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Two Tartrate-Pillared Coordination Polymers: Hydrothermal Preparation, Crystal Structures, Spectroscopic and Thermal Analyses of {[M2(μ-C4H4O6)2(H2O)] · 3H2O}∞ (M = Mn, Cd)

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Abstract

Two novel three-dimensional coordination polymers, formulated as {[M2(μ-C4H4O6)2(H2O)] · 3H2O}∞ (M = Mn for 1 and Cd for 2), have been synthesized under hydrothermal reaction condition. Both complexes were characterized by elemental analysis and IR spectroscopy. Their molecular and crystal structures were determined by X-ray crystal structure analysis and their thermal stability by TGA-DTA methods. Compound 1 crystallizes in the monoclinic space group, P21, while compound 2 crystallizes the orthorhombic space group, P212121. The structures are self-assembled from bifunctional tartrate and water molecules. Tartrate ligands in 1 and 2 contribute to both covalent and hydrogen bonds. Polymeric chains of 1 and 2 are composed of M(II) ions bridged by tartrate ions in O,O′ fashion. The asymmetric units of coordination polymers contain two metal centers having different coordination environments.

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Acknowledgments

This research was supported by Yazd Branch, Islamic Azad University, Yazd, Iran.

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Authors and Affiliations

  1. Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

    Masoumeh Tabatabaee, Atefeh Gholamighavamabad & Elaheh Khabiri

  2. Department of Chemistry, The University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4, Canada

    Masood Parvez

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  1. Masoumeh Tabatabaee
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  2. Atefeh Gholamighavamabad
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Correspondence to Masoumeh Tabatabaee.

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Tabatabaee, M., Gholamighavamabad, A., Khabiri, E. et al. Two Tartrate-Pillared Coordination Polymers: Hydrothermal Preparation, Crystal Structures, Spectroscopic and Thermal Analyses of {[M2(μ-C4H4O6)2(H2O)] · 3H2O}∞ (M = Mn, Cd). J Inorg Organomet Polym 21, 627–633 (2011). https://doi.org/10.1007/s10904-011-9495-5

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