Abstract
Cr3+ substituted cobalt–copper ferrites with chemical composition Co0.9Cu0.1Fe2−xCrxO4 (where x = 0.00, 0.03, 0.06, 0.09, 0.12, and 0.15) were prepared by sol–gel mediated auto combustion route utilizing malic acid as a complexing agent. The effect of incorporation of Cr3+ ions in low concentration on the structural, magnetic, dielectric, and electrical features of the Co–Cu ferrite compounds was investigated. The crystalline nature and variation in crystallite size with substituent content were identified from X-ray diffraction. Cr3+ substitution for Fe in the Co–Cu ferrite leads to a monotonic decrease in the saturation magnetization at 300 K as well as at 50 K, which could be credited to the decrease in strength of superexchange interaction on the substitution of Fe3+ ions by weakly magnetic Cr3+ ions in the octahedral site. Substitution of small fractions Cr3+ ions for some of the Fe in cobalt–copper ferrites decreased the Curie temperature. A decreasing pattern in DC resistivity with an increase in temperature was observed ensuring the semiconducting character of the ferrites under test. Dielectric properties such as dielectric constant (ε′) and dielectric loss (tan δ) of prepared materials were investigated.
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Harris, V.G., Geiler, A., Chen, Y., Yoon, S.D., Wu, M., Yang, A., Chen, Z., He, P., Parimi, P.V., Zuo, X., Patton, C.E., Abe, M., Acher, O., Vittoria, C.: Recent advances in processing and applications of microwave ferrites. J. Magn. Magn. Mater. 321, 2035–2047 (2009). https://doi.org/10.1016/j.jmmm.2009.01.004
Fu, Y., Chen, Q., He, M., Wan, Y., Sun, X., Xia, H., Wang, X.: Copper ferrite-graphene hybrid: a multifunctional heteroarchitecture for photocatalysis and energy storage. Ind. Eng. Chem. Res. 51, 11700–11709 (2012). https://doi.org/10.1021/ie301347j
Tsoncheva, T., Manova, E., Velinov, N., Paneva, D., Popova, M., Kunev, B., Tenchev, K., Mitov, I.: Thermally synthesized nanosized copper ferrites as catalysts for environment protection. Catal. Commun. 12, 105–109 (2010). https://doi.org/10.1016/j.catcom.2010.08.007
Lasheras, X., Insausti, M., Gil De Muro, I., Garaio, E., Plazaola, F., Moros, M., De Matteis, L., De La Fuente, J.M., Lezama, L.: Chemical synthesis and magnetic properties of monodisperse nickel ferrite nanoparticles for biomedical applications. J. Phys. Chem. C. 120, 3492–3500 (2016). https://doi.org/10.1021/acs.jpcc.5b10216
Pan, U., Sanpui, P., Paul, A., Chattopadhyay, A.: Surface complexed-zinc ferrite magnetofluorescent nanoparticles for killing cancer cells and single particle level cellular imaging. ACS Appl. Nano Mater. 1, 2496–2502 (2018). https://doi.org/10.1021/acsanm.8b00545
Mohit, K., Rani, V., Gupta, N., Rout, S.K.: Structural and microwave characterization of. Ceram. Int. 40, 1575–1586 (2014). https://doi.org/10.1016/j.ceramint.2013.07.045
Kefeni, K.K., Msagati, T.A.M., Mamba, B.B.: Ferrite nanoparticles: synthesis, characterisation and applications in electronic device. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 215, 37–55 (2017). https://doi.org/10.1016/j.mseb.2016.11.002
Kaur, M., Kaur, N.: Vibha: ferrites: synthesis and applications for environmental remediation. ACS Symp. Ser. 1238, 113–136 (2016). https://doi.org/10.1021/bk-2016-1238.ch004
Singh, R.N., Singh, N.K., Singh, J.P.: Electrocatalytic properties of new active ternary ferrite film anodes for O2 evolution in alkaline medium. Electrochim. Acta. 47, 3873–3879 (2002). https://doi.org/10.1016/S0013-4686(02)00354-7
Raghasudha, M., Ravinder, D., Veerasomaiah, P., Jadhav, K.M., Hashim, M., Bhatt, P., Meena, S.S.: Electrical resistivity and Mössbauer studies of Cr substituted Co nano ferrites. J. Alloys Compd. 694, 366–374 (2017). https://doi.org/10.1016/j.jallcom.2016.10.028
Jauhar, S., Singhal, S., Dhiman, M.: Manganese substituted cobalt ferrites as efficient catalysts for H2O2 assisted degradation of cationic and anionic dyes: their synthesis and characterization. Appl. Catal. A Gen. 486, 210–218 (2014). https://doi.org/10.1016/j.apcata.2014.08.020
Bhukal, S., Bansal, S., Singhal, S.: Magnetic Mn substituted cobalt zinc ferrite systems: structural, electrical and magnetic properties and their role in photo-catalytic degradation of methyl orange azo dye. Phys. B Condens. Matter. 445, 48–55 (2014). https://doi.org/10.1016/j.physb.2014.03.088
Vader, V.T.: Photocatalytic performance of fine particles of Cr doped magnesium ferrites prepared by sol–gel combustion route. J. Mater. Sci. Mater. Electron. 26, 66–71 (2015). https://doi.org/10.1007/s10854-014-2363-7
Goyal, A., Bansal, S., Kumar, V., Singh, J., Singhal, S.: Mn substituted cobalt ferrites (CoMnxFe2-xO4(x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0)): as magnetically separable heterogeneous nanocatalyst for the reduction of nitrophenols. Appl. Surf. Sci. 324, 877–889 (2015). https://doi.org/10.1016/j.apsusc.2014.11.065
Liu, P., He, H., Wei, G., Liang, X., Qi, F., Tan, F., Tan, W., Zhu, J., Zhu, R.: Effect of Mn substitution on the promoted formaldehyde oxidation over spinel ferrite: catalyst characterization, performance and reaction mechanism. Appl. Catal. B Environ. 182, 476–484 (2016). https://doi.org/10.1016/j.apcatb.2015.09.055
Fareghi-Alamdari, R., Zekri, N., Mansouri, F.: Enhancement of catalytic activity in the synthesis of 2-amino-4H-chromene derivatives using both copper- and cobalt-incorporated magnetic ferrite nanoparticles. Res. Chem. Intermed. 43, 6537–6551 (2017). https://doi.org/10.1007/s11164-017-3003-7
Ghadari, R., Namazi, H., Aghazadeh, M.: Synthesis of graphene oxide supported copper–cobalt ferrite material functionalized by arginine amino acid as a new high-performance catalyst. Appl. Organomet. Chem. 32, 1–10 (2018). https://doi.org/10.1002/aoc.3965
Dutta, M.M., Phukan, P.: Cu-doped CoFe2O4 nanoparticles as magnetically recoverable catalyst for C–N cross-coupling reaction. Catal. Commun. 109, 38–42 (2018). https://doi.org/10.1016/j.catcom.2018.02.014
Waldron, R.: Infrared spectra of ferrites. Phys. Rev. 99, 1727–1735 (1955). https://doi.org/10.1103/PhysRev.99.1727
Chandramohan, P., Srinivasan, M.P., Velmurugan, S., Narasimhan, S.V.: Cation distribution and particle size effect on Raman spectrum of CoFe2O4. J. Solid State Chem. 184, 89–96 (2011). https://doi.org/10.1016/j.jssc.2010.10.019
He, Q., Rui, K., Chen, C., Yang, J., Wen, Z.: Interconnected CoFe2O4−polypyrrole nanotubes as anode materials for high performance sodium ion batteries. ACS Appl. Mater. Interfaces. 9, 36927–36935 (2017). https://doi.org/10.1021/acsami.7b12503
Zhang, W., Quan, B., Lee, C., Park, S.K., Li, X., Choi, E., Diao, G., Piao, Y.: One-step facile solvothermal synthesis of copper ferrite-graphene composite as a high-performance supercapacitor material. ACS Appl. Mater. Interfaces. 7, 2404–2414 (2015). https://doi.org/10.1021/am507014w
Zhang, K., Li, J., Wu, F., Sun, M., Xia, Y., Xie, A.: Sandwich CoFe2O4/RGO/CoFe2O4 nanostructures for high-performance electromagnetic absorption. ACS Appl. Nano Mater. 2, 315–324 (2018). https://doi.org/10.1021/acsanm.8b01927
Gu, Z., Xiang, X., Fan, G., Li, F.: Facile synthesis and characterization of cobalt ferrite nanocrystals via a simple reduction-oxidation route. J. Phys. Chem. C. 112, 18459–18466 (2008). https://doi.org/10.1021/jp806682q
Bumajdad, A., Al-Ghareeb, S., Madkour, M., Al Sagheer, F.: Non-noble, efficient catalyst of unsupported α-Cr2O3 nanoparticles for low temperature CO oxidation. Sci. Rep. 7(2–10), 14788 (2017). https://doi.org/10.1038/s41598-017-14779-x
Naik, M.Z., Salker, A.V.: Tailoring the super-paramagnetic nature of MgFe2O4 nanoparticles by In3+ incorporation. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 211, 37–44 (2016). https://doi.org/10.1016/j.mseb.2016.05.019
Dobson, D.C., Linnett, J.W., Rahman, M.M.: Mössbauer studies of the charge transfer process in the system ZnxFe3-xO4. J. Phys. Chem. Solids. 31, 2727–2733 (1970). https://doi.org/10.1016/0022-3697(70)90270-2
Panda, R.K., Muduli, R., Jayarao, G., Sanyal, D., Behera, D.: Effect of Cr3+ substitution on electric and magnetic properties of cobalt ferrite nanoparticles. J. Alloys Compd. 669, 19–28 (2016). https://doi.org/10.1016/j.jallcom.2016.01.256
Krieble, K., Lo, C.C.H., Melikhov, Y., Snyder, J.E.: Investigation of Cr substitution in co ferrite (CoCrxFe2-xO4) using Mossbauer spectroscopy. J. Appl. Phys. 99(97–100), 08M912 (2006). https://doi.org/10.1063/1.2167051
Jadoun, P., Sharma, J., Kumar, S., Dolia, S.N., Bhatnagar, D., Saxena, V.K.: Structural and magnetic behavior of nanocrystalline Cr doped Co-Mg ferrite. Ceram. Int. 44, 6747–6753 (2018). https://doi.org/10.1016/j.ceramint.2018.01.091
Sijo, A.K.: Magnetic and structural properties of CoCrxFe2-xO4 spinels prepared by solution self combustion method. Ceram. Int. 43, 2288–2290 (2016). https://doi.org/10.1016/j.ceramint.2016.11.010
Kumar, L., Kumar, P., Kuncser, V., Greculeasa, S., Sahoo, B., Kar, M.: Strain induced magnetism and superexchange interaction in Cr substituted nanocrystalline cobalt ferrite. Mater. Chem. Phys. 211, 54–64 (2018). https://doi.org/10.1016/j.matchemphys.2018.02.008
Vadivel, M., Babu, R.R., Sethuraman, K., Ramamurthi, K., Arivanandhan, M.: Synthesis , structural , dielectric , magnetic and optical properties of Cr substituted CoFe2O4 nanoparticles by co-precipitation method. J. Magn. Magn. Mater. 362, 122–129 (2014). https://doi.org/10.1016/j.jmmm.2014.03.016
Li, L.Z., Tu, X.Q., Wang, R., Peng, L.: Structural and magnetic properties of Cr-substituted NiZnCo ferrite nanopowders. J. Magn. Magn. Mater. 381, 328–331 (2015). https://doi.org/10.1016/j.jmmm.2015.01.020
Alone, S.T., Shirsath, S.E., Kadam, R.H., Jadhav, K.M.: Chemical synthesis, structural and magnetic properties of nano-structured Co-Zn-Fe-Cr ferrite. J. Alloys Compd. 509, 5055–5060 (2011). https://doi.org/10.1016/j.jallcom.2011.02.006
Naik, S.R., Salker, A.V.: Change in the magnetostructural properties of rare earth doped cobalt ferrites relative to the magnetic anisotropy. J. Mater. Chem. 22, 2740–2750 (2012). https://doi.org/10.1039/C2JM15228B
Gajbhiye, N.S., Prasad, S., Balaji, G.: Experimental study of Hopkinson effect in single domain CoFe2O4 particles. IEEE Trans. Magn. 35, 2155–2161 (1999). https://doi.org/10.1109/20.774187
Pandya, P.B., Joshi, H.H., Kulkarni, R.G.: Bulk magnetic properties of Co-Zn ferrites prepared by the co-precipitation method. J. Mater. Sci. 26, 5509–5512 (1991). https://doi.org/10.1007/BF02403950
Shinde, T.J., Gadkari, A.B., Vasambekar, P.N.: Magnetic properties and cation distribution study of nanocrystalline Ni–Zn ferrites. J. Magn. Magn. Mater. 333, 152–155 (2013). https://doi.org/10.1016/j.jmmm.2012.12.049
Gabal, M.A., Al Angari, Y.M.: Low-temperature synthesis of nanocrystalline NiCuZn ferrite and the effect of Cr substitution on its electrical properties. J. Magn. Magn. Mater. 322, 3159–3165 (2010). https://doi.org/10.1016/j.jmmm.2010.05.054
Patange, S.M., Shirsath, S.E., Toksha, B.G., Jadhav, S.S., Jadhav, K.M.: Electrical and magnetic properties of Cr3+ substituted nanocrystalline nickel ferrite. J. Appl. Phys. 106, 023914 (2009). https://doi.org/10.1063/1.3176504
Verwey, E.J.W., Haayman, P.W.: Electronic conductivity and transition point of magnetite (“Fe3O4”). Physica. 8, 979–987 (1941). https://doi.org/10.1016/S0031-8914(41)80005-6
Kumari, N., Kumar, V., Singh, S.K.: Effect of Cr3+ substitution on properties of nano-ZnFe2O4. J. Alloys Compd. 622, 628–634 (2015). https://doi.org/10.1016/j.jallcom.2014.10.083
Verma, A., Thakur, O.P., Prakash, C., Goel, T.C., Mendiratta, R.G.: Temperature dependence of electrical properties of nickel–zinc ferrites processed by the citrate precursor technique. Mater. Sci. Eng. B. 116, 1–6 (2005). https://doi.org/10.1016/j.mseb.2004.08.011
Maxwell, J.: Electricity and magnetism. Oxford Univ. Press, London (1973)
Koops, C.G.: On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys. Rev. 83, 121–124 (1951). https://doi.org/10.1103/PhysRev.83.121
Kambale, R.C., Shaikh, P.A., Bhosale, C.H., Rajpure, K.Y., Kolekar, Y.D.: The effect of Mn substitution on the magnetic and dielectric properties of cobalt ferrite synthesized by an autocombustion route. Smart Mater. Struct. 18, 115028 (2009). https://doi.org/10.1088/0964-1726/18/11/115028
Maisnam, M., Phanjoubam, S., Sarma, H.N.K., Devi, L.R., Thakur, O.P., Prakash, C.: Dielectric properties of Ni2+ and Mn3+ substituted li-ferrite prepared by microwave sintering technique. Mod. Phys. Lett. B. 21, 497–503 (2007). https://doi.org/10.1142/S0217984907012827
Lakshmi, M., Kumar, K.V., Thyagarajan, K.: Study of the dielectric behaviour of Cr-doped zinc nano ferrites synthesized by sol-gel method. Adv. Mater. Phys. Chem. 6, 141–148 (2016). https://doi.org/10.4236/ampc.2016.66015
Hashim, M., Raghasudha, M., Shah, J., Shirsath, S.E., Ravinder, D., Kumar, S., Meena, S.S., Bhatt, P., Alimuddin, Kumar, R., Kotnala, R.K.: High temperature dielectric studies of indium-substituted NiCuZn nanoferrites. J. Phys. Chem. Solids. 112, 29–36 (2018). https://doi.org/10.1016/j.jpcs.2017.08.022
Rahman, M.T., Vargas, M., Ramana, C.V.: Structural characteristics, electrical conduction and dielectric properties of gadolinium substituted cobalt ferrite. J. Alloys Compd. 617, 547–562 (2014). https://doi.org/10.1016/j.jallcom.2014.07.182
Acknowledgments
The authors gratefully acknowledge Dr. V Sathe and Dr. V R Reddy, UGC-DAE consortium for scientific research, Indore, Madhya Pradesh, India, for providing Raman and Mӧssbauer facility. The authors are also thankful to UGC-BSR program, New Delhi, for providing UGC-BSR fellowship.
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Naik, C.C., Salker, A.V. Effect Cr3+ Ion Substitution on the Structural, Magnetic, and Dielectric Behavior of Co–Cu Ferrite. J Supercond Nov Magn 32, 3655–3669 (2019). https://doi.org/10.1007/s10948-019-05153-1
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DOI: https://doi.org/10.1007/s10948-019-05153-1