Skip to main content
Log in

Optimization of the Dy Content in Single Crystalline GdBCO Bulk Superconductors Fabricated in Air Via Top-Seeded Infiltration Growth Process

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

Single-crystalline bulk GdBa2Cu3O7−δ (GdBCO) superconductors were fabricated with top-seeded infiltration-growth technique (TSIG) in air by adding the different amounts of Dy2BaCuO5 (Dy-211) particles (5, 10, 15, 20, 25, 30, 35, and 40 wt%). All the samples show superconducting critical temperature at ∼93 K with sharp transition irrespective of the chemical composition. X-ray diffraction measurements confirmed that all the samples were single domain with high alignment. Microstructural studies through scanning electron microscopy showed that TSIG-processed GdBCO samples contained 211 phase particles of two different sizes, i.e., ∼2–4 and ∼10 μ m. The addition of Dy-211 phase particles led to a significant enhancement of critical current density (J c) at 77 K. GdBCO superconductor with the addition of 20 wt% of Dy-211 showed the highest J c of 45.5 kA/cm 2 at 77 K and self field.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Murakami, M., Yoo, S.I., Higuchi, T., Sakai, N., Weltz, J., Koshizuka, N., Tanaka, S.: Flux pinning in melt-grown NdBa2Cu3Oy and SmBa2Cu3Oy superconductors. Jpn. J. Appl. Phys. 33, L715–L717 (1994)

    Article  Google Scholar 

  2. Pradhan, A.K., Muralidhar, M., Koblischka, M.R., Murakami, M., Nakao, K., Koshizuka, N.: Evidence of strong flux pinning in melt-processed ternary (Nd–Eu–Gd)Ba2Cu3Oy superconductors. Appl. Phys. Lett. 75, 253–255 (1999)

    Article  ADS  Google Scholar 

  3. Muralidhar, M., Sakai, N., Nishiyama, M., Jirsa, M., Machi, T., Murakami, M.: Pinning characteristics in chemically modified (Nd, Eu, Gd)–Ba–Cu–O superconductors. Appl. Phys. Lett. 82, 943–945 (2003)

    Article  ADS  Google Scholar 

  4. Awad, R., Abou Aly, A.I., Mohammed, N.H., Isber, S., Motaweh, H.A., El-Said Bakeer, D.: Investigation on superconducting properties of GdBa2Cu3O7−δ added with nano sized ZnFe2O4. J. Alloys Compd. 610, 614–622 (2014)

    Article  Google Scholar 

  5. Sakai, N.: Murakami.: Fabrication of large melt-textured Gd-Ba-Cu-O superconductor with Ag addition. Phys. C 341–348, 2409–2412 (2000)

    Google Scholar 

  6. Izumi, M., Yabe, T., Wada, T., Maeda, A., Uchinokura, K., Tanaka, S., Asano, H.: Structural properties of the superconductor LaBa2Cu3−y O7−z in the solid solution system La1 + x Ba2−x Cu3−y O7−z . Phys. Rev. B 40, 6771–6786 (1989)

    Article  ADS  Google Scholar 

  7. Zhang, K., Dabrowski, B., Segre, C.U., Hinks, D.G., Schuller, I.K., Jorgensen, J.D., Slaski, M.: Solubility and superconductivity in RE(Ba2−x REx)Cu3O7 + δ systems (RE = Nd, Sm, Eu, Gd, Dy). J. Phys. C Solid State Phys. 20, L935–L940 (1987)

    Article  ADS  Google Scholar 

  8. Kramer, M.J., Yoo, S.I., McCallum, R.W., Yelon, W.B., Xie, H., Allenspach, P.: Hole filling, charge transfer and superconductivity in Nd1 + x Ba2−x Cu3O7 + δ . Phys. C 219, 145–155 (1994)

    Article  ADS  Google Scholar 

  9. Murakami, M., Yoo, S.I., Higuchi, T., Sakai, N., Weltz, J., Koshizuka, N., Tanaka, S.: Jpn. J. Appl. Phys. 33, L715–L717 (1994)

    Article  Google Scholar 

  10. Muralidhar, M., Murakami, M.: Effects of Gd BaCuO addition on critical current characteristics in melt-processed Nd, Eu, Gd–Ba–Cu–O. Phys. C 309, 43–48 (1998)

    Article  ADS  Google Scholar 

  11. Muralidhar, M., Tomita, M., Suzuki, K., Jirsa, M., Fukumoto, Y., Ishihara, A.: A low-cost batch process for high-performance melt-textured GdBaCuO pellets. Supercond. Sci. Technol. 23, 045033 (2010)

    Article  ADS  Google Scholar 

  12. Xu, C., Hu, A., Sakai, N., Izumi, N., Hirabayashi, I.: Effect of BaO2 and fine Gd2BaCuO7−δ addition on the superconducting properties of air-processed GdBa2Cu3O7−δ . Supercond. Sci. Technol. 18, 229–233 (2005)

    Article  ADS  Google Scholar 

  13. Li, B., Xu, K., Hara, S., Zhou, D., Zhang, Y., Izumi, M.: Enhanced pinning effect in air-processed Gd-123 bulk superconductors with BaTiO addition. Phys. C 475, 51–56 (2012)

    Article  ADS  Google Scholar 

  14. Shi, Y., Hari Babu, N., Iida, K., Yeoh, W.K., Dennis, A.R., Pathak, S.K., Cardwell, D.A.: Batch-processed gdBCO–ag bulk superconductors fabricated using generic seeds with high trapped fields. Phys. C 470, 685–688 (2010)

    Article  ADS  Google Scholar 

  15. Murakami, M., Sakai, N., Higuchi, T., Yoo, S.I.: Supercond. Sci. Technol. 9, 1015 (1996)

    Article  ADS  Google Scholar 

  16. Yoo, S.I., Sakai, N., Takaichi, H., Murakami, M.: Melt processing for obtaining NdBa2Cu3Oy superconductors with high Tc and large Jc. Appl. Phys. Lett. 65, 633–635 (1994)

    Article  ADS  Google Scholar 

  17. Saitoh, T., Segawa, K., Kamada, K., Sakai, N., Segawa, T., Yoo, S.I., Murakami, M.: Microstructures and superconducting properties of melt-processed (RE,RE’)-Ba-Cu-O. Phys. C 288, 141–147 (1997)

    Article  ADS  Google Scholar 

  18. Muralidhar, M., Koblischka, M.R., Saitoh, T., Murakami, M.: Microstructure and pinning in high-Tc and large-Jc (Nd, Eu, Gd)-123 superconductors prepared by OCMG process. Supercond. Sci. Technol. 11, 1349–1358 (1998)

    Article  ADS  Google Scholar 

  19. Nariki, S., Sakai, N., Murakami, M.: Melt-processed Gd–Ba–Cu–O superconductor with trapped field of 3 T at 77 K. Supercond. Sci. Technol. 18, S126–S130 (2005)

    Article  ADS  Google Scholar 

  20. Muralidhar, M., Sakai, N., Chikumoto, N., Jirsa, M., Machi, T., Nishiyama, M., Wu, Y., Murakami, M.: New type of vortex pinning structure effective at very high magnetic fields. Phys. Rev. Lett. 89, 23–25 (2002)

    Article  Google Scholar 

  21. Cloots, R., Koutzarova, T., Mathieu, J.P., Ausloos, M.: Supercond. Sci. Technol. 18, R9 (2005)

    Article  Google Scholar 

  22. Sudhakar Reddy, E., Rajasekharan, T.: Fabrication of textured REBa2Cu3O7/RE2BaCuO5 (RE = Y, Gd) composites by infiltration and growth of RE2BaCuO5 preforms by liquid phases. Supercond. Sci. Technol. 11, 523–534 (1998)

    Article  ADS  Google Scholar 

  23. Devendra Kumar, N., Rajasekharan, T., Muraleedharan, K., Banerjee, A., Seshubai, V.: Unprecedented current density to high fields in YBa2Cu3O7−δ superconductor through nano-defects generated by preform optimization in infiltration growth process. Supercond. Sci. Technol. 23, 105020–8 (2010)

    Article  ADS  Google Scholar 

  24. Pavan Kumar Naik, S., Devendra Kumar, N., Missak Swarup Raju, P., Rajasekharan, T., Seshubai, V.: Effect of infiltration temperature on the properties of infiltration growth processed YBCO superconductor. Phys. C 487, 72–76 (2013)

    Article  ADS  Google Scholar 

  25. Li, G.Z., Yang, W.M., Cheng, X.F., Fan, J., Guo, X.D.: A modified TSIG technique for simplifying the fabrication process of single-domain gdBCO bulks with a new kind of liquid source. J. Mater. Sci. 44, 6423–6426 (2009)

    Article  ADS  Google Scholar 

  26. Muralidhar, M., Ide, N., Koblischka, M.R., Diko, P., Inoue, K., Murakami, M.: Microstructure, critical current density and trapped field experiments in IG processed y-123. Supercond. Sci. Technol. 29, 054003–10 (2016)

    Article  ADS  Google Scholar 

  27. Li, B., Zhou, D., Xu, K., Hara, S., Tsuzuki, K., Miki, M., Felder, B., Deng, Z., Izumi, M.: Materials process and applications of single grain (RE)–ba–cu–o bulk high-temperature superconductors. Phys. C 482, 50–57 (2012)

    Article  ADS  Google Scholar 

  28. Iida, K., Babu, N.H., Shi, Y.H., Cardwell, D.A., Murakami, M.: Gd–ba–cu–o bulk superconductors fabricated by a seeded infiltration growth technique under reduced oxygen partial pressure. Supercond. Sci. Technol. 19, 641–647 (2006)

    Article  ADS  Google Scholar 

  29. Wang, M., Yang, P., Yang, W., Li, J.W., Hassan, Q.: The fabrication process of a high performance and pure c-axis grown gdBCO bulk superconductor with the TSMT-IG technique. Supercond. Sci. Technol. 28, 105011–10 (2015)

    Article  ADS  Google Scholar 

  30. Pavan Kumar Naik, S., Missak Swarup Raju, P., Rajasekharan, T., Seshubai, V.: Limited infiltration due to reactive sintering of nano-Sm2O3 with preforms - its effect on (Y, Sm)Ba2Cu3 O7−δ superconductors. Supercond. Sci. Technol. 29, 115001–11 (2016)

    Article  ADS  Google Scholar 

  31. Pavan Kumar Naik, S., Seshubai, V.: Role of nano and micron sized inclusions on the oxygen controlled POIG processed YBCO superconductors. J. Phys. Chem. Solids 101, 65–73 (2017)

    Article  ADS  Google Scholar 

  32. Pavan Kumar Naik, S., Missak Swarup Raju, P., Seshubai, V.: Role of Sm and Nb on the structural, microstructural and magnetic properties of the YBCO superconductors. Mater. Chem. Phys. 182, 503–507 (2016)

    Article  Google Scholar 

  33. Chen, D.X., Goldfarb, R.B.: Kim model for magnetization of type-II superconductors. J. Appl. Phys. 66, 2489–2500 (1989)

    Article  ADS  Google Scholar 

  34. Bean, C.P.: Magnetization of hard superconductors. Phys. Rev. Lett. 8, 250–253 (1962)

    Article  ADS  MATH  Google Scholar 

  35. Gyorgy, E.M., van Dover, R.B., Jackson, K.A., Schneemeyer, L.F., Waszczak, J.V.: Anisotropic critical currents in Ba2YCu3O7 analyzed using an extended Bean model. Appl. Phys. Lett. 55, 283–285 (1989)

    Article  ADS  Google Scholar 

  36. Muralidhar, M., Sakai, N., Jirsa, M., Murakami, M., Hirabayashi, I.: Record flux pinning in melt-textured NEG-123 doped by Mo and Nb nanoparticles. Appl. Phys. Lett. 92, 162512–162515 (2008)

    Article  ADS  Google Scholar 

  37. Yoo, S.I., Murakami, M., Sakai, N., Ohyama, T., Higuchi, T., Watahiki, M., Takahashi, M.: Melt processing for strong flux pinning in RE-ba-cu-o (RE: Nd, Sm, Eu, Gd) superconductors. J. Electron. Mater. 24, 1923–1930 (1995)

    Article  ADS  Google Scholar 

  38. Muralidhar, M., Murakami, M.: Effect of matrix composition on the flux pinning in (Nd,Eu,Gd)Ba2Cu3Oy superconductor. Phys. Rev. B 62, 13911–13914 (2000)

    Article  ADS  Google Scholar 

  39. Koblischka, M.R., Muralidhar, M., Murakami, M.: Flux pinning in ternary melt-processed (Nd0.33Eu0.33Gd0.33)Ba2Cu3Oy superconductors. Appl. Phys. Lett. 73, 2351 (1998)

    Article  ADS  Google Scholar 

  40. Muralidhar, M., Koblischka, M.R., Murakami, M.: Refinement of secondary phase particles for high critical current densities in Nd,Eu,Gd–Ba–Cu–O superconductors. Phys. C 313, 232–240 (1999)

    Article  ADS  Google Scholar 

  41. Kobayashi, S., Kaneko, T., Kato, T., Fujikami, J., Sato, K.: A novel scaling of magnetic field dependencies of critical currents for Ag-sheathed Bi-2223 superconducting tape. Phys. C 258, 336–340 (1996)

    Article  ADS  Google Scholar 

Download references

Acknowledgments

SPKN would like to acknowledge Shibaura Institute of Technology, Tokyo, Japan, gratefully for providing fellowship.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Muralidhar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pavan Kumar Naik, S., Muralidhar, M. & Murakami, M. Optimization of the Dy Content in Single Crystalline GdBCO Bulk Superconductors Fabricated in Air Via Top-Seeded Infiltration Growth Process. J Supercond Nov Magn 31, 981–987 (2018). https://doi.org/10.1007/s10948-017-4277-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-017-4277-0

Keywords

Navigation