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Synthesis, Structure and Luminescence Property of Cadmium(II) Coordination Polymer with Mixed 5-(Oxidediphenylphosphino)isophthalic Acid and 4,4′-Bipyridine Ligands

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Abstract

A new metal–organic framework {[Cd(L)(4,4′-bpy)]2·5H2O} n (1) had been synthesized by hydrothermal reaction of 5-(oxidediphenylphosphino)isophthalic acid, Cd(II) nitrate, NaOH and 4,4′-bipyridine (4,4′-bpy) as co-ligand. The novel compound was characterized by single crystal X-ray diffractometry as well as FTIR spectrum. Adjacent eight-member (C2Cd2O4) rings are connected each other through pairs of L2− ligands to result in a 1D double chain. Such ribbons are interconnected together by 4,4′-bpy to generate a 2D pillared layer, which are further held together by rich O–H···O hydrogen bonds to give a 3D supramolecular network. Solvent water molecules play an important role to bridge adjacent layers to form a 3D supramolecular architecture. The luminescence property and thermogravimetric analysis of title complex were investigated.

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Acknowledgments

The authors are grateful for financial support from the International Technology Cooperation Project of Science and Technology Department of Henan Province of China (no. 124300510050).

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Authors and Affiliations

  1. Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou, 450011, China

    Wen-Wen Shan, Xiao Mi, Jia-Yi Pu, Shi-Le Mei, Kai-Hui Li & Chong-Zhen Mei

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  1. Wen-Wen Shan
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  2. Xiao Mi
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  3. Jia-Yi Pu
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Correspondence to Chong-Zhen Mei.

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Shan, WW., Mi, X., Pu, JY. et al. Synthesis, Structure and Luminescence Property of Cadmium(II) Coordination Polymer with Mixed 5-(Oxidediphenylphosphino)isophthalic Acid and 4,4′-Bipyridine Ligands. J Inorg Organomet Polym 23, 533–538 (2013). https://doi.org/10.1007/s10904-012-9805-6

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  • DOI: https://doi.org/10.1007/s10904-012-9805-6

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