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Hg2+ determination by DPASV by using poly (methylene disulfide)/Au nanoparticle/MWCNT modified glassy carbon electrode by differential pulse anodic stripping voltammetry (DPASV) technique

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Abstract

In the present work, a glassy carbon electrode (GCE) was surface modified by a poly (methylene disulfide)/Au–nanoparticles/multiwall carbon nanotubes (PMDS/AuNPs/MWCNT) to improve its ability to detect of trace mercury cations in polluted water. The produced electrode was characterized with FE-SEM, HR-TEM, AFM, XRD, and FT-IR techniques. The obtained results proved the success of the modification process and revealed that the process had a significant effect on the morphology of the electrode and its surface roughness. EIS analysis demonstrated the improvement of the electrochemical properties of the surface-modified sample. Accordingly, the obtained charge transfer resistance (Rct) decreased from 477.1 Ohm cm2 for the unmodified GCE to 83.4 Ohm cm2 for the modified-GCE. The designed modified electrode was used as an ultra-sensitive electrode for determining the concentration of Hg2+ cation using the differential pulse anodic stripping voltammetry (DPASV) technique.

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References

  1. L.A. Malik, A. Bashir, A. Qureashi, A.H. Pandith, Environ. Chem. Lett. 17, 1495 (2019)

    Article  CAS  Google Scholar 

  2. S. Wadhawan, A. Jain, J. Nayyar, S.K. Mehta, J. Water Process. Eng. 33, 101038 (2020)

    Article  Google Scholar 

  3. R. Chakraborty, A. Asthana, A.K. Singh, B. Jain, A.B.H. Susan, Int. J. Environ. Anal. Chem. 102(2), 342–379 (2020)

    Article  Google Scholar 

  4. M.A. Albakri, T.A. Saleh, Y. Mankour, T.F. Garrison, O.C.S. Al, Hamouz, J. Coll. Interfac. Sci. 582, 428 (2021)

    Article  CAS  ADS  Google Scholar 

  5. T.-H. Kim, M.-J. Cho, Y. Lee, J.H. Kim, J.-Y. Hwang, H.-E. Lee, S.-H. Kim, J.-D. Choi, G.-J. Kang, J. AOAC Int. 103, 244 (2020)

    Article  PubMed  Google Scholar 

  6. https://www.epa.gov/mercury/what-epa-doing-reduce-mercury-pollution-and-exposures-mercury

  7. S. Balasurya, A. Syed, A.M. Thomas, N. Marraiki, A.M. Elgorban, L.L. Raju, A. Das, S.S. Khan, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 228, 117712 (2020)

    Article  CAS  Google Scholar 

  8. L. Huang, Q. Zhu, J. Zhu, L. Luo, S. Pu, W. Zhang, W. Zhu, J. Sun, J. Wang, Inorg. Chem. 58, 1638 (2019)

    Article  CAS  PubMed  Google Scholar 

  9. A. Thongsaw, R. Sananmuang, Y. Udnan, G.M. Ross, W.C. Chaiyasith, Spectrochim. Acta Part B At. Spectrosc. 160, 105685 (2019)

    Article  CAS  Google Scholar 

  10. T. Lech, Forensic Sci. Int. 237, e1 (2014)

    Article  CAS  PubMed  Google Scholar 

  11. J. Giersz, M. Bartosiak, K. Jankowski, Talanta. 167, 279 (2017)

    Article  CAS  PubMed  Google Scholar 

  12. J. Jebali, M. Banni, H. Gerbej, H. Boussetta, J. López-Barea, J. Alhama, Mar. Environ. Res. 65, 358 (2008)

    Article  CAS  PubMed  Google Scholar 

  13. S.C. Hight, J. Cheng, Anal. Chim. Acta. 567, 160 (2006)

    Article  CAS  Google Scholar 

  14. Y.S. Ho, P.C. Uden, J. Chromatogr. A 688, 107 (1994)

    Article  CAS  Google Scholar 

  15. E.G. Barrera, D. Bazanella, P.W. Castro, W. Boschetti, M.G.R. Vale, M.B. Dessuy, Microchem J. 132, 365 (2017)

    Article  CAS  Google Scholar 

  16. M.A. Deshmukh, R. Celiesiute, A. Ramanaviciene, M.D. Shirsat, A. Ramanavicius, Electrochim. Acta. 259, 930 (2018)

    Article  CAS  Google Scholar 

  17. M. Díaz-Somoano, M.A. López-Antón, M.R. Martínez-Tarazona, Fuel 83, 231 (2004)

    Article  Google Scholar 

  18. M.D. Raicopol, N.A. Chira, A.M. Pandele, A. Hanganu, A.A. Ivanov, V. Tecuceanu, I.G. Bugean, G.O. Buica, Sens. Actuators B Chem. 313, 128030 (2020)

    Article  CAS  Google Scholar 

  19. J. Gayathri, K.S. Selvan, S.S. Narayanan, Sens. Bio-Sensing Res. 19, 1 (2018)

    Article  Google Scholar 

  20. J. Jayadevimanoranjitham, S.S. Narayanan, Appl. Surf. Sci. 448, 444 (2018)

    Article  CAS  ADS  Google Scholar 

  21. A. Giacomino, A. Ruo Redda, S. Squadrone, M. Rizzi, M.C. Abete, C. La Gioia, R. Toniolo, O. Abollino, M. Malandrino, Food Chem. 221, 737 (2017)

    Article  CAS  PubMed  Google Scholar 

  22. P.S. Adarakatti, V. Gangaiah, A. Siddaramanna, Mater. Sci. Semicond. Process. 84, 157 (2018)

    Article  CAS  Google Scholar 

  23. H. İncebay, Z. Yazıcıgil, Surf. Interfac. 9, 160 (2017)

    Article  Google Scholar 

  24. H. Incebay, A. Ucar, Electroanalysis. 35, e202200235 (2023)

    Article  CAS  Google Scholar 

  25. C. Herrera, K.J. Ysinga, C.L. Jenkins, ACS Appl. Mater. Interfac. 11, 35312 (2019)

    Article  CAS  Google Scholar 

  26. H. Hirano, J. Kadota, Y. Agari, T. Harada, M. Tanaka, K. Hasegawa, Polym. Eng. Sci. 47, 262 (2007)

    Article  CAS  Google Scholar 

  27. P.D. Mumbauer, D.H. Carey, G.S. Ferguson, Chem. Mater. 7, 1303 (1995)

    Article  CAS  Google Scholar 

  28. H. Yi, T. Lan, Y. Yang, H. Zeng, T. Zhang, T. Tang, C. Wang, Y. Deng, Energy Storage Mater. 21, 61 (2019)

    Article  Google Scholar 

  29. M. Ling, L. Zhang, T. Zheng, J. Feng, J. Guo, L. Mai, G. Liu, Nano Energy. 38, 82 (2017)

    Article  CAS  Google Scholar 

  30. J. Zhu, P. Zhu, C. Yan, X. Dong, X. Zhang, Prog Polym. Sci. 90, 118 (2019)

    Article  CAS  Google Scholar 

  31. T. Velempini, K. Pillay, J. Environ. Chem. Eng. 7, 103350 (2019)

    Article  CAS  Google Scholar 

  32. J.G. Manjunatha, Open. Chem. Eng. J. (2019). https://doi.org/10.2174/1874123101913010081

    Article  Google Scholar 

  33. K.S. Selvan, S.S. Narayanan, J. Electroanal. Chem. 810, 176 (2018)

    Article  CAS  Google Scholar 

  34. J.G. Manjunatha, B.E.K. Swamy, G.P. Mamatha, O. Gilbert, M.T. Shreenivas, B.S. Sherigara, Int. J. Electrochem. Sci. 4, 1706 (2009)

    Article  CAS  Google Scholar 

  35. C.B. Hiemke, P. Bergemann, N. Conca, A. Dietmaier, O. Egberts, K. Fric, M. Gerlach, M. Greiner, C. Gründer, G. Haen, E. Havemann-Reinecke, U. Jaquenoud Sirot, E. Kirchherr, H. Laux, G. Lutz, U.C. Messer, T. Müller, M.J. Pfuhlmann, B. Rambec, Pharmacopsychiatry. 21, 195 (2011)

    Google Scholar 

  36. H. İncebay, R. Saylakci, Electroanalysis. 33, 1451 (2021)

    Article  Google Scholar 

  37. L. Dedelaite, S. Kizilkaya, H. Incebay, H. Ciftci, M. Ersoz, Z. Yazicigil, Y. Oztekin, A. Ramanaviciene, A. Ramanavicius, Coll. Surf. A Physicochem Eng Asp 483, 279 (2015)

    Article  CAS  Google Scholar 

  38. H. Incebay, L. Aktepe, Z. Leblebici, Surf. Interfac. 21, 100726 (2020)

    Article  CAS  Google Scholar 

  39. H. İncebay, J. Turkish Chem. Soc. Sect. A Chem. 5, 1205 (2018)

  40. N. Hareesha, J.G. Manjunatha, B.M. Amrutha, P.A. Pushpanjali, M.M. Charithra, N. Prinith, Subbaiah, J. Electron. Mater. 50, 1230 (2021)

    Article  CAS  ADS  Google Scholar 

  41. A. Balliamada Monnappa, J.G. Manjunatha, A.S. Bhatt, R. Chenthattil, P. Pemmatte, Ananda, Phys. Chem. Res. 7, 523 (2019)

    Google Scholar 

  42. N. Hareesha, J.G. Manjunatha, B.M. Amrutha, N. Sreeharsha, S.M. Basheeruddin, Asdaq, M.K. Anwer, Coll. Surf. A Physicochem Eng Asp 626, 127042 (2021)

    Article  CAS  Google Scholar 

  43. N.S. Prinith, J.G. Manjunatha, J. Electrochem. Sci. Eng. 10, 305 (2020)

    Article  CAS  Google Scholar 

  44. N.S. Prinith, J.G. Manjunatha, C. Raril, Anal. Bioanal Electrochem. 11, 742 (2019)

    CAS  Google Scholar 

  45. G. Ding, S. Xie, Y. Zhu, Y. Liu, L. Wang, F. Xu, Sens. Actuators B Chem. 221, 1084 (2015)

    Article  CAS  Google Scholar 

  46. H. Xiao, W. Wang, S. Pi, Y. Cheng, Q. Xie, Sens. Actuators B Chem. 317, 128202 (2020)

    Article  CAS  Google Scholar 

  47. N.F. Atta, A. Galal, E.H. El-Ads, Electrochim. Acta. 69, 102 (2012)

    Article  CAS  Google Scholar 

  48. H. Xu, L. Zeng, S. Xing, G. Shi, Y. Xian, L. Jin, Electrochem. Commun. 10, 1839 (2008)

    Article  CAS  Google Scholar 

  49. R. Wang, X. Liu, Y. Zhao, J. Qin, H. Xu, L. Dong, S. Gao, L. Zhong, Microchem J. 174, 107061 (2022)

    Article  CAS  Google Scholar 

  50. S.M. Ghalebi, V. Zare-Shahabadi, H. Parham, Microchim. Acta 186, 1–8 (2019)

    Article  CAS  Google Scholar 

  51. C. Gao, X.J. Huang, TrAC - Trends Anal. Chem. 51, 1 (2013)

    Article  Google Scholar 

  52. H. Xing, J. Xu, X. Zhu, X. Duan, L. Lu, Y. Zuo, Y. Zhang, W. Wang, J. Electroanal. Chem. 782, 250 (2016)

    Article  CAS  Google Scholar 

  53. M. Giannetto, G. Mori, F. Terzi, C. Zanardi, R. Seeber, Electroanalysis. 23, 456 (2011)

    Article  CAS  Google Scholar 

  54. K. Okitsu, M. Ashokkumar, F. Grieser, J. Phys. Chem. B 109, 20673 (2005)

    Article  CAS  PubMed  Google Scholar 

  55. P. Zhao, N. Li, D. Astruc, Coord. Chem. Rev. 257, 638 (2013)

    Article  CAS  Google Scholar 

  56. N. Elahi, M. Kamali, M.H. Baghersad, Talanta. 184, 537 (2018)

    Article  CAS  PubMed  Google Scholar 

  57. M.D. Đurović, R. Puchta, Å.D. Bugarčić, R. van Eldik, Dalt Trans. 43, 8620 (2014)

    Article  Google Scholar 

  58. A. Roshanghias, G. Sodeifian, A.A. Javidparvar, S. Tarashi, Results Eng. 14, 100460 (2022)

    Article  CAS  Google Scholar 

  59. A.A. Javidparvar, M.A. Mosavi, B. Ramezanzadeh, Mater. Chem. Phys. 296, 127279 (2023)

    Article  CAS  Google Scholar 

  60. A.A. Javidparvar, A. Farhadian, A.R. Shahmoradi, in Grafted Biopolym as Corrossion Inhibitors, ed. by J. Aslam (Wiley, New Jersey 2023), pp. 337–363

  61. A. Rahimi, A. Farhadian, L. Guo, E. Akbarinezhad, R. Sharifi, D. Iravani, A. Asghar Javidparvar, M.A. Deyab, M.A. Varfolomeev, J. Ind. Eng. Chem. 123, 170–186 (2023)

  62. A.R. Shahmoradi, M.S. Bejandi, E.H. Rasanani, A.A. Javidparvar, B. Ramezanzadeh, Prog Org. Coat. 178, 107493 (2023)

    Article  CAS  Google Scholar 

  63. A.A. Javidparvar, B. Ramezanzadeh, E. Ghasemi, J. Stud. Color. World. 4, 47 (2014)

    Google Scholar 

  64. A.A. Javidparvar, R. Naderi, B. Ramezanzadeh, J. Color. Sci. Technol. 13, 341 (2020)

    CAS  Google Scholar 

  65. A.A. Javidparvar, R. Naderi, B. Ramezanzadeh, Corros. Sci. 165, 108379 (2020)

    Article  CAS  Google Scholar 

  66. A.A. Javidparvar, R. Naderi, B. Ramezanzadeh, J. Hazard. Mater. 389, 122135 (2020)

    Article  CAS  PubMed  Google Scholar 

  67. S. Ramesh, K.H. Leen, K. Kumutha, A.K. Arof, Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 66, 1237 (2007)

    Article  CAS  ADS  Google Scholar 

  68. X. Hu, H. Li, X. Huang, Z. Zhu, H. Zhu, Y. Gao, Z. Zhu, H. Chen, Microchim. Acta. 187, 1 (2020)

    Article  Google Scholar 

  69. M. Sheydaei, A. Allahbakhsh, A.H. Haghighi, A. Ghadi, J. Sulfur Chem. 35, 67 (2014)

    Article  CAS  Google Scholar 

  70. A. Allahbakhsh, A.H. Haghighi, M. Sheydaei, J. Therm. Anal. Calorim. 128, 427 (2017)

    Article  CAS  Google Scholar 

  71. A.H. Haghighi, M. Sheydaei, A. Allahbakhsh, M. Ghatarband, F.S. Hosseini, J. Therm. Anal. Calorim. 117, 525 (2014)

    Article  CAS  Google Scholar 

  72. Y. Jafari, S.M. Ghoreishi, M. Shabani-Nooshabadi, J. Polym. Res. 23, 1–13 (2016)

    Article  CAS  Google Scholar 

  73. G. Geng, P. Chen, B. Guan, Y. Liu, C. Yang, N. Wang, M. Liu, RSC Adv. 7, 51838 (2017)

    Article  CAS  ADS  Google Scholar 

  74. A.A. Javidparvar, B. Ramezanzadeh, E. Ghasemi, J. Taiwan. Inst. Chem. Eng. 61, 356–366 (2016)

    Article  CAS  Google Scholar 

  75. A.A. Javidparvar, B. Ramezanzadeh, E. Ghasemi, J. Stud. Color. World. 5, 31 (2015)

    Google Scholar 

  76. R.K. Singh Raman, P. Chakraborty Banerjee, D.E. Lobo, H. Gullapalli, M. Sumandasa, A. Kumar, L. Choudhary, R. Tkacz, P.M. Ajayan, M. Majumder, Carbon N. Y. 50, 4040 (2012)

    Article  CAS  Google Scholar 

  77. R. Touir, R.A. Belakhmima, M. Ebn Touhami, L. Lakhrissi, M. El Fayed, B. Lakhrissi, E.M. Essassi, J. Mater. Environ. Sci. 4, 921 (2013)

    CAS  Google Scholar 

  78. F. Batmanghelich, M.B. Hariri, S. Sharifi-Asl, Y. Yaghoubinezhad, G. Mortazavi, Y. Seo, Met. Mater. Int. 22, 609 (2016)

    Article  CAS  Google Scholar 

  79. S. Alinejad, R. Naderi, M. Mahdavian, Prog Org. Coat. 101, 142 (2016)

    Article  CAS  Google Scholar 

  80. Y. Wang, L. Zhang, L. Shen, S. Ge, J. Yu, M. Yan, Microchim. Acta. 184, 2587 (2017)

    Article  CAS  Google Scholar 

  81. Y.-L. Yang, B. Unnikrishnan, S.-M. Chen, Int. J. Electrochem. Sci. 6, 3902 (2011)

    Article  CAS  Google Scholar 

  82. Y. Umasankar, B. Unnikrishnan, S.-M. Chen, T.-W. Ting, Int. J. Electrochem. Sci. 7(1), 484–498 (2012)

    Article  CAS  Google Scholar 

  83. M.M. Rahman, J. Ahmed, A.M. Asiri, I.A. Siddiquey, M.A. Hasnat, RSC Adv. 6, 90470 (2016)

    Article  CAS  ADS  Google Scholar 

  84. X. Lu, X. Dong, K. Zhang, Y. Zhang, Anal. Methods. 4, 3326 (2012)

    Article  CAS  Google Scholar 

  85. L.L. He, L. Cheng, Y. Lin, H.F. Cui, N. Hong, H. Peng, D.R. Kong, C.D. Chen, J. Zhang, G.B. Wei, H. Fan, J. Electroanal. Chem. 814, 161 (2018)

    Article  CAS  Google Scholar 

  86. A. Moutcine, A. Chtaini, Sens. Bio-Sensing Res. 17, 30 (2018)

    Article  Google Scholar 

  87. J.B.R. Carvalho, R.S. Silva, I. Cesarino, S.S. Machado, K.I.B. Eguiluz, E.B. Cavalcanti, G.R. Salazar-Banda, Ceram. Int. 40, 13437 (2014)

    Article  CAS  Google Scholar 

  88. A. Mao, H. Li, Z. Cai, X. Hu, J. Electroanal. Chem. 751, 23 (2015)

    Article  CAS  Google Scholar 

  89. H.R. Rajabi, M. Roushani, M. Shamsipur, J. Electroanal. Chem. 693, 16 (2013)

    Article  CAS  Google Scholar 

  90. B.C. Janegitz, L.C.S. Figueiredo-Filho, L.H. Marcolino-Junior, S.P.N. Souza, E.R. Pereira-Filho, O. Fatibello-Filho, J. Electroanal. Chem. 660, 209 (2011)

    Article  CAS  Google Scholar 

  91. X.-C. Fu, J. Wu, L. Nie, C.-G. Xie, J.-H. Liu, X.-J. Huang, Anal. Chim. Acta. 720, 29 (2012)

    Article  CAS  PubMed  Google Scholar 

  92. F. Wang, X. Wei, C. Wang, S. Zhang, B. Ye, Talanta. 80, 1198 (2010)

    Article  CAS  PubMed  Google Scholar 

  93. K.-C. Cheng, P.-Y. Chen, Electroanalysis. 20, 207 (2008)

    Article  CAS  Google Scholar 

  94. G.O. Buica, C. Bucher, J.-C. Moutet, G. Royal, E. Saint-Aman, E.M. Ungureanu, Electroanalysis. 21, 77 (2009)

    Article  CAS  Google Scholar 

  95. M. Ghanei-Motlagh, M.A. Taher, A. Heydari, R. Ghanei-Motlagh, V.K. Gupta, Mater. Sci. Eng. C 63, 367 (2016)

    Article  CAS  Google Scholar 

  96. J. Wei, D. Yang, H. Chen, Y. Gao, H. Li, Sens. Actuators B Chem. 190, 968 (2014)

    Article  CAS  Google Scholar 

  97. J. Gong, T. Zhou, D. Song, L. Zhang, X. Hu, Anal. Chem. 82, 567 (2010)

    Article  CAS  PubMed  Google Scholar 

  98. H. Abdolmohammad-Zadeh, R. Mohammad-Rezaei, A. Salimi, Microchim. Acta. 187, 2 (2020)

    Article  CAS  Google Scholar 

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Acknowledgements

This manuscript was extracted from the PhD thesis of Seyedeh Mina Ghalebi. We gratefully acknowledge the financial support from the Islamic Azad University, Iran, Mahshahr branch.

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  1. Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

    Seyedeh Mina Ghalebi

  2. Department of Chemistry, Faculty of Sciences, Shahid Chamran University, Ahvaz, Iran

    Hooshang Parham

  3. Department of Chemistry, Masjed-Soleiman Branch, Islamic Azad University, Masjed-Soleiman, Iran

    Abbas Shirmardi

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  1. Seyedeh Mina Ghalebi
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SMG was the primary investigator and drafted the manuscript. HP and JK contributed to the study design. CE, PH, EG, DN, and JK conducted data analysis. All authors reviewed the manuscript drafts and approved the final version.

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Ghalebi, S.M., Parham, H. & Shirmardi, A. Hg2+ determination by DPASV by using poly (methylene disulfide)/Au nanoparticle/MWCNT modified glassy carbon electrode by differential pulse anodic stripping voltammetry (DPASV) technique. J Porous Mater 31, 251–266 (2024). https://doi.org/10.1007/s10934-023-01510-7

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