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Mesoporous MCM-41@SnPr-Kryf.23-Mn a versatile and reusable nanocatalyst for the oxidation of primary and secondary alcohols in the presence of hydrogen peroxide as oxidant

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Abstract

In this study, we synthesized new silica-MCM-41 modified with kryptofix 23 immobilized with MnCl2·2H2O, an effective and heterogeneous reusable nanocatalyst, and characterized using FT-IR, SEM, TEM, EDS, XRD and BET techniques. This nanocatalyst catalyzed the oxidation of primary and secondary alcohols in the presence of H2O2 as an oxidant to corresponding carbonylated compounds under reflux in high yields. The oxidation of some primary alcohols gave the mixture of corresponding aldehyde and carboxylic acid and secondary alcohols gave corresponding ketones. Some cyclic secondary alcohols such as cyclohexanol (1m) and 1,4-cyclohexanediol (1,4-CHD, 1g) underwent ring opening oxidation and formed adipic acid and succinic acid, respectively, under the same condition.

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Acknowledgements

We express our gratitude to the Urmia University Research Council for supporting this research work.

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  1. Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, 57159, Iran

    Shirin Mahjabin & Nader Noroozi Pesyan

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  1. Shirin Mahjabin
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  2. Nader Noroozi Pesyan
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SM: Investigation, conceptualization, methodology. NNP: Funding acquisition and supervisor of project.

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Correspondence to Nader Noroozi Pesyan.

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Mahjabin, S., Noroozi Pesyan, N. Mesoporous MCM-41@SnPr-Kryf.23-Mn a versatile and reusable nanocatalyst for the oxidation of primary and secondary alcohols in the presence of hydrogen peroxide as oxidant. J Porous Mater 31, 557–567 (2024). https://doi.org/10.1007/s10934-023-01532-1

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