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Effect of reaction temperature on Fe–Al analcime formation

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Abstract

The effects of reaction period, temperature, and iron species on the zeolite framework type were studied in this work. Gismondine (GIS) is usually synthesized by hydrothermal method at 80°C from sodium metasilicate and aluminum nitrate as starting materials preferentially independent of the presence/absence of iron source. However, the present work revealed that pure analcime (ANA) could be formed at temperatures more than 120°C. A large polyhedral ANA crystal with a diameter of 180 µm was obtained even at a comparatively low temperature such as 150°C at a short reaction period of 1 week. The presence of iron source promoted the formation of pure ANA. Infrared spectroscopy, X-ray diffraction, and ICP-OES analysis suggested that the iron component added as a reactant was incorporated into the ANA framework through the isomorphous substitution for Al.

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References

  1. R.M. Barrer, Hydrothermal Chemistry of Zeolites, Academic Press, London (1982)

    Google Scholar 

  2. T. Wakihara, T. Okubo, Chem. Lett. 34, 276 (2005)

    Article  CAS  Google Scholar 

  3. K. Katsuki, K. Majim, Bull. Chem. Soc. Jpn. 55, 2576 (1982)

    Article  CAS  Google Scholar 

  4. K. Katsuki, K. Majima, Y. Yoshino, Nippon Kagaku Kaishi, 313 (1989) (in Japanese)

  5. K. Katsuki, M. Okamoto, E. Ichikawa, A. Iwashina, S. Koike, Y. Yamamoto, T. Takeuchi, Y. Yoshino, Nippon Kagaku Kaishi, 689 (1995) (in Japanese)

  6. K. Katsuki, A. Furushima, S. Koike, Y. Yamamoto, T. Takeuchi, Y. Yoshino, Nippon Kagaku Kaishi 849 (1996) (in Japanese)

  7. K. Katsuki, Y. Yoshino, Nippon Kagaku Kaishi 364 (1989) (in Japanese)

  8. K. Katsuki, S. Yoneoka, N. Mori, M. Hasegawa, Y. Yamamoto, Y. Yoshino, J. Porous Mater. (in press)

  9. Y. Yokomori, S. Idaka, Micropor. Mesopor. Mater. 21, 365 (1998)

    Article  CAS  Google Scholar 

  10. S. Shimizu, H. Hamada, Micropor. Mesopor. Mater. 48, 39 (2001)

    Article  CAS  Google Scholar 

  11. F. Farzaneh, A. Sadeghpoor, J. Sci. I. R. Iran 13, 225 (2002)

    CAS  Google Scholar 

  12. L.A. Harries, G.W. Clark, H.L. Yakel, Am. Miner. 48, 100 (1963)

    Google Scholar 

  13. L.M. Torves-Martinez, A.R. West, Zeitschrift für Kristallographie 175, 1 (1986)

    Article  Google Scholar 

  14. R. Kumar, A. Bhaumic, R.K. Ahedi, S. Ganapathy, Nature 381, 298 (1996)

    Article  CAS  Google Scholar 

  15. F. Hazel, R.U. Schock Jr., M. Gordon, J. Am. Chem. Soc. 71, 2256 (1949)

    Article  CAS  Google Scholar 

  16. W.J. Weber Jr., W. Stumm, J. Inorg. Nucl. Chem. 27, 237 (1965)

    Article  CAS  Google Scholar 

  17. R.A. Porter, W.J. Weber Jr., J. Inorg. Nucl. Chem. 33, 2443 (1971)

    Article  CAS  Google Scholar 

  18. M.M.J. Treacy, J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites (Elsevier, 2001)

  19. R. Kumar, P. Ratnasamy, J. Catal. 121, 89 (1990)

    Article  CAS  Google Scholar 

  20. R. Kumar, A. Thangaraj, R.N. Bhat, P. Ratnasamy, Zeolites 10, 85 (1990)

    Article  CAS  Google Scholar 

  21. R.B. Borade, Zeolites 7, 398 (1987)

    Article  CAS  Google Scholar 

  22. Y. Yokomori, S. Idaka, Micropor. Mesopor. Mater. 21, 365 (1998)

    Article  CAS  Google Scholar 

  23. Y. Nakamura, M. Hasaegawa, K. Katsuki, Chem. Lett. 34, 490 (2005)

    Article  CAS  Google Scholar 

  24. C.T.W. Chu, C.D. Chang, J. Phys. Chem. 89, 1569 (1985)

    Article  CAS  Google Scholar 

  25. Z. Gabelica, N. Blon, E.G. Derouane, Appl. Catal. 5, 227 (1983)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba, 274-8510, Japan

    Kazuko Katsuki, Hidenori Suzuki, Masatoshi Hasegawa, Michiko Heike, Noriko Hosomachi, Yuya Yamashita & Yuta Nakamura

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  1. Kazuko Katsuki
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  2. Hidenori Suzuki
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  3. Masatoshi Hasegawa
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  4. Michiko Heike
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  5. Noriko Hosomachi
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  6. Yuya Yamashita
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  7. Yuta Nakamura
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Correspondence to Kazuko Katsuki.

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Katsuki, K., Suzuki, H., Hasegawa, M. et al. Effect of reaction temperature on Fe–Al analcime formation. J Porous Mater 14, 443–448 (2007). https://doi.org/10.1007/s10934-006-9038-6

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  • DOI: https://doi.org/10.1007/s10934-006-9038-6

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