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Investigation of Growth Dynamics of Nanostructured Aluminum Doped Zinc Oxide Thin Films Deposited for the Solar Cell Applications

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Abstract

Al doped ZnO (AZO) is one of the most promising transparent conducting oxide materials, which widely utilizes as a front contact for the cadmium telluride based thin film solar cells and a working electrode for perovskite solar cells. This research presents the optimization process of the AZO thin films deposited by spray pyrolysis technique at room temperature by studying its structural, morphological and electrical properties at different thicknesses (100, 150, 200, 300 and 400 nm). Obtained results from X-ray diffraction revealed that the degree of crystallinity and the average grain size of the AZO deposited thin films enhance with increasing the thickness. Surface topography and growth behavior of AZO thin films have important role in optimization of optical and electrical properties of these films especially in the solar cell applications. In this research, the atomic force microscopy (AFM) has been used to assess the quantitative parameters related to the surface topography of the films. Obtained results from AFM analysis revealed that the surface topography of AZO deposited samples strongly depend on thickness. Also the electrical characteristics indicate that the thin films have an electrical resistivity of the order of 10−4 Ω cm.

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References

  1. R. Ghosh, G.K. Paul, D. Basak, Effect of thermal annealing treatment on structural, electrical and optical properties of transparent sol–gel ZnO thin films. Mater. Res. Bull. 40, 1905–1914 (2005)

    Article  CAS  Google Scholar 

  2. N.P. Ariyanto, H. Abdullah, S. Shaari, S. Junaidi, B. Yuliarto, Preparation and characterisation of porous nanosheets zinc oxide films; based on chemical bath deposition. World Appl. Sci. J. 6, 764–768 (2009)

    CAS  Google Scholar 

  3. N. Roy, A. Roy, Growth and temperature dependent photoluminescence characteristics of ZnO tetra pods. Ceram. Int. 41, 4154–4160 (2015)

    Article  CAS  Google Scholar 

  4. P.H. Lei, C.M. Hsu, Y.S. Fan, Flexible organic light-emitting diodes on a polyestersulfone (PES) substrate using Al-doped ZnO anode grown by dual-plasma-enhanced metal organic deposition system. Org. Electron. 14, 236–249 (2013)

    Article  CAS  Google Scholar 

  5. L.H. Yu, J.Y. Xi, K.C. Lo, L.J. Antrobus, D.L. Phillips, W.K. Chan, Transient absorption of N719 and its electron transfer kinetics on ZnO nanoparticles surface. J. Inorg. Organomet. Polym. 25, 169–175 (2015)

    Article  CAS  Google Scholar 

  6. S. Chen, M.E.A. Warwick, R. Binions, Effects of film thickness and thermal treatment on the structural and opto-electronic properties of Ga-doped ZnO films deposited by sol–gel method. Sol. Energy Mater. Sol. C. 137, 202–209 (2015)

    Article  CAS  Google Scholar 

  7. C. Jin, T. Yu, Z. Wu, X. Wu, L. Zhuge, Effect of low energy ion bombardment on structure and photoluminescence characterization of Al-doped ZnO thin films. Thin Solid Films 524, 39–43 (2012)

    Article  CAS  Google Scholar 

  8. M.F. Malek, M.H. Mamat, M.Z. Musa, T. Soga, S.A. Rahman, S.A.H. Alrokayan, H.A. Khan, M. Rusop, Metamorphosis of strain/stress on optical band gap energy of ZAO thin films via manipulation of thermal annealing process. J. Lumin. 160, 165–175 (2015)

    Article  CAS  Google Scholar 

  9. S. Zhu, X. Tian, L. Shan, Z. Ding, Z. Kan, X. Xu, Z. Zhou, L. Wang, Effect of Al3+ on the growth of ZnO nanograss film and its application in dye-sensitized solar cells. Ceram. Int. 39, 9637–9644 (2013)

    Article  CAS  Google Scholar 

  10. S. Mondal, K.P. Kanta, P. Mitra, Preparation of Al-doped ZnO (AZO) thin film by SILAR. J. Phys. Sci. 12, 221–229 (2008)

    Google Scholar 

  11. M. Saad, A. Kassis, Effect of rf power on the properties of RF magnetron sputtered ZnO: Al thin films. Mater. Chem. Phys. 136, 205–209 (2012)

    Article  CAS  Google Scholar 

  12. J. Perrenoud, L. Kranz, S. Buecheler, F. Pianezzi, A.N. Tiwari, The use of aluminium doped ZnO as transparent conductive oxide for CdS/CdTe solar cells. Thin Solid Films 519, 7444–7448 (2011)

    Article  CAS  Google Scholar 

  13. J.H. Kim, T.H. Shin, K.J. Yang, J. Jeong, B. Choi, Abstraction of blue photoluminescence in Al-doped ZnO nano particles prepared by electron beam deposition. Appl. Phys. Express. 5, 012603 (2012)

    Article  Google Scholar 

  14. Z. Pan, X. Tian, S. Wu, X. Yu, Z. Li, J. Deng, C. Xiao, G. Hu, Z. Wei, Investigation of structural, optical and electronic properties in Al–Sn co-doped ZnO thin films. Appl. Surf. Sci. 265, 870–877 (2013)

    Article  CAS  Google Scholar 

  15. C. Dwivedi, V. Dutta, Effect of seed layer on the self assembly of spray pyrolyzed Al-doped ZnO nanoparticles. AIP. Adv. 3, 032127 (2013)

    Article  Google Scholar 

  16. C.S. Prajapati, A. Kushwaha, P.P. Sahay, Effect of Al dopants on the structural, optical and gas sensing properties of spray-deposited ZnO thin films. Mater. Chem. Phys. 142, 276–285 (2013)

    Article  CAS  Google Scholar 

  17. J. Xu, H. Wang, L. Yang, M. Jiang, S. Wei, T. Zhang, Low temperature growth of highly crystallized ZnO: Al films by ultrasonic spray pyrolysis from acetylacetone salt. Mater. Sci. Eng. B 167, 182–186 (2010)

    Article  CAS  Google Scholar 

  18. J. Kim, N. Lim, C.R. Park, S. Yim, Growth dynamics of ZnPc and TiOPc thin films: effect of crystallinity on anomalous scaling behavior. Surf. Sci. 604, 1143–1147 (2010)

    Article  CAS  Google Scholar 

  19. D. Raoufi, Fractal analyses of ITO thin films: a study based on power spectral density. Phys. B 405, 451–455 (2010)

    Article  CAS  Google Scholar 

  20. A. Zendehnam, M. Mirzaee, S. Miri, Effect of annealing temperature on PL spectrum and surface morphology of zinc oxide thin films. Appl. Surf. Sci. 270, 163–168 (2013)

    Article  CAS  Google Scholar 

  21. B.D. Cullity, S.R. Stock, Elements of X-ray diffraction, 3rd edn. (Prentice-Hall, New York, 2001)

    Google Scholar 

  22. V. Ioannou-Sougleridis, V. Constantoudis, M. Alexe, R. Scholz, G. Vellianitis, A. Dimoulas, Effects on surface morphology of epitaxial Y2O3 layers on Si (0 0 1) after post growth annealing. Thin Solid Films 468, 303–309 (2004)

    Article  CAS  Google Scholar 

  23. M. Kardar, G. Parisi, Y.-C. Zhang, Dynamic scaling of growing interfaces. Phys. Rev. Lett. 56, 889–892 (1986)

    Article  CAS  Google Scholar 

  24. J. Oystein, H. Bakke, A. Hansen, Accuracy of roughness exponent measurement methods. Phys. Rev. E 76, 031136 (2007)

    Article  Google Scholar 

  25. D. Aurongzeb, E. Washington, M. Basavaraj, J.M. Berg, H. Temkin, M. Holtz, Nanoscale surface roughening in ultrathin aluminum films. J. Appl. Phys. 100, 114320 (2006)

    Article  Google Scholar 

  26. T. Babadagli, K. Develi, Fractal characteristics of rocks fractured under tension. Theor. Appl. Fract. Mech. 39, 73–88 (2003)

    Article  Google Scholar 

  27. T. Prasada Rao, M.C. Santhoshkumar, Effect of thickness on structural, optical and electrical properties of nanostructured ZnO thin films by spray pyrolysis. Appl. Surf. Sci. 255, 4579–4584 (2009)

    Article  CAS  Google Scholar 

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Acknowledgments

This research has been supported by the East Tehran Branch of Islamic Azad University, and the authors would like to thank for this support. Also the corresponding author gratefully acknowledges Dr. Reza Hoseinnezhad at RMIT University, Australia, for his valuable suggestions to improve the manuscript.

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Correspondence to Mohammad Taghi Hosseinnejad.

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Abrinaei, F., Shirazi, M. & Hosseinnejad, M.T. Investigation of Growth Dynamics of Nanostructured Aluminum Doped Zinc Oxide Thin Films Deposited for the Solar Cell Applications. J Inorg Organomet Polym 26, 233–241 (2016). https://doi.org/10.1007/s10904-015-0307-1

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  • DOI: https://doi.org/10.1007/s10904-015-0307-1

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