Abstract
In order to understand the influence of FKM surface morphology on wetting performance and tribological properties under high temperature conditions. According to the phenomenon of reducing resistance in the water of natural fish scales, we prepared the FKM with a convex structure using a 2800 mesh screen (which is called 2800FKM), by hot pressing and template replication, based on the fish-scales bionic structure. At 25 °C and 150 °C, the contact angle and rolling angle of the 2800FKM surface were measured, and then we evaluate the bounce behavior and self-cleaning performance of the 2800FKM surface. Finally, under the condition of dry friction and grease lubrication friction, the wear mechanism of 2800FKM was studied by SEM. The results show that compared with FKM, 2800FKM has excellent wetting performance (Contact angle = 143.51°) and heat retention rate (98.89%), and self-cleaning. Compared with FKM, 2800FKM has better anti-wear and antifriction performance under dry friction conditions, and no noticeable wear marks are found under grease lubrication conditions. The main factor of 2800FKM's excellent wetting performance and anti-wear and antifriction function is the fish scale bionic structure. The preparation of 2800FKM provides a new idea for exploring wear-resistant materials with bionic fish scale structure.
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References
Zhang J, Jiab Z, He Q (2021) Mechanical, thermal, and friction properties of addition-type fluororubber co-filled with Al2O3 particles at high temperature. Polym Test 96:107131
Ning M, Li K, Yan C et al (2021) Study on mechanical and tribological properties of ternary fluororubber filled with four needles of zinc oxide. Polym Compos 42:3064–3076
Yang H, Yao XueFeng, Ke Y-C, Ma Y-j, Liu Y-H (2016) Constitutive behaviors and mechanical characterizations of fabric reinforced rubber composites. Compos Struct 152:117–123
Chen Y, Gong Z, Cao L et al (2018) Novel fluorosilicone thermoplastic vulcanizates prepared via core‐shell dynamic vulcanization: Effect of fluororubber/silicone rubber ratio on morphology, crystallization behavior, and mechanical properties. Polym Adv Technol
Hufa W, Shoufeng T, Fenglong M (2018) Development and design of fluororubber kneading machine. China Rubber/Plastics Technol Equip
Ke Y, Yao XueFeng, Yang H, Ma Y (2017) Gas Leakage Prediction of Contact Interface in Fabric Rubber Seal Based on a Rectangle Channel Model. Tribol Trans 60(1):146–153
Zhang Z, Wang YM, Ma LY et al (2020) Ultra-light, heat-resistant, flexible and thermal insulation graphene-fluororubber foam prepared by using N2 as a blowing agent[J]. Colloids Surf, A 604:125310
Wu W, Yu B (2020) The mechanical and thermal properties of KH590-basalt fibre-reinforced silicone rubber/fluorine rubber composites. J Rubber Res
Kun Q, Qin Z, Kai Z et al (2019) Non-uniform abrasive particle size effects on friction characteristics of FKM O-ring seals under three-body abrasion. Tribol Int 136:216–233
Yamada Y, Sogo S (2017) Evaluation of Temperature Dependency of Gas Permeability on Various Kinds of Elastomers. J Vac Soc Japan 60(12):502–506
Qi M, Jia X, Wang G et al (2020) Research on High Temperature Friction Properties of PTFE/Fluorosilicone Rubber/Silicone Rubber. Polym Test 106817
Mendoza AI, Moriana R, Hillborg H et al (2019) Super-hydrophobic zinc oxide/silicone rubber nanocomposite surfaces. Surfaces Interfaces
Shi Y, Sun Y, Wang Z (2019) Super-hydrophobic and super-oleophilic surface based on high-density polyethylene/waste ground rubber tire powder thermoplastic elastomer. J Thermoplast Compos Mater
Khattab TA, Mowafi S, El-Sayed H (2019) Development of mechanically durable hydrophobic lanolin/silicone rubber coating on viscose fibers. Cellulose 26(17):9361–9371
Li A, Wang G, Zhang Y et al (2021) Preparation methods and research progress of superhydrophobic paper. Coord Chem Rev 449:214207
He Q, Xu Z, Li A et al (2021) Study on hydrophobic properties of fluororubber prepared by template method under high temperature conditions. Colloids Surf A 612:125837
Li A, Wang G, Ma Y et al (2021) Study on preparation and properties of superhydrophobic surface of RTV silicone rubber. J Market Res 11:135–143
Li Y, Sun H, Zhang Y et al (2019) The three-dimensional heterostructure synthesis of ZnO/cellulosic fibers and its application for rubber composites. Compos Ence Technol 177(16):10–17
Lv C, Wang H, Liu Z et al (2017) A fluorine-free superhydrophobic PPS composite coating with high thermal stability, wear resistance, corrosion resistance. Prog Org Coat 110:47–54
Zhou X, Wang G, Wang M et al (2020) Progress in organic coatings a simple preparation method for superhydrophobic surface on silicon rubber and its properties. Prog Org Coat 143.
Wang G, Zhou W, Zhou J et al (2020) Superhydrophobic silicone rubber surface prepared by direct replication. Surf Eng 10:1–10
Wang G, Zhou J, Wang M et al (2020) A superhydrophobic surface with aging resistance, excellent mechanical restorablity and droplet bounce properties. Soft Matter 16
Wang S, Xue Y, Ban C et al (2020) Fabrication of robust tungsten carbide particles reinforced Co Ni super-hydrophobic composite coating by electrochemical deposition. Surf Coat Technol 385:125390
Yuan H, Pan Y, Wang X et al (2020) Simple water tunable polyurethane microsphere for super-hydrophobic dip-coating and oil-water separation. Polymer 204:122833
Onozato H, Watabe N (1979) Studies on fish scale formation and resorption. Cell Tissue Res
Vihar B, Hanisch FG, Baumgartner W (2016) Neutral glycans from sandfish skin can reduce friction of polymers. J Royal Soc Interface 13(116)
Murcia S, Miyamoto Y, Varma MP et al (2018) Contributions of the layer topology and mineral content to the elastic modulus and strength of fish scales. J Mech Behav Biomed Mater 78:56–64
Zhang Z, Yanshuang et al (2010) Study on the Ultrastructure, Friction Properties and Resistance-Reducing Mechanism of the Ventral Scales's Surface from Burmese Python. China Renew Energy Sci Technol Develop Conf
Venkateshan DG, Tafreshi HV (2018) Modelling droplet sliding angle on hydrophobic wire screens. Colloids Surf A 538:310–319
Parvate S, Dixit P, Chattopadhyay S (2020) Superhydrophobic Surfaces: Insights from Theory and Experiment. J Phys Chem B 124(8):1323–1360
Robert NW (1936) Resistance of Solid Surfaces to Wetting by Water. Indust Eng Chem 28(8):28 988–994
Hijes PMD, Shi K, Noya EG et al (2020) The Young-Laplace equation for a solid-liquid interface. J Chem Phys 153(19):191102
Zhu D, Ortegac F, Motamedi R et al (2012) Structureand mechanical performance of a “modern” fish scale. Adv Eng Mater 14(4):185–194
Depaula SM, Huilamf G, Araki K et al (2010) Confocal Raman and electronic microscopy studies on the topotactic conversion of calcium carbonate from Pomacea lineate, shells into hydroxyapatite bioceramic materials in phosphate media. Micron 41(41):983–989
Gullekson C, Lucas L, Hewitt K et al (2011) Surfacesensitive raman spectroscopy of collagen I fibrils. Biophys J 100(7):1837–1845
Taegee MJ et al (2004) Effects of hydrophobic surface on skin-friction drag. Phys Fluids 16(7):55
Lee AGG, Rutter EH (2004) Experimental rock-on-rock frictional wear: Application to subglacial abrasion. J Geophys Res Atmosp 109(B9)
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This research project was supported by The 13th Five-Year National Key R&D Program of the Ministry of Science and Technology (2018YFC0809500).
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Xu, Z., Zhang, Y. & He, Q. Study on properties of fish scale biomimetic fluororubber prepared by template method. J Polym Res 29, 368 (2022). https://doi.org/10.1007/s10965-022-03222-z
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DOI: https://doi.org/10.1007/s10965-022-03222-z