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Iron-containing magnetic nanocomposites based on polyphenoxazine

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Abstract

Hybrid iron-containing nanocomposite materials based on polyphenoxazine (PPOA) were synthesized for the first time via chemical transformations of PPOA in the presence of iron(III) salt (FeCl3·6H2O, Fe(NO3)3·6H2O or Fe(CH3COCH=C(CH3)O)3) in an inert atmosphere under IR radiation in the temperature range of 350–600 °С. The developed hybrid nanocomposites were characterized by means of FTIR spectroscopy, X-ray diffraction (XRD), transmission (TEM) and scanning (SEM) electron microscopy, X-Ray fluorescence spectroscopy (XRF), Inductively coupled plasma atomic emission spectroscopy (ICP-AES), atomic absorption spectrometry (AAS), elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and magnetometry. The dependence of phase composition, magnetic and thermal properties of hybrid nanocomposites, as well as the size and shape of nanoparticles on synthesis temperature, Fe concentration and the nature of iron(III) salt was demonstrated.

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Acknowledgments

This work was carried out within the State Program of TIPS RAS. The equipment from the collective exploitation center “New petrochemical processes, polymer composites and adhesives” was used.

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Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prospect, Moscow, 119991, Russia

    Sveta Zhiraslanovna Ozkan, Galina Petrovna Karpacheva, Mikhail Nikolaevich Efimov, Galina Nikolaevna Bondarenko & Georgii Aleksandrovich Shandryuk

  2. National University of Science and Technology MISIS, 4 Leninsky prospect, Moscow, 119049, Russia

    Ella Leont’evna Dzidziguri

  3. Department of Chemistry Lomonosov Moscow State University, 1-3 Leninskie Gory, Moscow, 119991, Russia

    Petr Aleksandrovich Chernavskii & Galina Viktorovna Pankina

Authors
  1. Sveta Zhiraslanovna Ozkan
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  2. Galina Petrovna Karpacheva
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  3. Ella Leont’evna Dzidziguri
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  4. Mikhail Nikolaevich Efimov
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  5. Galina Nikolaevna Bondarenko
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  6. Georgii Aleksandrovich Shandryuk
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  7. Petr Aleksandrovich Chernavskii
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  8. Galina Viktorovna Pankina
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Correspondence to Sveta Zhiraslanovna Ozkan.

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Ozkan, S.Z., Karpacheva, G.P., Leont’evna Dzidziguri, E. et al. Iron-containing magnetic nanocomposites based on polyphenoxazine. J Polym Res 26, 176 (2019). https://doi.org/10.1007/s10965-019-1843-0

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