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Thermochemical Properties of Selected Terpenes

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Abstract

This work is a continuation of our project of physico-chemical characterization of terpenic compounds participating as a source of secondary organic aerosols. In this work, S-(–)-limonene, terpinolene, (1R)-(–)-myrtenal, and α-terpinyl acetate were studied. Their densities, sound velocities, and isobaric heat capacities were measured in the temperature range (290–343) K, vapor pressures were measured in temperature range where stable boiling was achieved. The previous work was supplemented by measurement of isobaric heat capacities of α-pinene and β-pinene. Experimental values of vapor pressures were compared with prediction by COSMO-RS. Modern nonstatistical algorithms based on mathematical gnostics were used for data analysis.

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Acknowledgements

Financial support of the Czech Science Foundation under Grant Number 17-19798S is acknowledged.

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Authors and Affiliations

  1. Department of Aerosols Chemistry and Physics, Institute of Chemical Process Fundamentals of the CAS, v. v. i., Rozvojová 135/1, 165 02, Prague 6, Czech Republic

    Zdeněk Wagner, Magdalena Bendová & Jan Rotrekl

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  1. Zdeněk Wagner
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  2. Magdalena Bendová
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  3. Jan Rotrekl
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Correspondence to Zdeněk Wagner.

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Wagner, Z., Bendová, M. & Rotrekl, J. Thermochemical Properties of Selected Terpenes. J Solution Chem 49, 1137–1153 (2020). https://doi.org/10.1007/s10953-020-01016-9

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