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Synthesis of MIL-101@g-C3N4 nanocomposite for enhanced adsorption capacity towards CO2

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Abstract

MIL-101@g-C3N4 nanocomposite was prepared by solvothermal synthesis and used for CO2 adsorption. The parent materials (MIL-101 and g-C3N4) and the MIL-101@g-C3N4 were characterized by X-ray diffraction, argon adsorption/desorption, Fourier transform infrared spectroscopy, thermal analysis (TG/DTA), transmission electronic microscopy, and Energy-dispersive X-ray spectroscopy. The results confirmed the formation of well-defined MIL-101@g-C3N4 with interesting surface area and pore volume. Furthermore, both MIL-101 and MIL-101@g-C3N4 were accomplished in carbon dioxide capture at different temperatures (280, 288, 273 and 298 K) at lower pressure. The adsorption isotherms show that the nanocomposite has a good CO2 adsorption affinity compared to MIL-101. The best adsorption capacity is about 1.6 mmol g−1 obtained for the nanocomposite material which is two times higher than that of MIL-101, indicating strong interactions between CO2 and MIL-101@g-C3N4. This difference in efficacy is mainly due to the presence of the amine groups dispersed in the nanocomposite. Finally, we have developed a simple route for the preparation of an effective and new adsorbent for the removal of CO2, which can be used as an excellent candidate for gas storage, catalysis, and adsorption.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux L.C.M., Université d’Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria

    Asmaa Argoub, Rachid Ghezini, Cherifa Bachir, Bouhadjar Boukoussa, Abdelkader Bengueddach & Rachida Hamacha

  2. Laboratoire de Chimie Appliquée LAC, C.U. Aïn-Témouchent, Route Sidi Bel Abbes BP 284, 46000, Aïn Témouchent, Algeria

    Cherifa Bachir

  3. Département de Génie des Matériaux, Faculté de Chimie, Université des Sciences et de la Technologie Mohamed Boudiaf, BP 1505 El-Mnaouer, 3100, Oran, Algeria

    Bouhadjar Boukoussa

  4. Laboratoire de Structure, Elaboration et Applications des Matériaux Moléculaires (SEA2M), Université Abdelhamid Ibn Badis Mostaganem, Mostaganem, Algeria

    Amine Khelifa

  5. Institute of Functional Interfaces, Karlsruher Institut für Technologie KIT, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

    Peter G. Weidler

Authors
  1. Asmaa Argoub
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  2. Rachid Ghezini
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  3. Cherifa Bachir
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  4. Bouhadjar Boukoussa
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  5. Amine Khelifa
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  6. Abdelkader Bengueddach
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  7. Peter G. Weidler
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  8. Rachida Hamacha
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Correspondence to Bouhadjar Boukoussa or Rachida Hamacha.

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Argoub, A., Ghezini, R., Bachir, C. et al. Synthesis of MIL-101@g-C3N4 nanocomposite for enhanced adsorption capacity towards CO2 . J Porous Mater 25, 199–205 (2018). https://doi.org/10.1007/s10934-017-0433-y

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  • DOI: https://doi.org/10.1007/s10934-017-0433-y

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