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An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation

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Abstract

In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl2 on the surface of magnetic Fe3O4 nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe3O4@Catechol/PZ-Phen-MnCl2], then we evaluated its catalytic performance in the synthesis of propargyl amines through the A3 and KA2-coupling three-component reactions aromatic aldehydes or ketones, with alkynes, and amines. FT-IR, SEM, TEM, EDX, XRD, TGA, VSM, ICP-OES and elemental mapping analyzes confirmed the successful synthesis of Fe3O4@Catechol/PZ-Phen-MnCl2 nanocatalyst. The results of the coupling reactions confirmed that the Fe3O4@Catechol/PZ-Phen-MnCl2 nanocomposite is a very efficient catalyst for the preparation of various derivatives of propargyl amines. This method has significant features compared to the previous methods, which can be mentioned as follows: synthesis of products with very high efficiency, carrying out the reaction under mild conditions and compatible with the environment, using green and recyclable catalyst, can being applicable to a wide range of substrates and providing NMR analysis for all propargyl amine products.

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Data Availability

All data generated or analysed during this study are included in this published article and its supplementary information files.

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Authors and Affiliations

  1. School of Life and Health, Wuhan Vocational College of Software and Engineering (Wuhan Open University), Wuhan, 430205, China

    Ying Liu

  2. School of Henan Vocational College of Applied Technology Chemical Engineering, Zhengzhou, 450042, China

    Huili Zhang

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  1. Ying Liu
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  2. Huili Zhang
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Ying Liu: Performing Experimental works and taking analyzes. Huili Zhang: Performing Experimental works and Manager Project.

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Liu, Y., Zhang, H. An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03086-4

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