Skip to main content
SpringerLink
Log in

Sonophotocatalytic degradation of eriochrome black-T dye in water using Ti grafted SBA-15

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Here in, a series of titanium-modified mesoporous silica (Ti-SBA-15) was prepared by grafting titanium isopropoxide. The as-synthesized Ti-SBA-15 nanocatalysts were characterized through N2-adsorption–desorption, XRD, TGA/DSC, TEM and EDX techniques. Sonocatalytic and sonophoto-catalytic degradation of Eriochrome Black T (EBT) dye were investigated. 88.7 % removal was achieved in 70 min by using 5 % Ti-SBA-15 through sonophotocatalytic degradation under visible light irradiation. The kinetic study revealed that photo-degradation of EBT follows pseudo-first order reaction mechanism, where the rate constant was 27.4 × 10−3 min−1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710 (1992)

    Article  CAS  Google Scholar 

  2. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L.J. Schlenker, Am. Chem. Soc. 114, 10834 (1992)

    Article  CAS  Google Scholar 

  3. A. Sayari, Chem. Mater. 8, 1840 (1996)

    Article  CAS  Google Scholar 

  4. A. Corma, Chem. Rev. 97, 2373 (1997)

    Article  CAS  Google Scholar 

  5. T. Maschmeyer, F. Rey, G. Sanker, J.M. Thomas, Nature 378, 159 (1995)

    Article  CAS  Google Scholar 

  6. A. Corma, V. Fornés, M.T. Navarro, J. Pérez-Pariente, J. Catal. 148, 569 (1994)

    Article  CAS  Google Scholar 

  7. T. Blasco, A. Corma, M.T. Navarro, J. Pérez-Pariente, J. Catal. 156, 65 (1995)

    Article  CAS  Google Scholar 

  8. K.A. Koyano, T. Tatsumi, Microporous Mater. 10, 259 (1997)

    Article  Google Scholar 

  9. R. Mokoya, W. Jones, Chem. Commun. 22, 2185 (1997)

    Article  Google Scholar 

  10. R. Ryoo, S.J. Jun, J.M. Kim, M.J. Kim, Chem. Commun. 22, 2225 (1997)

    Article  Google Scholar 

  11. J.Y. Ying, C.P. Mehnert, M.S. Wong, Angew. Chem. Int. Ed. 38, 56 (1999)

    Article  CAS  Google Scholar 

  12. F. Schüth, Chem. Mater. 13, 3184 (2001)

    Article  Google Scholar 

  13. Y. Wan, D.Y. Zhao, Chem. Rev. 107, 2821 (2007)

    Article  CAS  Google Scholar 

  14. Y. Han, D. Zhang, Curr. Opin. Chem. Eng. 1, 129 (2012)

    Article  CAS  Google Scholar 

  15. W.J.J. Stevens, K. Lebeau, M. Mertens, G. van Tendeloo, P. Cool, E.F. Vansant, J. Phys. Chem. B 110, 9183 (2006)

    Article  CAS  Google Scholar 

  16. F. Zhang, Y. Yan, H. Yang, Y. Meng, C. Yu, B. Tu, D. Zhao, J. Phys. Chem. 109, 8723 (2005)

    Article  CAS  Google Scholar 

  17. W. Zhang, J. Lu, B. Han, M. Li, J. Xiu, P. Ying, C. Li, Chem. Mater. 14, 3413 (2002)

    Article  CAS  Google Scholar 

  18. Z. Luan, E.M. Maes, P.A.W. van der Heide, D. Zhao, R.S. Czernuszewicz, L. Kevan, Chem. Mater. 11, 3680 (1999)

    Article  CAS  Google Scholar 

  19. N. Rahmat, A.A. Zuhairi, A. Rahman Mohamed, Am. J. Appl. Sci. 7, 1579 (2010)

    Article  CAS  Google Scholar 

  20. R. Huirache-Acuña, R. Nava, C.L. Peza-Ledesma, J. Lara-Romero, G. Alonso-Núñez, B. Pawelec, E.M. Rivera-Muñoz, Materials 6, 4139 (2013)

    Article  Google Scholar 

  21. B.L. Newalkar, J. Olanrewaju, S. Komarneni, Chem. Mater. 13, 552 (2001)

    Article  CAS  Google Scholar 

  22. M.S. Morey, S. O’Brien, S. Schwarz, G.D. Stucky, Chem. Mater. 12, 898 (2002)

    Article  Google Scholar 

  23. P. Wu, T. Tatsumi, T. Komatsu, T. Yashima, Chem. Mater. 14, 1657 (2002)

    Article  CAS  Google Scholar 

  24. D. Zhao, J. Sun, Q. Li, G.D. Stucky, Chem. Mater. 12, 275 (2000)

    Article  CAS  Google Scholar 

  25. A.K. Aboul-Gheit, S.M. Abdel-Hamid, S.A. Mahmoud, R.A. El-Salamony, J. Valyon, M.R. Mihályi, A. Szegedi, J. Mater. Sci. 46, 3319 (2011)

    Article  CAS  Google Scholar 

  26. H. Gobara, R. El-Salamony, D. Mohamed, M. Mishrif, Y. Moustafa, T. Gendy, Chem. Mater. Res. 6(6), 63–81 (2014)

    Google Scholar 

  27. S.A. Mahmoud, H.M. Gobara, Synthesis of nanostructured mesoporous ordered silica supported Fe2O3 nanoparticles for water purification, “Processing of nanostructure materials and nanostructure films”,ed. By Kathy Lu, Chris Li, Eugene Medvedoveski and Eugene A. Olevesky, Ceramics Transaction Volume 233, the American Chemical Society, Wiley (2010)

  28. M.-J. Kim, S.-H. Chang, J.-S. Choi, W.-S. Ahn, React. Kinet. Catal. Lett. 82(1), 27 (2004)

    Article  CAS  Google Scholar 

  29. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, Pure Appl. Chem. 57, 603 (1985)

    Article  CAS  Google Scholar 

  30. K. Chandra Mouli, K. Soni, A. Dalai, J. Adjaye, Appl. Catal. A Gen. 404, 21 (2011)

    Article  CAS  Google Scholar 

  31. G. Muthu Kumaran, S. Garg, K. Soni, M. Kumar, L.D. Sharma, G. Murali Dhar, K.S. Rama Rao, Appl. Catal. A Gen. 305, 123 (2006)

    Article  Google Scholar 

  32. G. Muthu Kumaran, S. Garg, K. Soni, M. Kumar, L.D. Sharma, G. Murali Dhar, K.S. Rama Rao, Ind. Eng. Chem. Res. 46, 4747 (2007)

    Article  Google Scholar 

  33. A.M.A. Naggar, H.M. Gobara, H.A. Sayed, F.S. Soliman, Energy Convs. Manage 106, 615 (2015)

    Article  Google Scholar 

  34. H.H. PhucNguyen, H. Ohkita, T. Mizushima, N. Kakuta, J Jpn Petrol. Inst 54(6), 373–379 (2011)

    Article  Google Scholar 

  35. Z. Cheng, X. Quan, Y. Xiong, L. Yang, Y. Huang, Ultrason. Sonochem. 18, 1027 (2012)

    Article  Google Scholar 

  36. M. Radetic, J. Photochem. Photobiol. C 16, 62 (2013)

    Article  CAS  Google Scholar 

  37. S.F. Xiong, Z.L. Yin, Z.F. Yuan, W.B. Yan, W.Y. Yang, Ultrason. Sonochem. 19, 756 (2012)

    Article  CAS  Google Scholar 

  38. Y.L. Pang, A.Z. Abdullah, S. Bhatia, Desalination 277, 1 (2011)

    Article  CAS  Google Scholar 

  39. N. Talebian, M.R. Nilforoushan, F.J. Mogaddas, Ceram. Int. 39, 4913 (2013)

    Article  CAS  Google Scholar 

  40. D. Markovic, B. Jokic, Z. Saponjic, B. Potkonjak, P. Jovancic, M. Radetic, Clean-Soil Air Water 41(10), 1002 (2013)

    CAS  Google Scholar 

  41. C.G. Joseph, G.L. Puma, A. Bono, D. Krishnaiah, Ultrason. Sonochem. 16, 583 (2009)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Egyptian Petroleum Research Institute, 1 Ahmed El-Zomor St., Nasr City, Cairo, 11727, Egypt

    Heba M. Gobara & Radwa A. Elsalamony

  2. Chemistry Department, Faculty of Science, Ain Shams University, Abbassia, Cairo, 11566, Egypt

    Salah A. Hassan

Authors
  1. Heba M. Gobara
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Radwa A. Elsalamony
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Salah A. Hassan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Heba M. Gobara.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gobara, H.M., Elsalamony, R.A. & Hassan, S.A. Sonophotocatalytic degradation of eriochrome black-T dye in water using Ti grafted SBA-15. J Porous Mater 23, 1311–1318 (2016). https://doi.org/10.1007/s10934-016-0190-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-016-0190-3

Keywords

Search

Navigation