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Cyclodextrin@TiO2 Preparation of Bidirectional Composites for TCH Removal by Photocatalytic Synergistic Adsorption

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Abstract

Photocatalytic degradation combined with adsorption removal of contaminants is one of the most effective methods of removing TCH P-(CM-β-CD/HPCS/KHA)@AC/TiO2 composite material was prepared by etheration modification of β-Cyclodextrin (β-CD) and combination of activated carbon (AC) and TiO2, the adsorption/photocatalytic degradation behavior of tetracycline hydrochloride (TCH) was studied, the P-(CM-β-CD/HPCS/KHA)@AC/TiO2 composites were successfully prepared by FTIR, SEM, XRD and XPS Characterisation tests. At 298 K and pH 4, the removal rate of TCH can reach 98% in 2 h. The adsorption of the composites follows the quasi-second-order kinetic model, which is highly consistent with the Langmuir model, an endothermic and spontaneous adsorption process is formed through intermolecular forces and coordination. Photocatalytic degradation follows the quasi-first order model, the photocatalytic performance was verified in conjunction with TOC testing, and the process was known to be a detoxification process through toxicity testing. Finally, after 10 cycles of treatment, the composite material removed up to 70% of TCH.

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Funding

This work was supported by the National Natural Science Foundation of China [grant number 51803114]; Shaanxi Province Key R&D Program [grant number 2022NY-195]; Xi’an City Innovation Capability Strong Foundation Plan-Agricultural Technology R&D [grant number 21NYYF0025]; Shaanxi Provincial Department of Education Service Local Special Plan Project [grant number 22JC015], National key research and development program [grant number. 2021YFC1808900] and Science and Technology Project of Xianyang City [grant number. 2021ZDYF-NY-0013].

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Authors and Affiliations

  1. Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi’an, 710021, China

    Jie Song, Lijun Chen, Zhiqiang Wei & Yuhua Niu

  2. Northwest University, Xi’an, 710021, China

    Yuhua Niu & Xiaoli Zhu

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  1. Jie Song
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  2. Lijun Chen
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  4. Yuhua Niu
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Contributions

JS: Reading and final approval of the version to be published. LC: Data Curation, Validation, Writing- Original draft preparation, Formal analysis, Writing-Reviewing and Editing. YN: Conceptualization; Critically reading. ZW: Methodology, Writing-Reviewing and Editing. XZ: Conceptualization, Methodology.

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Correspondence to Jie Song.

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Song, J., Chen, L., Wei, Z. et al. Cyclodextrin@TiO2 Preparation of Bidirectional Composites for TCH Removal by Photocatalytic Synergistic Adsorption. J Polym Environ (2023). https://doi.org/10.1007/s10924-023-03131-2

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