Skip to main content

Advertisement

SpringerLink
Log in

UV-curable waterborne polyurethane acrylate modified with octavinyl POSS for weatherable coating applications

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

UV-curable waterborne polyurethane acrylate (WPUA) modified with octavinyl polyhedral oligomeric silsesquioxane (OVPOSS) was prepared via photopolymerization between OVPOSS and WPUA. Structural and morphological features of WPUA/OVPOSS coatings were assessed using Fourier transform infrared spectroscopy, transmission electron microscopy and X-ray diffraction. Thermal properties of the WPUA/OVPOSS hybride coatings have been improved over the pure waterborne polyurethane acrylate analyzed by thermal gravimetric analysis. Performance of the coatings was also evaluated using water absorption, hardness, contact angle, X-ray photoelectron spectroscopy (XPS). The data showed that the WPUA/OVPOSS coatings possessed better water resistance and thermal oxidative stability in comparison with pure WPUA.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Madbouly SA, Otaigbe JU (2009) Prog Polym Sci 34:1283–1332

    Article  CAS  Google Scholar 

  2. Chattopadhyay DK, Raju KVSN (2007) Prog Polym Sci 32:352–418

    Article  CAS  Google Scholar 

  3. Asif A, Shi WF (2004) Polym Adv Technol 15:669–675

    Article  CAS  Google Scholar 

  4. Xiao P, Zhang HQ, Dai MZ, Nie J (2009) Prog Org Coat 64:510–514

    Article  CAS  Google Scholar 

  5. Huang ZG, Shi WF (2006) Eur Polym J 42:1506–1515

    Article  CAS  Google Scholar 

  6. Xu G, Shi WF (2005) Prog Org Coat 52:110–117

    Article  CAS  Google Scholar 

  7. Chen WH, Chen PC, Chen PS, Wang SC, Yeh JT, Chen KN (2009) J Polym Res 16:329–339

    Article  CAS  Google Scholar 

  8. Huang ZG, Shi WF (2007) Prog Org Coat 59:312–317

    Article  CAS  Google Scholar 

  9. Subramani S, Lee JM, Lee JY, Kim JH (2007) Polym Adv Technol 18:601–609

    Article  CAS  Google Scholar 

  10. Chen JJ, Zhu CF, Deng HT, Qin ZN, Bai YQ (2009) J Polym Res 16:375–380

    Article  Google Scholar 

  11. Jalilian M, Yeganeh H, Haghighi MN (2010) Polym Adv Technol 21:118–127

    CAS  Google Scholar 

  12. Asif A, Shi WF, Shen XF, Nie KM (2005) Polymer 46:11066–11078

    Article  CAS  Google Scholar 

  13. Zhang CY, Zhang XY, Dai JB, Bai CY (2008) Prog Org Coat 63:238–244

    Article  CAS  Google Scholar 

  14. Yeh JM, Yao CT, Hsieh CF, Lin LH (2008) Eur Polym J 44:3046–3056

    Article  CAS  Google Scholar 

  15. Zhang SL, Zou QC, Wu LM (2006) Macromol Mater Eng 291:895–901

    Article  CAS  Google Scholar 

  16. Liu HZ, Zheng SX (2005) Macromol Rapid Commun 26:196–200

    Article  Google Scholar 

  17. Madbouly SA, Otaigbe JU, Nanda AK, Wicks DA (2007) Macromolecules 40:4982–4991

    Article  CAS  Google Scholar 

  18. Oaten M, Choudhury NR (2005) Macromolecules 38:6392–6401

    Article  CAS  Google Scholar 

  19. Baney RH, Itoh M, Sakakibara A, Suzuki T (1995) Chem Rev 95:1409–1430

    Article  CAS  Google Scholar 

  20. Lu TL, Liang GZ, Kou KC (2005) J Mater Sci 40:4721–4726

    Article  CAS  Google Scholar 

  21. Feng Y, Jia Y, Xu HY (2009) J Appl Polym Sci 111:2684–2690

    Article  CAS  Google Scholar 

  22. Lai YS, Tsai CW, Yang HW, Wang GP, Wu KH (2009) Mater Chem Phys 117:91–98

    Article  CAS  Google Scholar 

  23. Turri S, Levi M (2005) Macromolecules 38:5569–5574

    Article  CAS  Google Scholar 

  24. Choi J, Yee AF, Laine RM (2003) Macromolecules 36:5666–5682

    Article  CAS  Google Scholar 

  25. Liu YH, Ni Y, Zheng SX (2006) Macromol Chem Phys 207:1842–1851

    Article  CAS  Google Scholar 

  26. Liu YH, Zheng SX, Nie KM (2005) Polymer 46:12016–12025

    CAS  Google Scholar 

  27. Ni Y, Zheng SX (2005) Macromol Chem Phys 206:2075–2083

    Article  CAS  Google Scholar 

  28. Bourbigot S, Le Bras M, Delobel R, Gengembre L (1997) Appl Surf Sci 120:15–29

    Article  CAS  Google Scholar 

  29. Wu K, Song L, Hu Y, Lu HD, Kandola BK, Kandare E (2009) Prog Org Coat 65:490–497

    Article  CAS  Google Scholar 

  30. Wu K, Hu Y, Song L, Lu HD, Wang ZZ (2009) Ind Eng Chem Res 48:3150–3157

    Article  CAS  Google Scholar 

  31. Wu LM, Chen XC, Hu DZ, Zou LJ (2001) Surf Interface Anal 31:1094–1099

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The work was supported by the Program for Specialized Research Fund for the Doctoral Program of Higher Education (200803580008), the Program for Science and Technology of Suzhou (SG-0841), the Opening Project of State Key Laboratory of Environmental Adaptability for Industrial Product, and the Program for the graduate innovation fund in University of Science and Technology of China.

Author information

Authors and Affiliations

  1. State Key Lab of Fire Science, University of Science and Technology of China, Hefei, Anhui, 230026, People’s Republic of China

    Xin Wang, Yuan Hu, Lei Song, Weiyi Xing & Hongdian Lu

  2. Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, People’s Republic of China

    Xin Wang

  3. Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study, University of Science and Technology of China, Suzhou, Jiangsu, 215123, People’s Republic of China

    Yuan Hu

  4. State Key Laboratory of Environmental Adaptability for Industrial Products, China National Electric Apparatus Research Institute, Guangzhou, 510300, People’s Republic of China

    Pin Lv & Ganxin Jie

Authors
  1. Xin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuan Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lei Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Weiyi Xing
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hongdian Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Pin Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Ganxin Jie
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yuan Hu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X., Hu, Y., Song, L. et al. UV-curable waterborne polyurethane acrylate modified with octavinyl POSS for weatherable coating applications. J Polym Res 18, 721–729 (2011). https://doi.org/10.1007/s10965-010-9468-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10965-010-9468-3

Keywords

Search

Navigation