Skip to main content
SpringerLink
Log in

Selective synthesis of the SAPO-5 and SAPO-34 mixed phases by controlling Si/Al ratio and their excellent catalytic methanol to olefins performance

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

The selective synthesis of SAPO-5, SAPO-5/SAPO-34 mixture and SAPO-34 was performed by increasing Si/Al ratio and pH through hydrothermal synthesis route, in which the product was successively switched from AFI to AFI/CHA and to CHA. The samples were characterized by XRD, XRF, SEM, and NH3-TPD techniques. It indicates that the SAPO-5/SAPO-34 mixture exhibits higher acidity than the pure SAPO-5 and SAPO-34 phases. During methanol-to-olefins reaction, the catalytic lifetime of the SAPO-5/SAPO-34 mixture was significantly longer than that of SAPO-34, which may be attributed to the moderate acidity of the SAPO-5/SAPO-34 mixture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. S. Askari, R. Halladj, M. Sohrabi, Microporous Mesoporous Mater. 163, 334 (2012)

    Article  CAS  Google Scholar 

  2. L. Ye, F. Cao, W. Ying, D. Fang, Q. Sun, J. Porous Mater. 18, 225 (2011)

    Article  CAS  Google Scholar 

  3. M. Nazari, R.M. Behbahani, G. Moradi, A.S. Lemraski, J. Porous Mater. 23, 1037 (2016)

    Article  CAS  Google Scholar 

  4. P. Tian, Y. Wei, M. Ye, Z. Liu, ACS Catal. 5, 1922 (2015)

    Article  CAS  Google Scholar 

  5. P. Tian, X. Su, Y. Wang, Q. Xia, Y. Zhang, D. Fan, S. Meng, Z. Liu, Chem. Mater. 23, 1406 (2011)

    Article  CAS  Google Scholar 

  6. A. Corma, Chem. Rev. 95, 559 (1995)

    Article  CAS  Google Scholar 

  7. J. Chen, J. Li, Y. Wei, C. Yuan, B. Li, S. Xu, Y. Zhou, J. Wang, M. Zhang, Z. Liu, Catal. Commun. 46, 36 (2014)

    Article  CAS  Google Scholar 

  8. C. Wang, M. Yang, P. Tian, S. Xu, Y. Yang, D. Wang, Y. Yuan, Z. Liu, J. Mater. Chem. A 3, 5608 (2015)

    Article  CAS  Google Scholar 

  9. E. Aghaei, M. Haghighi, J. Porous Mater. 22, 187 (2015)

    Article  CAS  Google Scholar 

  10. T. Wang, X. Lu, Y. Yan, Microporous Mesoporous Mater. 168, 155 (2013)

    Article  CAS  Google Scholar 

  11. P. Liu, J. Ren, Y. Sun, Microporous Mesoporous Mater. 114, 365 (2008)

    Article  CAS  Google Scholar 

  12. Y. Fan, H. Xiao, G. Shi, H. Liu, X. Bao, J. Catal. 285, 251 (2012)

    Article  CAS  Google Scholar 

  13. Y. Liu, X. Cui, L. Han, Z. Yu, X. Liu, Microporous Mesoporous Mater. 198, 230 (2014)

    Article  CAS  Google Scholar 

  14. L. Guo, Y. Fan, X. Bao, G. Shi, H. Liu, J. Catal. 301, 162 (2013)

    Article  CAS  Google Scholar 

  15. D. Jin, Z. Liu, J. Zheng, W. Hua, J. Chen, K. Zhu, X. Zhou, RSC Adv. 6, 32523 (2016)

    Article  CAS  Google Scholar 

  16. M. Liu, W. Wu, O. Kikhtyanin, L. Xiao, A. Toktarev, G. Wang, A. Zhao, M.Y. Smirnova, G. Echevsky, Microporous and Mesoporous Mater. 181, 132 (2013)

    Article  CAS  Google Scholar 

  17. J. Chen, P.A. Wright, S. Natarajan, J.M. Thomas, Stud. Surf. Sci. Catal. 2, 1731 (1994)

    Article  Google Scholar 

  18. H. Hajfarajollah, S. Askari, R. Halladj, React. Kinet. Mech. Catal. 111, 723 (2014)

    Article  CAS  Google Scholar 

  19. S.R. Venna, M.A. Carreon, J. Mater. Chem. 19, 3138 (2009)

    Article  CAS  Google Scholar 

  20. D. Zhao, Y. Zhang, Z. Li, Y. Wang, J. Yu, RSC Adv. 7, 939 (2017)

    Article  CAS  Google Scholar 

  21. R.L. Smith, S. Svelle, P.D. Campo, T. Fuglerud, B. Arstad, A. Lind, S. Chavan, M.P. Attfield, D. Akporiaye, M.W. Anderson, Appl. Catal. A 505, 1 (2015)

    Article  CAS  Google Scholar 

  22. Y. Naraki, K. Ariga, K. Nakamura, K. Okushita, T. Sano, Microporous and Mesoporous Mater. 12, 1 (2017)

    Google Scholar 

  23. J. Zheng, W. Zhang, Z. Liu, Q. Huo, K. Zhu, X. Zhou, W. Yuan, Microporous and Mesoporous Mater. 225, 74 (2016)

    Article  CAS  Google Scholar 

  24. A. Amoozegar, M. Haghighi, S. Aghamohammadi, RSC Adv. 6, 51024 (2016)

    Article  CAS  Google Scholar 

  25. B. Gao, M. Yang, Y. Qiao, J. Li, X. Xiang, P. Wu, Y. Wei, S. Xu, P. Tian, Z. Liu, Catal. Sci. Technol. 6, 7569 (2016)

    Article  CAS  Google Scholar 

  26. Z. Li, J. Martínez-Triguero, J. Yu, A. Corma, J. Catal. 329, 379 (2015)

    Article  CAS  Google Scholar 

  27. W. Dai, G. Cao, L. Yang, G. Wu, M. Dyballa, M. Hunger, N. Guan, L. Li, Catal. Sci. Tech. 7, 607 (2017)

    Article  CAS  Google Scholar 

  28. Q. Sun, N. Wang, R. Bai, X. Chen, J. Yu, J. Mater. Chem. A 4, 14978 (2016)

    Article  CAS  Google Scholar 

  29. Q. Sun, N. Wang, G. Guo, X. Chen, J. Yu, J. Mater. Chem. A 3, 19783 (2015)

    Article  CAS  Google Scholar 

  30. C. Wang, M. Yang, W. Zhang, X. Su, S. Xu, P. Tian, Z. Liu, RSC Adv. 6, 47864 (2016)

    Article  CAS  Google Scholar 

  31. P. Wu, M. Yang, W. Zhang, S. Xu, P. Guo, P. Tian, Z. Liu, Chem. Commun. 53, 4985 (2017)

    Article  CAS  Google Scholar 

  32. P. Wang, D. Yang, J. Hu, J.a.. Xu, G. Lu, Catal. Today 212, 62 (2013)

    Google Scholar 

  33. Y. Wang, S.L. Chen, Y.J. Jiang, Y.Q. Cao, F. Chen, W.K. Chang, Y.L. Gao, RSC Adv. 6, 104985 (2016)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was supported by Postdoctoral Science Research Developmental Foundation of Heilongjiang Province of China (LBH-Z16176), Open Topics Fund of Key Laboratory of Functional Inorganic Material Chemistry (HDRCCX-201606), Foundation for Young Scientists of Heilongjiang University (QL201507).

Author information

Authors and Affiliations

  1. Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, China

    Syed ul Hasnain Bakhtiar, Sher Ali, Xiaotong Wang, Fulong Yuan, Zhibin Li & Yujun Zhu

  2. College of Environmental and Chemical Engineering, Heilongjiang University of Science and Technology, Harbin, 150022, China

    Yongli Dong

Authors
  1. Syed ul Hasnain Bakhtiar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sher Ali
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongli Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaotong Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Fulong Yuan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Zhibin Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yujun Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Zhibin Li or Yujun Zhu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bakhtiar, S.u.H., Ali, S., Dong, Y. et al. Selective synthesis of the SAPO-5 and SAPO-34 mixed phases by controlling Si/Al ratio and their excellent catalytic methanol to olefins performance. J Porous Mater 25, 1455–1461 (2018). https://doi.org/10.1007/s10934-018-0558-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-018-0558-7

Keywords

Search

Navigation