Skip to main content
SpringerLink
Log in

Encapsulation of molybdenum(VI) complex with thiazole-hydrazone ligand in zeolite Y: an efficient reusable catalyst for oxidation of primary alcohols and hydrocarbons

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

The reaction between 2-hydroxy-3-methoxybenzaldehyde and 2-hydrazinobenzothiazole in methanol gave (E)-2-((2-(benzo[d]thiazol-2-yl)hydrazono)methyl)-6-methoxyphenol (H2L). Interaction of this ligand with Mo-Y in the ethanol, led to [MoO2L(EtOH)]/Y. FT-IR, TGA, XRD, ICP and elemental analysis indicate the presence of [MoO2L(EtOH)] within the cavity pores of zeolite-Y. This material serves as a catalyst for the oxidation of primary alcohols, saturated hydrocarbons, such as ethylbenzene and toluene, using TBHP (70% solution in H2O) as an oxidant. The reaction conditions have been optimized for solvent, temperature and amount of oxidant and catalyst. The encapsulation of catalyst in zeolite, played an significant role in the catalytic behavior of this heterogeneous catalyst. The catalyst was easily recovered from the reaction medium and it could be re-used for other three runs without significant loss of activity. In addition, in comparison with the homogeneous [MoO2L(EtOH)] catalyst, high catalytic activity, improved stability, recycling ability and operational flexibility make the encapsulated catalyst, [MoO2L(EtOH)]/Y, better.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Z. Hai, L. Ying, Z. Xungao, Chin. J. Catal. 32, 1693–1701 (2011)

    Article  Google Scholar 

  2. Q. Jinwei, F. Zaihui, L. Yachun, H. Xiangling, Z. Dexi, W. Wenfeng, W. Yanlong, G. Xinglang, D. Xiaolin, W. Haitao, Z. Yanhong, Y. Ningya, Y. Dulin, Chin. J. Catal. 32, 1342 (2011)

    Article  Google Scholar 

  3. V. Conte, B. Floris, Dalton Trans. 40, 1419 (2011)

    Article  CAS  Google Scholar 

  4. E. Koohsaryan, M. Anbia, Chin. J. Catal. 37, 447 (2016)

    Article  CAS  Google Scholar 

  5. M. Moosavifar, A. Navid Arbat, Z. Rezvani, K. Nejati, Chin. J. Catal. 36, 1719 (2015)

    Article  CAS  Google Scholar 

  6. R.J. Corrêa, G.C. Salomão, M.H.N. Olsen, L. Cardozo Filho, V. Drago, C. Fernandes, O.A.C. Antunes, Appl. Catal. A 336, 35 (2008)

    Article  Google Scholar 

  7. M. Bagherzadeh, M. Zare, J. Coord. Chem. 66, 2885 (2013)

    Article  CAS  Google Scholar 

  8. M. Salavati-Niasari, S. Abdolmohammadi, J. Porous Mater. 16, 19 (2009)

    Article  CAS  Google Scholar 

  9. I. Kuźniarska-Biernacka, O. Rodrigues, M.A. Carvalho, I.C. Neves, A.M. Fonseca, Appl. Organometal. Chem. 26, 44 (2012)

    Article  Google Scholar 

  10. K. Kervinen, C.A.B. Pieter, M.B. Andrew, J.G. Gerbrand Mesu, G. Koten, J.M.K.G. Robertus, B.M. Weckhuysen, J. Am. Chem. Soc. 128, 3208 (2006)

    Article  CAS  Google Scholar 

  11. B.P. Nethravathi, K.N. Mahendra, K.R.K. Reddy, J. Porous Mater. 18, 389 (2011)

    Article  CAS  Google Scholar 

  12. M. Ghorbanloo, S. Ghamari, H. Yahiro, Turk. J. Chem. 39, 550 (2015)

    Article  CAS  Google Scholar 

  13. M. Ghorbanloo, S. Rahmani, H. Yahiro, Transition Met. Chem. 38, 725 (2013)

    Article  CAS  Google Scholar 

  14. J. Joseph, B.H. Mehta, Russ. J. Coord. Chem. 33, 124 (2007)

    Article  CAS  Google Scholar 

  15. S.M. Saadeh, Arab. J. Chem. 6, 191 (2013)

    Article  CAS  Google Scholar 

  16. M.A. Santos, S.M. Marques, S. Chaves, Coord. Chem. Rev. 256, 240 (2012)

    Article  CAS  Google Scholar 

  17. M. Ghorbanloo, R. Bikas, G. Małecki, Inorg. Chim. Acta 445, 8 (2016)

    Article  CAS  Google Scholar 

  18. M. Ghorbanloo, R. Tarasi, J. Tao, H. Yahiro, Turk. J. Chem. 38, 488 (2014)

    Article  CAS  Google Scholar 

  19. S.N. Rao, K.N. Munshi, N.N. Rao, J. Mol. Catal. A 145, 203 (1999)

    Article  CAS  Google Scholar 

  20. M.A. Katkar, S.N. Rao, H.D. Juneja, RSC. Adv. 2, 8071 (2012)

    Article  CAS  Google Scholar 

  21. S.R. Girish, V.K. Revankar, V.B. Mahale, Trans. Met. Chem. 21, 401 (1996)

    Article  CAS  Google Scholar 

  22. P. Neves, S. Gago, S.S. Balula, A.D. Lopes, A.A. Valente, L. Cunha-Silva, F.A. Almeida Paz, M. Pillinger, J. Rocha, C.M. Silva, I.S. Goncalves, Inorg. Chem. 50, 3490 (2011)

    Article  CAS  Google Scholar 

  23. R. Bikas, H. Hosseini-Monfared, P. Aleshkevych, R. Szymczak, M. Siczek, T. Lis, Polyhedron 88, 48 (2015)

    Article  CAS  Google Scholar 

  24. C. Jin, W. Fan, Y. Jia, B. Fan, J. Ma, R. Li, J. Mol. Catal. A 249, 23 (2006)

    Article  CAS  Google Scholar 

  25. M. Asadi, J.K. Aein, K.A. Hossein, Inorg. Chim. Acta 360, 1725 (2007)

    Article  CAS  Google Scholar 

  26. A. Choudhary, B. Das, S. Ray, Dalton Trans. 44, 3753 (2015)

    Article  CAS  Google Scholar 

  27. R. Ganesan, B. Viswanathan, J. Phys. Chem. B 108, 7102 (2004)

    Article  CAS  Google Scholar 

  28. M. Salavati-Niasari, Z. Salimi, M. Bazarganipour, F. Davar, Inorg. Chim. Acta 362, 3715 (2009)

    Article  CAS  Google Scholar 

  29. S. Velusamy, M. Ahmad, T. Punniyamurthy, Org. Lett. 6, 4821 (2004)

    Article  CAS  Google Scholar 

  30. K.G. Sekar, C.L. Edison Raj, J. Chem. Pharm. Res. 3, 596 (2011)

    CAS  Google Scholar 

  31. P.D. Sharma, P. Panchariya, P. Purohit, P.K. Sharma, Eur. Chem. Bull. 2, 816 (2013)

    CAS  Google Scholar 

  32. R. Xie, G. Fan, L. Yang, F. Li, Catal. Sci. Technol. 5, 540 (2015)

    Article  CAS  Google Scholar 

  33. X. Li, B. Lu, J. Sun, X. Wang, J. Zhao, Q. Cai, Catal. Commun. 39, 115 (2013)

    Article  Google Scholar 

  34. D.J. Cole-Hamilton, R.P. Tooze, Catalyst Separation, Recovery and Recycling: Chemistry and Process Design (Springer, Dordrecht, 2006)

    Book  Google Scholar 

  35. P. Barbaro, F. Liguori, Heterogenized Homogeneous Catalysts for Fine Chemicals Production: Materials and Processes (Springer, Dordrecht, 2010)

    Book  Google Scholar 

Download references

Acknowledgements

Authors are thankful to University of Zanjan for financial support of this study.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, 45371-38791, Iran

    Massomeh Ghorbanloo & Ali Maleki Alamooti

Authors
  1. Massomeh Ghorbanloo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ali Maleki Alamooti
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Massomeh Ghorbanloo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ghorbanloo, M., Alamooti, A.M. Encapsulation of molybdenum(VI) complex with thiazole-hydrazone ligand in zeolite Y: an efficient reusable catalyst for oxidation of primary alcohols and hydrocarbons. J Porous Mater 24, 769–777 (2017). https://doi.org/10.1007/s10934-016-0314-9

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-016-0314-9

Keywords

Search

Navigation