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Synthesis of layered MCM-22(P) in the presence of hexamethonium cations and its transformation into EUO- and MWW-type zeolites

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Abstract

Layered MCM-22(P) was synthesized in the presence of hexamethonium (HM) cations. Compared to zeolite EU-1 (EUO-type structure), which crystallizes in similar conditions, its formation is favored at high HM concentrations (HM/SiO2 ≥ 0.3) and in the absence of Na2O. HM-containing MCM-22(P) was used as starting material for zeolite formation. Upon hydrothermal treatment, HM-MCM-22(P) transforms into zeolite EU-1 and upon calcination into a MWW-type zeolite. Transformation mechanisms were studied by standard characterization techniques such as XRD, SEM and TEM. Catalytic properties of the MWW-type zeolite obtained from this precursor were evaluated in a m-xylene isomerization reaction. Compared to zeolite MCM-22 prepared with hexamethyleneimine, a higher catalytic activity and an increased isomerization selectivity were observed and discussed.

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Acknowledgments

The authors would like to give special thanks to Bernadette Rebours, Fanny Tihay, Emmanuelle Trela-Baudot (IFP-Lyon) and Mohammed Ali Saada, Séverinne Rigolet (MPC-IS2 M-Mulhouse) for their contribution to the characterization of the samples.

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Author notes

  1. Simone Goergen

    Present address: Department of Chemical and Biological Engineering, Tufts University, Medford, MA, 02155, USA

Authors and Affiliations

  1. IFP Energies nouvelles, Direction Catalyse et Séparation, BP 3, 69360, Solaize, France

    Simone Goergen, Elie Fayad & Loïc Rouleau

  2. Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), LRC CNRS 7228, Université de Haute Alsace, ENSCMu, 3, rue Alfred Werner, 68093, Mulhouse, France

    Simone Goergen & Joël Patarin

  3. Equipe “Catalyse sur Zéolithes et Solides Apparentés”, Laboratoire de Catalyse en Chimie Organique (LACCO), UMR 6503 CNRS, Université de Poitiers, 40, avenue du Recteur Pineau, 86022, Poitiers, France

    Sébastien Laforge & Patrick Magnoux

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  1. Simone Goergen
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Correspondence to Loïc Rouleau.

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Goergen, S., Fayad, E., Laforge, S. et al. Synthesis of layered MCM-22(P) in the presence of hexamethonium cations and its transformation into EUO- and MWW-type zeolites. J Porous Mater 18, 639–650 (2011). https://doi.org/10.1007/s10934-010-9421-1

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  • DOI: https://doi.org/10.1007/s10934-010-9421-1

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