  Google Scholar 

  33. Zhou Y, Hu X, Zhang M et al (2013) Preparation and characterization of modified cellulose for adsorption of Cd (II), Hg (II), and acid fuchsin from aqueous solutions. Ind Eng Chem Res 52(2):876–884

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by Scientific Research Fund of Hunan Provincial Education Department (No. 21B0306), and Natural Science Foundation of Changsha (No. kq2202184).

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Authors and Affiliations

  1. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation & Hunan Provincial Key Laboratory of Cytochemistry, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, 410114, People’s Republic of China

    Biao Wang, Xin Wan, Ziqian Liu, Jinrong Zhong, Jinglin Tan, Yan Li & Yue-Fei Zhang

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  1. Biao Wang
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  2. Xin Wan
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  3. Ziqian Liu
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  5. Jinglin Tan
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  6. Yan Li
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Correspondence to Yan Li or Yue-Fei Zhang.

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Wang, B., Wan, X., Liu, Z. et al. Synthesis of polyacrolein organic gel and its adsorption properties on acid fuchsin. J Polym Res 29, 483 (2022). https://doi.org/10.1007/s10965-022-03333-7

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